N-Ethyl-m-Toluidine N-乙基-间-甲苯胺

CAS 102-27-2 MFCD00009027

化学结构图

102-27-2
SMILES: CCNc1cccc(C)c1

化学属性

Mol. FormulaC₉H₁₃N
Mol. Weight135.21
Refractive index1.5450 to 1.5480
Boiling Point
Density0.957
Flash Point104°C(lit.)
Solubility1131 MG/L (20 ºC)
Melting PointNo data available

别名和识别编码

Chemical NameN-Ethyl-m-Toluidine
MDL NumberMFCD00009027
CAS Number102-27-2
Synonym 3-Methyl-N-ethylaniline m-Methyl-N-ethylaniline N-ETHYL-3-TOLUIDINE N-Ethyl-3-aminotoluene N-Ethyl-N-(3-methylphenyl)amine N-Ethyl-m-toluidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {SNA} N-乙基间甲苯胺 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} N-ethyl-m-methylaniline
PubChem Substance ID7603
EC Number203-019-4
Beilstein Registry Number12(3)1954
Alfabeta NameETHYLMETHYLANILINE N3---
Reaxys-RN742170
Chemical Name TranslationN-乙基-间-甲苯胺
InChIInChI=1S/C9H13N/c1-3-10-9-6-4-5-8(2)7-9/h4-7,10H,3H2,1-2H3
LabNetwork Molecule IDLN00177714
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C9, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301+H311+H331
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSCY0440000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P310
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P302+P350
  • P337+P313
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P403+P233
Signal word
Hazard Codes T
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R52/53
UN Number
Warnings IRRITANT 危化品目录(2015) 危险化学品
Packing GroupII
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 580 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(1),50,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 280 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(1),50,1986

Storage condition 4

其他信息

  • TCI Shanghai:N-乙基间甲苯胺 N-Ethyl-m-toluidine,>;98.0%(GC)(102-27-2)
  • 用途一:用作染料中间体及感光材料中间体
  • 毒性分级:高毒
  • 类别:有毒物品
  • 用途二:彩色显影剂的重要中间体，亦可作染料中间体。
  • 图谱信息:N-乙基间甲苯胺(102-27-2)核磁图( 1 HNMR) N-乙基间甲苯胺(102-27-2)红外图谱(IR1) N-乙基间甲苯胺(102-27-2)红外图谱(IR2) N-乙基间甲苯胺(102-27-2)核磁图( 13 CNMR) N-乙基间甲苯胺(102-27-2)质谱(MS)
  • 储运特性:库房通风低温干燥; 与氧化剂, 酸类, 及食品分开储运
  • MSDS 信息:N-乙基间甲苯胺(102-27-2).msds
  • MOL 文件:102-27-2.mol
  • Sigma Aldrich:102-27-2(sigmaaldrich)
  • 急性毒性:口服- 大鼠 LD50 500 毫克/ 公斤; 口服- 小鼠 LD50: 200 毫克/公斤
  • 下游产品:碱性蓝 11 --> 4-(N-乙基-N-羟乙基)-2-甲基苯二胺硫酸盐
  • 方法一:以间甲苯胺为原料，在反应釜中加热升温，在一定温度下滴加溴乙烷溶液，回流维持几小时后，再加碱液中和，分离后，经精馏而得成品。
  • 可燃性危险特性:可燃; 燃烧分解有毒氧化氮气体
  • N-乙基间甲苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0178 N-乙基间甲苯胺 N-Ethyl-m-toluidine 500ML 1130元 2014/06/02 E0178 N-乙基间甲苯胺 N-Ethyl-m-toluidine 25ML 239元 2010/06/21 146835000 N-乙基间甲苯胺 N-Ethyl-m-toluidine 99+% 500 GR 1373元
  • 外观性质:无色至琥珀色液体。
  • Acros Organics:N-乙基-间-甲苯胺 N-Ethyl-m-toluidine, 99+%(102-27-2)
  • 灭火剂:二氧化碳, 泡沫, 干粉, 砂土
  • 上游原料:溴乙烷 --> 3-甲基苯胺

系列性分类

  1. C13 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds

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