m-Toluidine 3-甲基苯胺

CAS 108-44-1 MFCD00007808

化学结构图

108-44-1
SMILES: Cc1cccc(N)c1

化学属性

Mol. FormulaC7H9N
Mol. Weight107.15
Density0.999
Refractive index1.5660 to 1.5700
Boiling Point-
Flash Point-
TSCAYes
Melting Point-30°
Solubility微溶于水，溶于醇、醚、稀酸。
Stability对光敏感

别名和识别编码

Chemical Namem-Toluidine
MDL Number-
CAS Number108-44-1
EC Number203-583-1
Beilstein Registry Number635944
Synonym 3-Toluidine {LY} 3-Toluidine 3-甲基苯胺 3-甲基苯胺,间氨基甲苯,间甲基苯胺,3-氨基甲苯 m-Methylbenzenamine m-Tolylamine Benzenamine, 3-methyl- Benzenamine,3-methyl- M-TOLUIDINE aniline,3-methyl- m-Toluidin m-Toluidine {} {LY} 3-Toluidine {} {} {LY} 3-Toluidine {} {} {} {LY} 3-Toluidine {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} { {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Toluidine {} {} {} {} {} {} {} {} {} {
PubChem Substance ID7934
Merck Number9536
Chemical Name Translation3-甲基苯胺
Reaxys-RN635944
Wiswesser Line NotationZR C1
LabNetwork Molecule IDLN00199379
InChIInChI=1S/C7H9N/c1-6-3-2-4-7(8)5-6/h2-5H,8H2,1H3
Canonical SMILESNC1=CC=CC(C)=C1
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分类

  • {SNA} Analytical Standards, Organic Pollutant Standards, Volatiles & Semivolatiles, 分析/色谱
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 检定锇、钯、铂、钌和亚硝酸盐。

相关文献及参考

  • Merck:14,9536 Beilstein:12,853
  • Merck:14,9536
  • Short: II/5
  • Short: III/20a
  • Short: II/27B

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P308+P313
  • P332+P313
  • P302+P352
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312+P330
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P302+P350
  • P337+P313
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301+H311+H331
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSXU2800000
Packing GroupII
UN Number
Hazard Codes T,N
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 450 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 90,260,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 740 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher i

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 116 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AISFAR Archivio Italiano di Scienze Farmacologiche.  (Modena, Italy) V.1-11,
   1932-42; Series 2: V.1-3, 1948-50; Series 3: V.1-15, 1951-65. Discontinued. 
   Volume(issue)/page/year: 1,284,1951

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 242 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST

Restrict 危险品

其他信息

  • 刺激数据:皮肤-兔子500 毫克/24小时 轻度;眼睛-兔子20毫克/24小时 中度
  • 见光或在空气中被氧化，逐渐变成褐色。能随水蒸气挥发。溶于乙醇、DMF、乙醚和稀酸，微溶于水。溶于稀无机酸并生成盐。溶解度：0.2 G/100ML水 (20°C)，>50 G/100ML甲醇，>50 G/100ML乙醇。
  • 可燃性危险特性:遇明火可燃;燃烧产生有毒氮氧化物烟雾; 与氧化剂反应
  • 职业标准:TWA 9 毫克/立方米
  • 用途四:间甲苯胺（108-44-1）用作聚酯树脂的溶剂，聚氨基甲酚乙酯泡沫塑料的添加剂，偶氨染料和阳离子树脂的中间体。
  • Sigma Aldrich:108-44-1(sigmaaldrich)
  • Hazard Note:Toxic
  • MOL 文件:108-44-1.mol
  • 3-甲基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80131328 间甲苯胺;3-甲基苯胺;间叨胺;间氨基甲苯 500ml 52.7元 2011/08/23 80131380 间甲苯胺;3-甲基苯胺;间叨胺;间氨基甲苯 250ml 137元 2011/04/16 T0298 间甲苯胺 m-Toluidine 500ML 676元
  • 用途二:用作分析试剂，也用于有机和染料的合成
  • 类别:有毒物品
  • 上游原料:4-硝
  • 下游产品:4-溴-3-甲基乙酰苯胺 --> 7-喹啉甲酸 --> 直接耐晒嫩黄RS --> 3-[(甲氧羰基)氨基]苯基-N-(3-甲基苯基)氨基甲酸酯 --> 7-甲基喹啉 --> 1-(3-（甲基苯基）哌啶 --> CI 42735 --> 3-氯甲苯 --> 5-甲基苯并三氮唑 --> 7-喹啉甲醛 --> N-乙基间甲苯胺 --> 涛洛西酮 --> 直接黄86 --> 3-氟甲苯 --> 酸性红 B --> 活性黄M-3RE --> N,N-二乙基间甲苯胺 --> 溶剂蓝63 --> 3-氟三氟甲苯 --> 溶剂红 25 --> 间甲苯基苄胺 --> 活性黄4
  • Alfa Aesar:间甲苯胺,99% m-Toluidine, 99%(108-44-1)
  • Acros Organics:
  • 健康危害:108-44-1（间甲苯胺）是强烈的高铁血红蛋白形成剂，并能刺激膀胱尿道，能致血尿。急性中毒：多由皮肤污染而吸收引起。自觉脸部灼热、剧烈头痛、头晕、呼吸困难，呈现紫绀症。以后出现血尿、尿闭、精神障碍、肌肉抽搐。慢性中毒：可引起膀胱刺激症状。
  • 用途五:检定锇、钯、铂、钌和亚硝酸盐。
  • TCI Shanghai:间甲苯胺 m-Toluidine,>;98.0%(GC)(T
  • 图谱信息:3-甲基苯胺(108-44-1)红外图谱(IR2) 3-甲基苯胺(108-44-1)质谱(MS) 3-甲基苯胺(108-44-1)核磁图( 1 HNMR) 3-甲基苯胺(108-44-1)红外图谱(IR1) 3-甲基苯胺(108-44-1)核磁图( 13 CNMR)
  • 急性毒性:口服-大鼠 LD50: 450 毫克/公斤; 口服-小鼠LD50: 740 毫克/公斤
  • 外观性质:无色油状液体。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • F:8-23
  • 用途三:该品为活性黄X-R
  • 存储注意事项:空气敏感;氮气保护;湿度敏感
  • 包装储存:200kg 220kg镀锌桶包装，贮存于阴凉干燥处。
  • 毒性分级:
  • MSDS 信息:3-甲基苯胺(108-44-1).m
  • 海关编码:29214300
  • 特性:能随水蒸气挥发。在空气和光的作用下色泽变深。
  • 用途一:用作阳离子染料、彩色电影显影剂的中间体

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. C8 - Amines
  1. C10 to C11 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C2 to C6

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