Propyltriphenylphosphonium Bromide 丙基三苯基溴化鏻

CAS 6228-47-3 MFCD00011843

化学结构图

6228-47-3
SMILES: CCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]

化学属性

Mol. FormulaC21H22BrP
Mol. Weight385.29
Melting Point235-238°C
TSCANo
Solubility可溶
Density0.904
Stability易吸潮

别名和识别编码

Chemical NamePropyltriphenylphosphonium Bromide
Synonym Triphenyl(propyl)phosphonium bromide {LY} Triphenyl(propyl)phosphonium bromide {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyl(propyl)phosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyl(propyl)p
MDL NumberMFCD00011843
PubChem Substance ID80374
CAS Number6228-47-3
EC Number240-056-5
Beilstein Registry Number3599726
Reaxys-RN3599726
Chemical Name Translation丙基三苯基溴化鏻
InChIKeyXMQSELBBYSAURN-UHFFFAOYSA-M
LabNetwork Molecule IDLN00192760
InChIInChI=1S/C21H22P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
Canonical SMILESCCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 6. W. E. Noland, et al., J. Heterocycl. Chem. 46 , 1154-1176, (2009)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 溶于水。
  • MOL 文件:6228-47-3.mol
  • Sigma Aldrich:6228-47-3(sigmaaldrich)
  • 三苯基丙基溴化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1200 丙基三苯基溴化 Triphenylpropylphosphonium Bromide 500G 2480元 2014/06/02 P1200 丙基三苯基溴化 Triphenylpropylphosphonium Bromide 25G 305元 2010/05/25 A12968 (1-丙基)三苯基溴化磷, 99% (1-Propyl)triphenylphosphonium bromide, 99% 250g 1988元
  • 敏感性:Hygroscopic
  • F:3-8
  • TCI Shanghai:丙基三苯基溴化膦 Triphenylpropylphosphonium Bromide,>;98.0%(T)(6228-47-3)
  • Alfa Aesar:(1-丙基)三苯基溴化磷,99% (1-Propyl)triphenylphosphonium bromide, 99%(6228-47-3)

系列性分类


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