Tetrakis(2,4-pentanedionato)zirconium(IV) 乙酰丙酮锆

CAS 17501-44-9 MFCD00000036

化学结构图

17501-44-9
SMILES: CC(=O)/C=C(/C)\O[Zr](O/C(/C)=C\C(C)=O)(O/C(/C)=C\C(C)=O)O/C(/C)=C\C(C)=O

化学属性

Mol. FormulaZr(C5H7O2)4
Mol. Weight488
Density1.415
TSCAYes
Melting Point191
Stability易吸潮

别名和识别编码

Chemical NameTetrakis(2,4-pentanedionato)zirconium(IV)
CAS Number17501-44-9
EC Number241-510-5
Beilstein Registry Number4160373
MDL NumberMFCD00000036
PubChem Substance ID87577924
Synonym Zirconium, tetrakis(2,4-pentanedionato-O,O')-, (SA-8-11''11''1'1'''1'1''')- Zirconium acetylacetonate Tetrakis(acetylacetonato)-zirkon (IV) AC 150 tetrakis(2,4-pentanedionato-O,o')zirconium Zirconium(IV) acetylacetonate 2,4-Pentanedione, zirconium complex Zirconium (IV) 2,4-pentanedionate 四(2,4-戊二酮)锆 Tetrakis(2,4-pentanedionato)zirconium Zirconium tetrakis(acetylacetonate) Orgatix ZC 150 Tetrakis(acetylacetonato)zirconium(IV) 乙酰基丙酮锆,四(2 Nacem Zirconium Tetrakisacetylacetonatozirconium Zirconium, acetyl-, acetonate zirconium, tetrakis(2,4-pentanedionato-O,o')- ZR 181 Zirconium acetylacetonateTet
Chemical Name Translation乙酰丙酮锆
Wiswesser Line Notation1V1V1 2 &-ZR-
LabNetwork Molecule IDLN00192919
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分类

  • {uni_hamburg} no charge; ketone; 5fragments; ionic
  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Zirconium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Zirconium, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Zirconium

产品应用

  • 金属内消旋锆的起始物质。

相关文献及参考

  • Short: III/10b
  • Short: EINECS
  • Short: IV/8A
  • Beilstein: 1,IV,3672
  • Short: II/2

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSZH9280000
Hazard statements
  • H302+H312+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Ocular
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Sense Organs and Special Senses (Eye) - corneal damage
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD441-640

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 316 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD441-640

其他信息

  • The starting material for zirconium metallomesogens: zirconium tetrakis-β-diketonate liquid crystals.

系列性分类