Binol, (+)- (R)-(+)-1,1′-联(2-萘酚)

CAS 18531-99-2 MFCD00004068

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 439325
(R)-(+)-1,1'-Bi(2-naphthol) (R)-(+)-1,1′-联(2-萘酚)
99% 5g 140
96-99 %
INFI 439325
(R)-(+)-1,1'-Bi(2-naphthol) (R)-(+)-1,1′-联(2-萘酚)
99% 10g 680
96-99 %
INFI 439325
(R)-(+)-1,1'-Bi(2-naphthol) (R)-(+)-1,1′-联(2-萘酚)
99% 25g 320
96-99 %
INFI 439325
(R)-(+)-1,1'-Bi(2-naphthol) (R)-(+)-1,1′-联(2-萘酚)
99% 100g 1,060
96-99 %
Innochem 563711
500g 2,200
Alfa 246806
(S)-(-)-1,1'-Bi(2-naphthol)
99% 1g 613
SH-CN BJ-CN CN
中国国内现货 0
Alfa 246806
(S)-(-)-1,1'-Bi(2-naphthol)
99% 5g 1,542
SH-CN BJ-CN CN
中国国内现货 0
Alfa 246806
(S)-(-)-1,1'-Bi(2-naphthol)
99% 25g 6,579
BJ-CN CN
中国国内现货 0
TCI 271355
( S )-(-)-1,1'-Bi-2-naphthol >
>98.0%(HPLC)(T) 5g 780
SH-CN TJ-CN BJ-CN TK-JP
中国国内现货 99
TCI 271355
( S )-(-)-1,1'-Bi-2-naphthol >
>98.0%(HPLC)(T) 25g 2,750
SH-CN BJ-CN TK-JP
中国国内现货 99
J&K 308862
(S)-(-)-1,1'-Bi-2,2'-naphthol, 99%
99% 1g 74
HB
中国国内现货 99
J&K 308862
(S)-(-)-1,1'-Bi-2,2'-naphthol, 99%
99% 5g 92
HB
中国国内现货 99
J&K 308862
(S)-(-)-1,1'-Bi-2,2'-naphthol, 99%
99% 25g 184
HB
中国国内现货 99
Matrix 66873
(S)-(-)-1,1'-Bi-2-naphthol
95+% 25g 169
BJ-CN
中国国内现货 99
Matrix 66873
(S)-(-)-1,1'-Bi-2-naphthol
95+% 100g 528
BJ-CN
中国国内现货 99
Acros 279182
(S)-(-)-1,1'-Bi-2-naphthol, 99%
1g 315
99
Acros 279182
(S)-(-)-1,1'-Bi-2-naphthol, 99%
5g 1,077
99
Acros 279182
(S)-(-)-1,1'-Bi-2-naphthol, 99%
25g 3,364
99
Apollo 381479
(R)-2,2'-Dihydroxy-[1,1']-binaphthyl
25g 550
0
TRC 532952
rac-[1,1'-Binaphthalene]-2,2'-di…
1g 1,200
0
TRC 532952
rac-[1,1'-Binaphthalene]-2,2'-di…
10g 1,680
0
TRC 532952
rac-[1,1'-Binaphthalene]-2,2'-di…
50g 2,280
0
Energy-chemical 558273
(S)-(-)-1,1'-Bi-2-naphthol S-1,1'-联-2-萘酚
99% 5g 55
CN-BJ CN-SH
中国国内现货 96-99 %
Energy-chemical 558273
(S)-(-)-1,1'-Bi-2-naphthol S-1,1'-联-2-萘酚
99% 25g 129
CN-SH
中国国内现货 96-99 %
Energy-chemical 558273
(S)-(-)-1,1'-Bi-2-naphthol S-1,1'-联-2-萘酚
99% 100g 365
CN-BJ CN-SH
中国国内现货 96-99 %
Energy-chemical 558273
(S)-(-)-1,1'-Bi-2-naphthol S-1,1'-联-2-萘酚
99% 500g 1,580
CN-BJ CN-SH
中国国内现货 96-99 %
Shao Yuan 561662
(S)-(-)-1,1’-Bi-2-naphthol (S)-1,1’-联-2-萘酚
98% 97+% 1g 65
SH-CN
中国国内现货 96-99 %
