Silver perchlorate 高氯酸银

CAS 7783-93-9 MFCD00003400

化学结构图

7783-93-9
SMILES: [Ag+].[O-][Cl+3]([O-])([O-])[O-]

化学属性

Mol. FormulaAgClO4
Mol. Weight207.32
Density2.8 g/mL at 25 °C(lit.)
SolubilitySoluble in water and many organic solvents (benzene, toluene, pyridine)
TSCAYes
Melting Point486 °C (lit.)

别名和识别编码

Chemical NameSilver Perchlorate
Synonym AgClO4 Perchloricacid,silver(1+)salt SILVER (I) PERCHLORATE SILVER PERCHLORATE SILVER PERCHLORATE 99.9% SILVER PERCHLORATE, ANHYDROUS REAGENT SILVER PERCHLORATE, ANHYDROUS, 97% SILVER(I) PERCHLORATE, ANHYDROUS, REAGENT: (SILBERGEHALT: 48%) Silberperchlorat Silver perchlorate Silver perchlorate (AgClO4) Silver perchlorate anhydrous Silver perchlorate, anhydrous Silver(1+) perchlorate Silver(I) perchlorate Silver(I) perchlorate, anhydrous, reagent SilverIperchlorateanhydrousreagentSilbergehalt perchloricacid,silver(1++)salt silver perchlorate {} {Chemi {} {} {Chemical {} {} {} {} {Chemicalbook} {} {} {} {} {} {Chemicalbook} {} {} {} {} {} {} {} {} {} {} {Chemi {} {} {} {} {} {} {} {} {
MDL NumberMFCD00003400
CAS Number7783-93-9
EC Number232-035-4
Merck Number14,8523
PubChem Substance ID24562
Chemical Name Translation高氯酸银
LabNetwork Molecule IDLN02144932
InChIInChI=1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts, Silver, Silver Additives, Silver Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials,

相关文献及参考

  • Short: III/7b2 Title: Crystal Structure Data of Inorganic Compounds: Key Element : O Author: Pies, W.; Weiss, A. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/7b2 Page: 1-210 Year: 1980 ISBN: 3-540-09593-4 ISBN: 978-3-540-09593-4 Internet Resource: DOI:10.1007/b19974 RefComment: 14 figs., XXV, Hardcover Abstract: Volume III/7 contains structure data on those compounds which contain at least one of the elements F, Cl, Br, I, O, N, and P and cannot be called "organic". The structure data of the remaining inorganic compounds and the elements are dealt with in volumes III/6 and III/14, while the organic compounds are treated in volumes III/5 and III/10. The systematic arrange-ment is based on the anions ordered according to "key elements", since this system allows the arrangement of the crystal structure data in such a way that both chemical and crystallographical relationships can be recognized. Structure data are compiled as completely as possible for all inorganic substances, where crystal structures have been examined by means of X-ray, neutron, and electron diffraction,and for which at least the lattice constants have been determined.
  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: IV/1b Title: Densities of Liquid Systems: Densi

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S17 Keep away from combustible material 远离可燃物料；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
UN Number UN 1481 5.1/PG 2 UN1481
Risk Statements
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R34 Causes burns 会导致灼伤
  • R50 Very toxic to aquatic organisms 对水生生物极毒
Storage condition Light Sensitive & Hygroscopic
WGK Germany3
GHS Symbol
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes O,C
Hazard Class5.1
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 下游产品:电解法合成的聚吡咯
  • 外观性质:白色结晶，有潮解性。
  • MOL 文件:7783-93-9.mol
  • 用途一:用于制造炸药。
  • Alfa Aesar:无水高氯酸银(I),anhydrous Silver perchlorate, anhydrous(7783-93-9)
  • MSDS 信息:高氯酸银(7783-93-9).msds
  • Sigma Aldrich:7783-93-9(sigmaaldrich)
  • 高氯酸银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 42209 无水高氯酸银(I), anhydrous Silver perchlorate, anhydrous 5g 357元 2010/05/25 42209 无水高氯酸银(I), anhydrous Silver perchlorate, anhydrous 25g 1610元 2010/05/25 42209 无水高氯酸银(I), anhydrous Silver perchlorate, anhydrous 100g 5782元
  • F:3-8-10
  • 敏感性:Hygroscopic
  • 上游原料:氯化银
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 455g/0℃;484g/10℃;525g/20℃;594g/30℃;635g/40℃ 793g/100℃
  • 方法一:复分解法把高氯酸钠溶液加入反应器中，与加入的氯化银加热进行复分解反应，生成高氯酸银和氯化钠，过滤除去氯化钠，将滤液蒸发浓缩，冷却结晶，再精制，经过滤，滤液经冷却结晶，离心分离，干燥，制得高氯酸银。其 NaClO4+AgCl→AgC1O4+NaCl
  • 参考质量标准:参考标准 指标名称 指标 高氯酸银(AgC1O4)含量/%≥ 99
  • 毒性:参见高氯酸钡。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Silver 银
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Perchlorates - Oxidation