Diethyl ethylidenemalonate 亚乙基丙二酸二乙酯

CAS 1462-12-0 MFCD00009145

化学结构图

1462-12-0
SMILES: CC=C(C(=O)OCC)C(=O)OCC

化学属性

Mol. FormulaC9H14O4
Mol. Weight186.21
Density1.019 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.442(lit.)
Flash Point85.1°C
TSCANo
Boiling Point232.1°C at 760 mmHg

别名和识别编码

Chemical NameDiethyl ethylidenemalonate
MDL NumberMFCD00009145
CAS Number1462-12-0
Synonym Diethyl 2-ethylidenemalonate {LY} Diethyl 2-ethylidenemalonate {} {LY} Diethyl 2-ethylidenemalonate {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl 2-ethylidenemalonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diet
EC Number215-965-5
Beilstein Registry Number1773932
PubChem Substance ID73831
Chemical Name Translation亚乙基丙二酸二乙酯
InChIKeyLBBAWVLUOZVYCC-UHFFFAOYSA-N
LabNetwork Molecule IDLN01808564
InChIInChI=1S/C9H14O4/c1-4-7(8(10)12-5-2)9(11)13-6-3/h4H,5-6H2,1-3H3
Canonical SMILESO=C(OCC)C(C(OCC)=O)=CC
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分类

  • {SNA} Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Addition of dibromocarbene (bromoform/NaOH) gives the dibromocyclopropane in good yield: Tetrahedron Lett., 26, 6353 (1985). Reaction with propargyl bromides in the presence of zinc leads to cyclopentenes: Synthesis, 150 (1978).
  • Reaction with crotyltriisopropoxytitanium produces the anti-adduct as the major product: J. Chem. Soc., Chem. Commun., 386 (1985):

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves
Hazard Codes Xi
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:1462-12-0.mol
  • 亚乙基丙二酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L12117 亚乙基丙二酸二乙酯, 99% Diethyl ethylidenemalonate, 99% 5g 535元 2010/05/25 L12117 亚乙基丙二酸二乙酯, 99% Diethyl ethylidenemalonate, 99% 1g 176元
  • Sigma Aldrich:1462-12-0(sigmaaldrich)
  • Alfa Aesar:亚乙基丙二酸二乙酯,99% Diethyl ethylidenemalonate, 99%(1462-12-0)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C8 to C9 - Esters

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