Shao Yuan 561662
(S)-(-)-1,1’-Bi-2-naphthol (S)-1,1’-联-2-萘酚
98% 97+% 5g 97
SH-CN
中国国内现货 96-99 %
Shao Yuan 561662
(S)-(-)-1,1’-Bi-2-naphthol (S)-1,1’-联-2-萘酚
98% 97+% 25g 155
SH-CN
中国国内现货 96-99 %
Shao Yuan 561662
(S)-(-)-1,1’-Bi-2-naphthol (S)-1,1’-联-2-萘酚
98% 97+% 100g 387
SH-CN
中国国内现货 96-99 %
Shao Yuan 561662
(S)-(-)-1,1’-Bi-2-naphthol (S)-1,1’-联-2-萘酚
98% 97+% 500g 1,355
SH-CN
中国国内现货 96-99 %
Ark 563712
98% 10g 80
SH-CN BJ-CN
中国国内现货 96-99 %
Ark 563712
98% 25g 144
SH-CN BJ-CN
中国国内现货 96-99 %
Ark 563712
98% 100g 440
SH-CN BJ-CN
中国国内现货 96-99 %
Ark 563712
98% 500g 1,680
SH-CN BJ-CN
中国国内现货 96-99 %
Ark 563712
98% 1000g 3,040
SH-CN BJ-CN
中国国内现货 96-99 %
Strem 563713
S-(-)-1,1'-Bi-2-naphthol, 99% (S)-BINOL
99% 1g 480
96-99 %
Strem 563713
S-(-)-1,1'-Bi-2-naphthol, 99% (S)-BINOL
99% 5g 1,260
96-99 %
Strem 563713
S-(-)-1,1'-Bi-2-naphthol, 99% (S)-BINOL
99% 25g 5,010
96-99 %
TRC 563715
(1S)-[1,1'-Binaphthalene]-2,2'-diol
5g 1,100
TRC 563715
(1S)-[1,1'-Binaphthalene]-2,2'-diol
25g 3,500
TRC 563715
(1S)-[1,1'-Binaphthalene]-2,2'-diol
100g 9,750
Apollo 564308
(S)-2,2'-Dihydroxy-[1,1']-binaphthyl
5g 308
Apollo 564308
(S)-2,2'-Dihydroxy-[1,1']-binaphthyl
25g 462
Adamas 570060
99%+ 1g 44
SH-CN BJ-CN
中国国内现货 96-99 %
Adamas 570061
99%+ 5g 70
SH-CN BJ-CN
中国国内现货 96-99 %
Adamas 570062
99%+ 25g 170
SH-CN BJ-CN
中国国内现货 96-99 %
Adamas 570063
99%+ 100g 520
SH-CN BJ-CN
中国国内现货 96-99 %
Acros 590405
99% 1g 245
96-99 %
Acros 590405
99% 5g 838
96-99 %
Acros 590405
99% 25g 2,617
96-99 %
Aladdin 638644
1g 41
SH-CN BJ-CN
中国国内现货
Aladdin 638645
5g 54
SH-CN BJ-CN
中国国内现货
Aladdin 638646
25g 128
SH-CN BJ-CN
中国国内现货
Aladdin 638647
100g 361
SH-CN
中国国内现货
Acros 735786
1g 318
Acros 735787
5g 1,090
Acros 735788
25g 3,402
Aladdin 735789
500g 1,564
BJ-CN
中国国内现货
Accela 735790
1g 35
BJ-CN
中国国内现货
Accela 735790
5g 54
BJ-CN
中国国内现货
Accela 735790
10g 59
BJ-CN
中国国内现货
Accela 735790
25g 119
BJ-CN
中国国内现货
Accela 735790
100g 361
BJ-CN
中国国内现货
Accela 735790
500g 1,404
Aldrich 735794
1g 437
Aldrich 735797
5g 1,158
Aldrich 735798
25g 4,833
Key Organics 735799
250g 2,895
药明康德 735800
100g 562
Key Organic 854694
S-(-)-1,1'-Bi-2-Naphthol
>97% 250g 2,895
96-99 %

