4-Iodophenol 4-碘苯酚

CAS 540-38-5 MFCD00002327

化学结构图

540-38-5
SMILES: Oc1ccc(I)cc1

化学属性

Mol. FormulaC₆H₅IO
Mol. Weight220.01
Melting Point91-95°C
TSCAT
Boiling Point
Solubility微溶于水，易溶于醇、醚。
Density2.001
Stability对光敏感
Flash Point112.4±22.6 °C

别名和识别编码

Chemical Name4-Iodophenol
CAS Number540-38-5
Alfabeta NameIODOPHENOL 4-
MDL NumberMFCD00002327
PubChem Substance ID160870966
EC Number208-745-5
Beilstein Registry Number1904544
Reaxys-RN1904544
Merck Number5036
Synonym 4-Iodophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation4-碘苯酚
InChIKeyVSMDINRNYYEDRN-UHFFFAOYSA-N
Wiswesser Line NotationQR DI
LabNetwork Molecule IDLN00007927
InChIInChI=1S/C6H5IO/c7-5-1-3-6(8)4-2-5/h1-4,8H
Canonical SMILESOC1=CC=C(I)C=C1
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分类

  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

产品应用

  • 该品与氯乙酸缩合得到对碘苯氧乙酸。这是一种植物生长调节剂，也称增产灵；它也用于生猪的催肥增膘，因此又称肥猪灵。对碘酚还用于其他有机合成。

相关文献及参考

  • Merck:14,5036
  • Merck:14,5036 Beilstein:6,208

安全信息

Warnings 危化品目录(2015) IRRITANT, LACHRYMATOR
GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 8 C C,Xi,Xn Xn
RTECSSL5600000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Danger
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 4 Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number 3261
Packing GroupIII 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7200 mg/kg/18W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   19,413,1959

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 67,1154,1978

Restrict 危险品

其他信息

  • 毒性分级:中毒
  • 可燃性危险特性:明火可燃
  • Hazard Note:Irritant
  • Sigma Aldrich:540-38-5(sigmaaldrich)
  • 灭火剂:二氧化碳、砂土、泡沫、干粉、雾状水
  • 类别:有毒物品
  • 4-碘苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw020007 对碘苯酚 5g 120元 2011/04/16 I0311 4-碘苯酚 4-Iodophenol 25G 920元 2011/04/16 I0311 4-碘苯酚 4-Iodophenol 10G 406元
  • MSDS 信息:4-碘苯酚(540-38-5).msds
  • Alfa Aesar:4-碘苯酚,98+% 4-Iodophenol, 98+%(540-38-5)
  • 敏感性:Light Sensitive
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 上游原料:铜 --> 4-氨基苯酚
  • TSCA:T
  • 用途一:可用作消毒剂或有机合成中间体
  • MOL 文件:540-38-5.mol
  • TCI Shanghai:4-碘苯酚 4-Iodophenol,>;98.0%(GC)(540-38-5)
  • 易溶于醇和醚，难溶于水。能随水蒸气挥发，在空气中蒸馏时分解，有特殊气味。
  • 下游产品:对碘苯氧乙酸
  • 急性毒性:腹腔-小鼠 LD50: 700 毫克/公斤
  • 用途二:该品与氯乙酸缩合得到对碘苯氧乙酸。这是一种植物生长调节剂，也称增产灵；它也用于生猪的催肥增膘，因此又称肥猪灵。对碘酚还用于其他有机合成。
  • 方法一:由对氨基苯酚经重氮化、置换而得。对氨基苯酚、水和硫酸的混合液用冰冷至0℃，在搅拌下于1h内加完亚硝酸钠溶液。加毕，继续搅拌20min，再加入浓硫酸，得重氮化液。将重氮化液倒入用冰冷却过的碘化钾溶液中，再加入铜粉，并在75-80℃下搅拌，反应至无氮气放出为止。冷至室温，用氯仿萃取三次，合并萃取液，用硫代硫酸钠稀溶液洗涤。蒸馏回收氯仿。蒸余物进行减压蒸馏，收集135-140℃（61.3kPa）馏分，冷却结晶得对碘酚粗品。用稀乙醇结晶得精品。收率约70%。
  • Acros Organics:4-碘苯酚 4-Iodophenol, 99%(540-38-5)
  • 外观性质:白色或带红色针状结晶，有特殊气味。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Protected Alcohols/Phenols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers

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