Sodium Hexafluoroantimonate 六氟锑酸钠

CAS 16925-25-0 MFCD00003482

化学结构图

16925-25-0
SMILES: [Na+].F[Sb-](F)(F)(F)(F)F

化学属性

Mol. FormulaNaSbF6
Mol. Weight259
Density3.375 g/mL at 25 °C(lit.)
TSCAYes
Solubility可溶
Flash Point247-254°C
Appearance 邻三氟甲基苯甲酸是白色固体，m.p.109～113℃，b.p.247℃/0.1 MPa，难溶于水，易溶于有机溶剂。
Boiling Point247 °C753 mm Hg(lit.)
Melting Point107-110 °C(lit.)

别名和识别编码

Chemical NameSodium Hexafluoroantimonate
Synonym {uni_hamburg} 2-(Trifluoromethyl)benzoic Natriumhexafluoroantimonat(V) Antimonate(1-), hexafluoro-, sodium, (OC-6-11)- 2-(Trifluoromethyl)benzoicacid98% 2，2，2-trifluoro-o-toluic acid 2-TRIFLUROMETHYLBENZOIC ACID Natriumhexafluorantimonat 2-(三氟甲基)苯甲酸 SODIUM HEXAFLUOROANTIMONATE α,α,α-Trifluoro-o-toluic acid, 2-Carboxybenzotrifluoride Natriumhexafluoroantimonat (OC-6-11)- Sodium hexafluoroantimonate(V) 邻三甲基苯甲酸 邻三氟甲基苯甲酸 Benzoic acid, 2-(trifluoromethyl)- SODIUM HEXAFLUOROANTIMONATE(V) sodium hexafluoroantimonate Sodium hexafluoroantimonate (V) 六氟锑酸钠 2-(Trifluoromethyl)benzoic acid 98% 2-三氟甲基苯甲酸 SODIUM ANTIMONY FLUORIDE alpha,alpha,alpha-Trifluoro-o-toluic acid 2-Carboxybenzotrifluoride 2-(Trifluoromethyl)benzoic acid 2-(三氟甲基)苯甲酸, 98+% α,α,α-trifluoro-o-toluic acid à,à,à-trifluoro-o-toluic acid ANTIMONY SODIUM FLUORIDE Natrium-hexafluoroantimonat
MDL NumberMFCD00003482
PubChem Substance ID24854282
EC Number240-989-8
CAS Number16925-25-0
Chemical Name Translation六氟锑酸钠
Beilstein Registry Number976984
LabNetwork Molecule IDLN00132224
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分类

  • {SNA} Antimony, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Sodium Salts, 材料科学
  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 酰胺类杀菌剂
  • {uni_hamburg} no charge; 2fragments; ionic
  • {SNA} Antimony Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Sodium Salts, 材料科学
  • {SNA} Antimony, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts,

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: IV/4 Title: High-Pressure Properties of Matter Author: Beggerow, G. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/4 Year: 1980 ISBN: 3-540-09370-2 ISBN: 978-3-540-09370-1 Internet Resource: DOI:10.1007/b90280 RefComment: 589 figs., VIII, 427 pages. Hardcover Abstract: The main topics are pressure dependences of phase equilibria, compressibility, thermal and caloric properties, transport phenomena, static and magnetic properties, optical phenomena, kinetic phenomena, and systems in the neighbourhood and above the critical area.

安全信息

Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
WGK Germany2
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Packing GroupIII
UN Number UN1549 UN 1549 6.1/PG 3
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R51/53
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive
Hazard Codes Xn;N Xn,N,Xi Xn,N

其他信息

  • 下游产品:氟担菌宁 --> 4-硝基-2-三氟甲基苯甲酸 --> 2-三氟甲基苯甲酰氯
  • Acros Organics:2-(三氟甲基)苯甲酸 2-(Trifluoromethyl)benzoic acid, 98%(433-97-6)
  • MSDS 信息:alpha,alpha,alpha-Trifluoro-o-toluic acid(433-97-6).msds
  • Sigma Aldrich:433-97-6(sigmaaldrich)
  • MOL 文件:433-97-6.mol
  • 2-三氟甲基苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1302 2-(三氟甲基)苯甲酸 2-(Trifluoromethyl)benzoic Acid 10G 1200元 2010/06/21 188450050 2-三氟甲基苯甲酸 2-(Trifluoromethyl)benzoic acid 98% 5 GR 753元 2010/06/21 188450010 2-三氟甲基苯甲酸 2-(Trifluoromethyl)benzoic acid 98% 1 GR 259元
  • TCI Shanghai:2-三氟甲基苯甲酸 2-(Trifluoromethyl)benzoic Acid,>;98.0%(T)(433-97-6)
  • 方法一:其制备方法是将2-氯-三氟甲基苯加入到溶剂四氢呋喃中，再在55～60℃加入金属镁，分批加入使发生格氏反应，然后再加入在乙醚中的干冰(二氧化碳)搅拌反应而得到成品。
  • 上游原料:镁 --> 二氧化碳 --> 邻氯三氟甲苯
  • Hazard Note:Irritant
  • F:1-10
  • 用途一:邻三氟甲基苯甲酸是杀菌剂氟酰胺的中间体。
  • 检测方法:HPLC,NMR
  • Alfa Aesar:2-(三氟甲基)苯甲酸,98+% 2-(Trifluoromethyl)benzoic acid, 98+%(433-97-6)
  • 图谱信息:2-三氟甲基苯甲酸(433-97-6)核磁图( 13 CNMR) 2-三氟甲基苯甲酸(433-97-6)质谱(MS) 2-三氟甲基苯甲酸(433-97-6)红外图谱(IR2) 2-三氟甲基苯甲酸(433-97-6)核磁图( 1 HNMR) 2-三氟甲基苯甲酸(433-97-6)红外图谱(IR1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Antimony - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Sodium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Sodium Salts 钠盐
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Aluminum