1-Bromohexane 1-溴己烷

CAS 111-25-1 MFCD00000271

化学结构图

111-25-1
SMILES: CCCCCCBr

化学属性

Mol. FormulaCH3(CH2)5Br
Mol. Weight165
Density1.176
Refractive index1.4450 to 1.4490
Vapor Density5.7 (vs air)
Boiling Point154-158
Vapor Pressure<;10 mmHg ( 20 °C)
Melting Point-85
Flash Point52°C(lit.)
TSCAYes
Solubility不溶于水,溶于醇、醚、酯。
Stability对光敏感

别名和识别编码

Chemical Name1-Bromohexane
CAS Number111-25-1
EC Number203-850-2
Beilstein Registry Number1731290
MDL NumberMFCD00000271
Synonym 1-BROMOHEXANE pure 1-Bromohexane 1-Bromohexane99+% 1-Hexyl bromide 1-hexylbromide 1-溴己烷 Bromohexane C6H13Br (1-bromo-hexane) HEXYL BROMIDE Hexyl bromide N-HEXYL BROMIDE N-Hexyl romide N-hexyl bromide N-溴己烷 hexylbromide(1-bromohexane) n-Hexyl bromide 己基溴 正己基溴 正溴己烷 溴代正已烷 溴己烷,1-溴己烷,1-溴代正己烷,己基溴,溴代己烷
PubChem Substance ID8101
Reaxys-RN1731290
Chemical Name Translation1-溴己烷
LabNetwork Molecule IDLN00223360
InChIInChI=1S/C6H13Br/c1-2-3-4-5-6-7/h2-6H2,1H3
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 溶剂,有机合成。

相关文献及参考

  • Beilstein:1(4)352
  • Short: III/20b
  • Short: III/38B
  • Short: III/47

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSMO0925000
Hazard Codes 3
UN Number 1993
Packing GroupIII
Hazard Class3
Storage condition 密封避光保存。
Warnings 危化品目录(2015)
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 550 gm/m3/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAVUAI Fiziologicheski Aktivnye Veshchestva.  Physiologically Active
   Substances.  (Izdatel'stvo Naukova Dumka, Kiev, USSR)  No.1-    1966-
   Volume(issue)/page/year: 7,35,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1226 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(12),52,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 13600 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 18(4),55,1974

其他信息

  • 毒性分级:中毒
  • 用途二:溴己烷(111-25-1)是用于制备聚酮的离子液体的原料药
  • Alfa Aesar:1-溴己烷,99% 1-Bromohexane, 99%(111-25-1)
  • TCI Shanghai:溴己烷 1-Bromohexane,>;98.0%(GC)(111-25-1)
  • 急性毒性:腹注- 小鼠 LD50: 1226 毫克/ 公斤
  • 图谱信息:溴己烷(111-25-1)核磁图( 13 CNMR) 溴己烷(111-25-1)核磁图( 1 HNMR) 溴己烷(111-25-1)红外图谱(IR2) 溴己烷(111-25-1)质谱(MS) 溴己烷(111-25-1)红外图谱(IR1)
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃; 受热分解有毒溴化氢气体
  • MSDS 信息:溴己烷(111-25-1).msds
  • 蒸气密度:5.7 (vs air)
  • 检测方法:GC
  • 不溶于水。
  • 类别:易燃液体
  • 职业标准:STEL 0.3 毫克/ 立方米
  • 外观性质:无色或淡黄色液体,有刺激性气味。
  • 用途一:用作溶剂,也用于有机合成
  • Sigma Aldrich:111-25-1(sigmaaldrich)
  • 蒸气压:<;10 mm Hg ( 20 °C)
  • 溴己烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80020726 1-溴代己烷 100ml 120.5元 2011/04/16 B0600 1-溴己烷 1-Bromohexane 500G 440元 2011/04/16 B0600 1-溴己烷 1-Bromohexane 25G 150元
  • MOL 文件:111-25-1.mol
  • 参考质量标准:水分 ≤0.05% pH值 6.0~8.0 不挥发物 ≤50PPM
  • 灭火剂:泡沫、二氧化碳、干粉、砂土、雾状水
  • 储运特性:包装完整、轻装轻放; 库房通风、远离明火、高温、与氧化剂、强酸分开存放
  • Acros Organics:1-溴已烷 1-Bromohexane, 99+%(111-25-1)
  • 海关编码:29033036
  • 下游产品:2-已基十一酸 --> 1-己烷磺酸钠一水合物 --> 三己基膦 --> 1-己烷磺酸钠 --> 二乙二醇单己醚 --> 正己基三甲基溴化铵

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