分类

  • Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Other Ligands
  • {SNA} Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Polyols

相关文献及参考

  • Merck: 14,1226
  • Forms a complex with lithium aluminum hydride, useful for the asymmetric reduction of ketones: J. Am. Chem. Soc., 101, 3129, 5843 (1979); alkynyl alcohols: Tetrahedron Lett., 22, 247 (1981); or steroidal enones: J. Chem. Soc., Chem. Commun., 115 (1981).
  • For diastereoselective alkyation of
  • The complex with diisopropoxytitanium dichloride catalyzes the "glyoxylate ene reaction", in which glyoxylate ester adds to alkenes in a highly stereospecific manner: J. Am. Chem. Soc., 111, 1940 (1989):
  • See also (R)-(+)-2,2'-Bis(diphenyl­phosphino)-1,1'-binaphthyl­, B23785.
  • Chiral precursor of various reagents used in enantioselective syntheses.
  • In combination with Titanium(IV)­ isopropoxide, A13703, catalyzes the asymmetric allylation of aldehydes using allylstannanes to give chiral homoallylic secondary alcohols: J. Am. Chem. Soc., 115, 8467 (1993). The same transformation has also been achieved using the dichlorotitanium complex: J. Am. Chem. Soc., 115, 7001 (1993).
  • See also (R)-(+)-2,2'-Bis(diphenyl­phosphino)-1,1'-binaphthyl­, B23785.
  • Used in combination with 2-Formyl­benzeneboronic acid, B25434 in a protocol for determining the enantiomeric excess of primary amines by NMR: Org. Lett., 8, 609
  • Merck: 14,1226 Beilstein:6,1051
  • Merck 14 ,1226
  • Forms a chiral boron-containing Lewis acid which has been used in asymmetric Diels-Alder reactions: Tetrahedron, 49, 1749 (1993); J. Am. Chem. Soc., 115, 1151 (1993).
  • For further example usingɑ-Methyl­styrene, L03609, see: Org. Synth. Coll., 9, 596 (1998).

安全信息

Warnings
  • IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment
  • Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes
  • T
RTECSDU3106100
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261305+351+338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 如果食入:立即呼叫中毒控制中心或医生/医师。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P302+350 IF ON SKIN: Gently wash with plenty of soap and water. 如果在皮肤上:轻轻地用大量肥皂和水清洗
  • P308+313 IF exposed or concerned: Get medical advice/attention. 如接触到或有疑虑:求医/就诊。
  • P302+352+332+313+362+364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P301+310305+351+338
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P201202264270280301+310+330302+352+332+313+362+364305+351+338+337+313
  • P305+351+338+337+313
  • P301+310+330
  • P405 Store locked up. 上锁保管。
Signal word
  • Danger
UN Number
  • UN 2811 6.1/PG 3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R25 Toxic if swallowed 吞咽有毒
  • R36 Irritating to eyes 刺激眼睛
Packing GroupIII
Hazard Class6.1
Storage condition
  • 2-8°C
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 42 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 14,111,1985

