CAS 99-03-6 MFCD00007796-3’-Aminoacetophenone 3-氨基苯乙酮 -LabNovo

3’-Aminoacetophenone 3-氨基苯乙酮

CAS 99-03-6 MFCD00007796

化学结构图

SMILES: CC(=O)c1cccc(N)c1

化学属性

Mol. Formula	C8H9NO
Mol. Weight	135.16
Boiling Point	289-290°C at 760 mmHg
Melting Point	94-98°C
TSCA	T
Density	1.215
Flash Point	289-291°C
Appearance	从乙醇中得苍黄色片状体，熔点98-99℃，沸点289-290℃，溶于醇，不溶于水。在水蒸气中部分挥发。

别名和识别编码

Chemical Name	3’-Aminoacetophenone
CAS Number	99-03-6
Alfabeta Name	AMINOACETOPHENONE 3-'
MDL Number	MFCD00007796
Synonym	3-Acetylaniline {LY} 3-Acetylaniline {} {LY} 3-Acetylaniline {} {} {LY} 3-Acetylaniline {} {} {} {LY} 3-Acetylaniline {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Acetylaniline {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	7417
EC Number	202-722-3
Beilstein Registry Number	386009
Merck Number	413
Reaxys-RN	386009
Chemical Name Translation	3-氨基苯乙酮
InChIKey	CKQHAYFOPRIUOM-UHFFFAOYSA-N
Wiswesser Line Notation	ZR CV1
LabNetwork Molecule ID	LN00117176
InChI	InChI=1S/C8H9NO/c1-6(10)7-3-2-4-8(9)5-7/h2-5H,9H2,1H3
Canonical SMILES	CC(C1=CC(N)=CC=C1)=O

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

医药中间体。

安全信息

Warnings IRRITANT

GHS Symbol

WGK Germany2

Hazard statements

H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

RTECSAM5800000

Precautionary statements

P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P332+P313
P337+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Safety Statements

S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R22 Harmful if swallowed 吞咽有害

Hazard Codes Xn Xn,Xi

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2048 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 2,55,1950

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1870 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 4340 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Subcutaneous
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 400 mg/kg
REFERENCE :
   TGANAK Tsitologiya i Genetika.  Cytology and Genetics.  For English
   translation, see CYGEDX. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-    1967-  Volume(issue)/page/year: 2,538,1968

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 mg/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5,803,1983

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

Alfa Aesar:3'-氨基苯乙酮,97% 3'-Aminoacetophenone, 97%(99-03-6)
毒性分级:中毒
TCI Shanghai:3'-氨基苯乙酮 3'-Aminoacetophenone,>;98.0%(GC)(99-03-6)
Hazard Note:Irritant
急性毒性:口服-大鼠LD50: 1870毫克/公斤
可燃性危险特性:可燃;燃烧产生有毒氮氧化物烟雾
类别:有毒物品
上游原料:铁粉 --> 工业盐酸 --> 间硝基苯乙酮
方法一:由间硝基苯乙酮用铁粉还原而得，将水加入反应罐，搅拌下加入铁粉，缓缓加入工业盐酸。再分批投入间硝基苯乙酮。加热回流6h。冷却至30℃，加盐酸使反应液呈强酸性。过滤，滤液加氨水至呈弱碱性，析出固体物。甩滤，滤饼为间氨基苯乙酮。收率85%。
图谱信息:间氨基苯乙酮(99-03-6)红外图谱(IR2) 间氨基苯乙酮(99-03-6)红外图谱(IR1) 间氨基苯乙酮(99-03-6)质谱(MS) 间氨基苯乙酮(99-03-6)核磁图( 13 CNMR) 间氨基苯乙酮(99-03-6)核磁图( 1 HNMR) 间氨基苯乙酮(99-03-6)红外图谱(IR3)
Acros Organics:3'-氨基苯乙酮 3'-Aminoacetophenone, 97%(99-03-6)
MOL 文件:99-03-6.mol
用途二:医药中间体。
Sigma Aldrich:99-03-6(sigmaaldrich)
海关编码:29223900
储运特性:库房通风低温干燥
TSCA:T
MSDS 信息:m-Aminoacetophenone(99-03-6).msds
用途一:用于合成苯肾上腺素药物、催眠药扎来普隆等，又可作为有机合成原料
下游产品:3-乙酰胺基苯乙酮 --> 3-羟基苯乙酮 --> 二甲氨基苯乙酮
从乙醇中得苍黄色片状体，溶于醇，不溶于水。在水蒸气中部分挥发。
刺激数据:皮肤-兔子500 毫克/24小时轻度
灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
间氨基苯乙酮价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 L0210101 3-氨基苯乙酮97％ 50g 195元 2011/04/16 A0249 3'-氨基苯乙酮 3'-Aminoacetophenone 25G 189元 2011/04/16 A0249 3'-氨基苯乙酮 3'-Aminoacetophenone 500G 1270元