2,4,6-Trichloroaniline 2,4,6-三氯苯胺

CAS 634-93-5 MFCD00007663

化学结构图

634-93-5
SMILES: Nc1c(Cl)cc(Cl)cc1Cl

化学属性

Mol. FormulaC6
Mol. Weight196
Density1.54
Boiling Point262
Melting Point77.0 to 81.0 deg-C
TSCAYes
Solubility<0.1 G/100 ML AT 21.5 ºC
Stability对光敏感
Flash Point262°C

别名和识别编码

Chemical Name2,4,6-Trichloroaniline
Synonym 1-Amino-2,4,6-trichlorobenzene 1-Amino-2,4,6-trichlorobenzene 1-氨基-2,4,6-三氯苯 2 2,4,6-TRICHLOROANILINE 2,4,6-TRICHLOROANILINE PESTANAL, 250 MG 2,4,6-Trichloraminobenzol 2,4,6-Trichloranilin 2,4,6-Trichloro-aniline 2,4,6-Trichloroaniline 2,4,6-Trichloroaniline, 98+% 2,4,6-Trichloroaniline, 98.50% 2,4,6-Trichloroanyline 2,4,6-Trichlorobenzenamine 2,4,6-Trichlorobenzeneamine 2,4,6-Trichlorophenylamine 2,4,6-tca 2,4,6-trichloraniline 2,4,6-trichloro-anilin 2,4,6-trichloro-benzenamin 2,4,6-trichloroaniline 2,4,6-trichloroaniline hydrochloride 2,4,6-trichlorobenzenamine 2,4,6-三氯苯氨 2,4,6-三氯苯胺 2,4,6-三氯苯胺, 98+%
CAS Number634-93-5
EC Number211-219-8
Beilstein Registry Number12,627
MDL NumberMFCD00007663
PubChem Substance ID12471
Reaxys-RN879568
Chemical Name Translation2,4,6-三氯苯胺
Wiswesser Line NotationZR BG DG FG
LabNetwork Molecule IDLN00241853
InChIInChI=1S/C6H4Cl3N/c7-3-1-4(8)6(10)5(9)2-3/h1-2H,10H2
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, All alphabetically sorted, Amines, Analytical Standards, Analytical/Chromatography
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, Environmental Standards, Pesticides & Metabolites, Q-Z, T, TP - TZ
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C6, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 有机合成。

相关文献及参考

  • Short: III/20b
  • Short: III/31a
  • Short: III/10a
  • Beilstein:12,627

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R33 Danger of cumulative effects 有累积作用的危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R50/53
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P316
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H303 May be harmfully swallowed 吞食可能有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H331 Toxic if inhaled 吸入中毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
RTECSBZ0250000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Packing GroupIII
UN Number 3077
Hazard Codes T,N
Storage condition 密封避光保存。
Hazard Class9
Warnings 危化品目录(2015)
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 780 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Liver - tumors
REFERENCE :
   JEPTDQ Journal of Environmental Pathology and Toxicology.  (Park Forest
   South, IL)  V.1-5(3), 1977-81(?).  For publisher information, see JEPOEC.
   Volume(issue)/page/year: 2(2),325,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 390 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Liver - tumors
REFERENCE :
   JEPTDQ Journal of Environmental Pathology and Toxicology.  (Park Forest
   South, IL)  V.1-5(3), 1977-81(?).  For publisher information, see JEPOEC.
   Volume(issue)/page/year: 2(2),325,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS 206512

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1180 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - changes in motor activity (specific assay)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(6),86,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2400 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - changes in motor activity (specific assay)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(6),86,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Env

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   54DEAI "Occupational Health in the Chemical Industry, Proceedings of the
   International Congress, 11th, Alberta, Canada, 1983," Oxford, R.R., et al.,
   eds., Calgary, Alberta, Canada, Univ. of Calgary, 1984
   Volume(issue)/page/year: -,497,1984

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 5 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 211,279,1988

Restrict 危险品

其他信息

  • 类别:有毒物品
  • Alfa Aesar:2,4,6-三氯苯胺,98+% 2,4,6-Trichloroaniline, 98+%(634-93-5)
  • Acros Organics:2,4,6-三氯苯胺 2,4,6-Trichloroaniline, 98.50%(634-93-5)
  • 毒性分级:中毒
  • 可燃性危险特性:明火可燃; 燃烧释放有毒氯化物和氮氧化物烟雾
  • 易溶于二硫化碳,溶于乙醇、乙醚和石油醚,不溶于水。有毒。有刺激性。
  • MSDS 信息:2,4,6-三氯苯胺(634-93-5).msds
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土。
  • Sigma Aldrich:634-93-5(sigmaaldrich)
  • 上游原料:氨基苯
  • Hazard Note:Toxic
  • 图谱信息:2,4,6-三氯苯胺(634-93-5)质谱(MS) 2,4,6-三氯苯胺(634-93-5)红外图谱(IR1) 2,4,6-三氯苯胺(634-93-5)红外图谱(IR2) 2,4,6-三氯苯胺(634-93-5)红外图谱(IR3) 2,4,6-三氯苯胺(634-93-5)核磁图( 1 HNMR) 2,4,6-三氯苯胺(634-93-5)核磁图( 13 CNMR)
  • 外观性质:白色针状结晶。
  • 用途一:用作偶氮染料、杀虫剂、杀菌剂、除草剂和照相用碱性品红偶联剂的原料
  • TCI Shanghai:2,4,6-三氯苯胺 2,4,6-Trichloroaniline,>;98.0%(GC)(634-93-5)
  • MOL 文件:634-93-5.mol
  • 急性毒性:口服-大鼠 LD50: 2400 毫克/公斤; 口服-小鼠 LD50: 1180 毫克/公斤
  • 下游产品:1,3,5-三氯苯
  • 2,4,6-三氯苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010325 2,4,6-三氯苯胺;均三氯苯胺 100g 400元 2011/04/16 T0375 2,4,6-三氯苯胺 2,4,6-Trichloroaniline 500G 1950元 2011/04/16 T0375 2,4,6-三氯苯胺 2,4,6-Trichloroaniline 25G 218元
  • 储运特性:库房通风低温干燥; 与酸类、氧化剂、食品添加剂分开存放

系列性分类


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