Galvinoxyl Free Radical 加尔万氧基自由基

CAS 2370-18-5 MFCD00001616

化学结构图

2370-18-5
SMILES: CC(C)(C)C1C=C(C=C2C=C(C(=O)C(=C2)C(C)(C)C)C(C)(C)C)C=C(C=1[O])C(C)(C)C |^1:26|

化学属性

Mol. FormulaC29H41O2
Mol. Weight422
Melting Point156-160
Density1.422
TSCANo

别名和识别编码

Chemical NameGalvinoxyl Free Radical
Synonym 2,6-二叔丁基-α-(3,5-二叔丁基-4-氧-2,5-环己二烯亚基)-对甲苯氧基, 自由基 Galvinoxyl, free radical Phenoxy, 4-[[3,5-bis(1,1-dimethylethyl)-4-oxo-2,5-cyclohexadien-1-ylidene]methyl]-2,6-bis(1,1-dimethylethyl)- 2,6-Di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxy, free radical 2,6-二叔丁基-α-(3,5-二叔丁基-4-氧-2,5-环己二烯亚基)-对甲苯氧基, 自由基 Galvinoxyl free radical Galvinoxyl radical Coppinger's radical 2,6-Di-tert-butyl-4-(3,5-di-tert-butyl-4-oxocylohexa-2,5-dienylidene methyl)phenoxyl 2,6-Di-tert-butyl-alpha-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxy, free radical p-Tolyloxy, 2,6-di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)- Phenol, 2,6-di(tert-butyl)-4-[3,5-di(tert-butyl)-4-oxo-2,5-cyclohexadien-1-ylidenemethyl]-,radical ion(1-) 加尔万氧基自由基 Galvinoxyl, freies Radikal galvinoxy radical 2,6-di-tert-butyl-α-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-p-tolyloxy Coppinger's radical Galvinoxyl Galvanoxyl Phenoxy(free radical),2,6-di-t-butyl-4-[(3,5-di-t-butyl-4-oxo-2,5-cyclohexadien-1-ylidene
MDL NumberMFCD00001616
PubChem Substance ID87570247
CAS Number2370-18-5
Reaxys-RN19244296
Merck Number4357
EC Number219-133-2
Beilstein Registry Number2384789
Chemical Name Translation加尔万氧基自由基
Wiswesser Line NotationL6V DYTJ BX1&1&1 FX1&1&1 DU1R DQ BX1&1&1 FX1&1&1
LabNetwork Molecule IDLN01742398
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分类

  • {uni_hamburg} no charge; radical; carbocycle; aromatic; 6RingOnly; 6ring; ketone; 1fragment
  • {SA} Chemical Synthesis, Others, Radical Chemistry, Stable Radicals, Synthetic Reagents

相关文献及参考

  • Merck 14 ,4357
  • Fieser 1 ,409
  • Aldrich MSDS 1 , 987:D / Corp MSDS 1 (1), 1763:A / FT-IR 1 (2), 78:D / FT-IR 2 (2), 2482:B / IR-Spectra (2), 784:B / IR-Spectra (3), 896:E / RegBook 1 (2), 1683:A / Structure Index 1 , 266:B:7
  • Short: III/10b Title: Structure Data of Organic Crystals: C 16 ... C 168 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10b Year: 1985 ISBN: 3-540-13932-X ISBN: 978-3-540-13932-4 Internet Resource: DOI:10.1007/b19985 RefComment: XIX,652 pages. Hardcover
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Widely used free radical scavenger and antioxidant.

安全信息

WGK Germany3
RTECSXV7978000
Storage condition 0-10 0-10°C
Signal word Warning
GHS Symbol
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02987

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 20 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,95,1981

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. Others - Stable Radicals
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. Others - Stable Radicals
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals

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