Chloromethyl Ethyl Ether 氯甲基乙基醚

CAS 3188-13-4 MFCD00000887

化学结构图

3188-13-4
SMILES: CCOCCl

化学属性

Mol. FormulaC₃H₇ClO
Mol. Weight94.54
Refractive index1.4030 to 1.4050
Boiling Point
Density1.019
Flash Point7°C
Solubility溶于多数有机溶剂。
Melting PointN/A

别名和识别编码

Chemical NameChloromethyl Ethyl Ether
CAS Number3188-13-4
PubChem Substance ID18523
EC Number221-687-5
MDL NumberMFCD00000887
Beilstein Registry Number1(4)3047
Reaxys-RN906702
Synonym (Chlormethyl)-ethylether (chloromethoxy)-ethan (chloromethoxy)ethane 1-(Chloromethoxy)ethane 1-氯甲基乙基醚 CHLOROMETHYL ETHYL ETHER Chlorethylmethylether Chlormethoxyethan Chlormethylethylether Chloromethoxyethane Chloromethyl Ethyl Ether 90% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation氯甲基乙基醚
LabNetwork Molecule IDLN00198824
InChIInChI=1S/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3
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分类

  • {Chemicalbook} 农药中间体: 除草剂中间体: 酰胺类除草剂
  • Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {SNA} Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Other Protecting and Derivatizing Reagents, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

相关文献及参考

  • Aldrich MSDS 1 , 417:A / Corp MSDS 1 (1), 803:C / FT-IR 2 (1), 311:B / FT-IR 1 (1), 209:C / FT-NMR 1 (1), 327:A / IR-Spectra (2), 116:C / IR-Spectra (3), 126:H / NMR-Reference 2 (1), 179:A / RegBook 1 (1), 215:E / Sax 6 , 737 / Sigma FT-IR 1 (2), 382:C / Structure Index 1 , 29:E:8 / Vapor Phase 3 , 273:C
  • Beil. 1 ,581
  • Fieser 12 ,116 / Fieser 13 ,75
  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,Xn
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302+H312+H332
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P370+P378
  • P403+P235
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P308+P313
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P378 Use … for extinction. 使用...灭火。
  • P235 Keep cool. 保持凉爽。
  • P403+P233
  • P301+P330+P331+P310
  • P305+P351+P338+P310
Signal word
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S29 Do not empty into drains 不要排入下水道；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number UN 2354 3/PG 2
Packing GroupII
Hazard Class3/6.1
Storage condition 0-6°C 4
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 氯甲基乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0201 氯甲基乙醚 Chloromethyl Ethyl Ether 500G 6030元 2014/06/02 C0201 氯甲基乙醚 Chloromethyl Ethyl Ether 25G 789元 2010/06/21 355720250 氯甲基乙醚 Chloromethyl ethyl ether 80%, tech., stabilized 25 ML 760元
  • 用途一:用于有机合成
  • 方法一:其制备方法是在反应釜中加入乙醇和三聚甲醛，在搅拌下通入氯化氢气体，控制反应温度，通入一定量氯化氢后，取样分析，达反应终点，静置分层，下层为盐酸，上层为氯甲基乙基醚，可蒸馏提纯。 3C 2 H 5 OH+(CH 2 O) 3 +3HCl→3ClCH 2 OC 2 H 5 +3H 2 O
  • 下游产品:乙草胺
  • MSDS 信息:氯甲基乙醚(3188-13-4).msds
  • Acros Organics:Chloromethyl ethyl ether, contains ca 12% chloroethyl methyl ether, tech., 80%(3188-13-4)
  • 可燃性危险特性:易燃; 火场放出有毒氯化物烟雾
  • Sigma Aldrich:3188-13-4(sigmaaldrich)
  • 类别:易燃液体
  • 爆炸物危险特性:遇火燃烧爆炸
  • 外观性质:无色液体。
  • TCI Shanghai:氯甲基乙醚 Chloromethyl Ethyl Ether,>;96.0%(GC)(3188-13-4)
  • 上游原料:三聚甲醛
  • 储运特性:库房低温, 通风, 干燥 ; 防火; 防震动
  • 用途二:氯甲基乙基醚是除草剂乙草胺的中间体。
  • 灭火剂:二氧化碳, 泡沫, 干粉
  • 图谱信息:氯甲基乙醚(3188-13-4)核磁图( 1 HNMR) 氯甲基乙醚(3188-13-4)质谱(MS) 氯甲基乙醚(3188-13-4)核磁图( 13 CNMR)
  • MOL 文件:3188-13-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents

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