2-Aminobenzotrifluoride 邻三氟甲基苯胺

CAS 88-17-5 MFCD00007718

化学结构图

88-17-5
SMILES: Nc1ccccc1C(F)(F)F

化学属性

Mol. FormulaCF3C6H4NH2
Mol. Weight161
Refractive index1.4800 to 1.4830
Boiling Point170-173
Density1.282
Melting Point34
Flash Point55°C(lit.)
TSCAYes
Solubility4 G/L (20 ºC)
Appearance 无色或淡黄色液体，有刺激性。熔点34℃，沸点174℃，闪点55℃，折光率1.4800，比重1.282。

别名和识别编码

Chemical Name2-Aminobenzotrifluoride
Synonym 2-AMINOBENZOTRIFLUORIDE 邻三氟甲基苯胺 {Chem 2-(三氟甲基)苯胺 2-(Trifluoromethyl)benzenamine 2-AMINO-A,A,A-TRIFLUOROTOLUENE 2-胺基三氟甲苯 Α,Α,Α-三氟鄰甲苯胺 2-Aminobenzotrifluoride {Chemica AKOS 91135 2-(Trifluoromethyl)aniline; 2-Trifluoromethyl aniline 间三氟甲(基)苯胺 2-(Trifluoromethyl)aniline ,,-Trifluoro-o-toluidine, 2-(Trifluoromethyl)aniline 2-(trifluoromethyl)-benzenamin 2-(trifluoromethyl)-Benzenamine Benzenamin α,α,α-Trifluoro-o-toluidine 2-(三氟甲基)苯甲酰胺 {Ch 2-氨基三氟甲苯 Α,Α,Α-三氟邻甲苯胺 2-Trifluormethylaminobenzol
CAS Number88-17-5
PubChem Substance ID87562062
EC Number201-806-7
Beilstein Registry Number879494
MDL NumberMFCD00007718
Reaxys-RN879494
Chemical Name Translation邻三氟甲基苯胺
InChIKeyVBLXCTYLWZJBKA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00226507
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分类

  • Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 该品是合成含氟除草剂和医药、染料的重要中间体。

相关文献及参考

  • Short: III/35D2
  • The CF3 group promotes ionization of the amino group under basic conditions which also make the CF3 unusually reactive towards nucleophiles. Many examples have been reported by L. Strekowski et al in which various heterocyclic systems have been synthesized. See, e.g.: J. Org. Chem., 59, 5886 (1994); Tetrahedron Lett., 35, 7597 (1994) and refs therein:
  • Short: III/35B
  • Beilstein:12(2)453

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H331 Toxic if inhaled 吸入中毒
  • H301 Toxic if swallowed 吞食有毒
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T,Xi,Xn Xn T
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P305+P351+P338+P337+P313
  • P301+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P337+P313
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P302+P352+P312+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P403+P235
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
Signal word
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
  • R33 Danger of cumulative effects 有累积作用的危险
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R51/53
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
UN Number
Packing GroupIII
Hazard Class6.1
RTECSXU9210000
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • Sigma Aldrich:88-17-5(sigmaaldrich)
  • 图谱信息:邻氨基三氟甲苯(88-17-5)质谱(MS) 邻氨基三氟甲苯(88-17-5)Raman光谱 邻氨基三氟甲苯(88-17-5)核磁图( 13 CNMR) 邻氨基三氟甲苯(88-17-5)红外图谱(IR1) 邻氨基三氟甲苯(88-17-5)核磁图( 1 HNMR)
  • 用途三:该品是合成含氟除草剂和医药、染料的重要中间体。
  • 用途二:用作染料、医药、农药中间体
  • Hazard Note:Toxic/Irritant
  • MSDS 信息:2-(Trifluoromethyl)aniline(88-17-5).msds
  • Alfa Aesar:2-氨基三氟甲苯,98% 2-(Trifluoromethyl)aniline, 98%(88-17-5)
  • Acros Organics:2-三氟甲基苯胺 2-Aminobenzotrifluoride, 99%(88-17-5)
  • 海关编码:29214300
  • 用途一:用作医药、农药及染料的中间体
  • 邻氨基三氟甲苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0433 2-氨基三氟甲苯 2-Aminobenzotrifluoride 25ML 240元 2014/06/02 A0433 2-氨基三氟甲苯 2-Aminobenzotrifluoride 500ML 1430元 2010/06/21 103180050 邻氨基三氟甲苯 2-Aminobenzotrifluoride 99% 5 ML 162元
  • 有刺激性，水中溶解度：4g/L(20℃),溶于醚、醇和乙醚。
  • 下游产品:4-氯-8-(三氟甲基)喹啉 --> 8-三氟甲基喹啉-2-甲醛 --> 间三氟甲苯异氰酸酯 --> 酸性红337
  • 检测方法:GC,NMR
  • TCI Shanghai:2-氨基三氟甲苯 2-Aminobenzotrifluoride,>;98.0%(GC)(T)(88-17-5)
  • MOL 文件:88-17-5.mol

系列性分类

  1. C7 - Amines
  1. C10 to C11 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C2 to C6

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