其他信息

  • 可燃性危险特性:可燃; 燃烧产生刺激烟雾
  • 储运特性:通风低温干燥; 与库房食品原料分开存放
  • 存储注意事项:湿度敏感;氮气保护
  • Sigma Aldrich:602-09-5(sigmaaldrich)
  • 不溶于水,微溶于醋酸和乙醇。
  • MSDS 信息:2,2'-Dihydroxy-1,1'-binaphthyl(602-09-5).msds
  • 海关编码:29072900
  • 毒性分级:高毒
  • 1,1'-联-2-萘酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0461 1,1'-联-2-萘酚 1,1'-Bi-2-naphthol 5G 366元 2014/06/02 B0461 1,1'-联-2-萘酚 1,1'-Bi-2-naphthol 25G 995元 2010/06/21 147350050 1,1'-联-2-萘酚 1,1'-Bi-2-naphthol 99% 5 GR 388元
  • 图谱信息:1,1'-联-2-萘酚(602-09-5)核磁图( 13 CNMR) 1,1'-联-2-萘酚(602-09-5)红外图谱(IR2) 1,1'-联-2-萘酚(602-09-5)核磁图( 1 HNMR) 1,1'-联-2-萘酚(602-09-5)红外图谱(IR1) 1,1'-联-2-萘酚(602-09-5)质谱(MS)
  • 检测方法:HPLC
  • MOL 文件:602-09-5.mol
  • TCI Shanghai:1,1'-联-2-萘酚 1,1'-Bi-2-naphthol,>;99.0%(GC)(602-09-5)
  • Acros Organics:1,1'-联-2-萘酚 1,1'-Bi-2-naphthol, 99%(602-09-5)
  • F:10
  • 用途一:手性拆分剂,广泛用于手性液晶,药物,香料,农药的手性合成。
  • 类别:有毒物品
  • 急性毒性:口服-小鼠 LDL0: 42 毫克/公斤
  • 下游产品:1,1'-联萘-2,2'-双二苯膦 --> 联萘二溴
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • Alfa Aesar:(±)-1,1-联萘酚,99% (+/-)-1,1'-Bi(2-naphthol), 99%(602-09-5)

化学结构图

CAS 18531-99-2  MFCD00004068
SMILES:

化学属性

Mol. FormulaHOC10H6C10H6OH
Mol. Weight286.32
Melting Point208-210 °C(lit.)
TSCANo
Density1.301
Solubilitydioxane: 50 mg/mL, clear

别名和识别编码

Chemical Name(R)-(+)-1,1'-Bi(2-naphthol)
CAS Number18531-99-2
Alfabeta NameBINAPHTHOL S112(())------,'
MDL NumberMFCD00004068
Synonym
  • 1,1'-聯(2-萘酚)
  • 联萘酚
  • (+)-2,2′-二羟基-1,1′-联萘 (R)-(+)-1,1′-联萘-2,2′-二醇 (R)-BINOL
  • 2,2'-二羥-1,1'-聯萘
  • (S)-(-)-1,1′-联(2-萘酚)
  • (R)-(+)-1,1′-联(2-萘酚)
  • R-联萘酚
  • (±)-1,1′-联萘-2,2′-二醇 (±)-2,2′-二羟基-1,1′-联萘
  • (+/-)-1,1'-BI(2-NAPHTHOL)
  • (S)-(-)-BINOL
  • AURORA KA-7212
  • 1,1′-联-2-萘酚
  • Bis-beta-naphthol
  • (S)-(-)-1,1′-联萘-2,2′-二醇
  • 2,2'-Dihydroxybinaphthalene
  • (-)-2,2′-二羟基-1,1′-联萘
  • (±)-1,1′-联萘-2,2′-二醇 (±)-2,2′-二羟基-1,1′-联萘 2,2'-Dihydroxybinaphthalene 2,2'-Dihydroxydinaphthyl 2,2'-Dinaphthol BINOL
  • 2,2'-Dinaphthol
  • (S)-BINOL
    PubChem Substance ID 24854838
    Beilstein Registry Number4296068
    Reaxys-RN997518
    Merck Number14,1226
    EC Number210-014-0
    Chemical Name Translation(R)-(+)-1,1′-联(2-萘酚)
    InChIKeyPPTXVXKCQZKFBN-UHFFFAOYSA-N
    LabNetwork Molecule IDLN00009837

    系列性分类


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