• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} A-B, Puriss p.a., Analytical Reagents for General Use, Puriss p.a., 分析/色谱, 分析试剂
• {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
• {SNA} Building Blocks, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds, UV-VIS, 分析/色谱, 分析试剂
• {SA} Analytical Reagents, Analytical/Chromatography, Building Blocks, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds, UV-VIS
• {Chemicalbook} 农药

产品应用

• 农药；染料；医药的中间体。用于冰染染料色基的制造，如红色基B；红色基GL。用于磺胺药物的制造。苯磺酰氯是检定胶类的试剂。

相关文献及参考

• Short: II/25D
• Merck: 14,1072 Beilstein: 11,IV,49
• Alternatively, MgBr2 induces a ring-opening reaction leading to ß-unsaturated acids. See, e.g.: Synth. Commun., 19, 2243 (1989).
• Short: II/14a
• Merck: 14,1072
• Reacts with ß-hydroxy esters in pyridine to give ß-lactones which, at higher temperatures eliminate CO2 in a stereospecific alkene synthesis: J. Am. Chem. Soc., 94, 2000 (1972); J. Org. Chem., 39, 1322, 1650 (1974):
• Short: II/24B

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 828 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 36(6),19,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 76 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   MEPAAX Medycyna Pracy.  Industrial Medicine.  (Ars-Polona, POB 1001, 00-068
   Warsaw 1, Poland) V.1-    1950-  Volume(issue)/page/year: 20,513,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1960 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   MEPAAX Medycyna Pracy.  Industrial Medicine.  (Ars-Polona, POB 1001, 00-068
   Warsaw 1, Poland) V.1-    1950-  Volume(issue)/page/year: 20,513,1969

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF E

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 828 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/

其他信息

• 用途一:用于制磺胺药物等，也用于鉴定各种胺
• 可燃性危险特性:可燃; 遇水分解有毒氯化物气体; 燃烧产生有毒氯化物和硫氧化物烟雾
• 毒性分级:中毒
• 灭火剂:砂土、干石粉、二氧化碳
• 下游产品:4-甲苯磺酰氯 --> 4-硝基-2-甲苯胺 --> 4-甲基-2-硝基苯胺 --> 苯硫酚 --> (三氟甲基)三甲基硅烷 --> 亮丙瑞林 --> 颜料紫 23 --> 苯亚磺酸钠 --> 苯磺酰胺 --> 磺胺喹恶啉 --> 2,5-二氯吡啶 --> 2-(2-氯乙氧基)苯磺酰胺 --> 苯硫代磺酸钠 --> 柳氮磺吡啶 --> 克瘟散 --> N,N-二甲基,对十八烷基苯磺酰胺丙基铵基丙磺酸盐 --> 1-(苯磺酰)-1H-吲哚-2-甲醛 --> 2,4-二氯-5-磺酰胺基苯甲酸 --> 酸性黄79 --> 冰染重氮组分 34 --> 2-甲基-3-硝基苯胺 --> 苯磺酰肼 --> 双苯磺酰亚胺
• MSDS 信息:苯磺酰氯(98-09-9).msds
• 用途三:苯磺酰氯是一种有机合成原料，在农药上用于合成沙蚕毒类杀虫剂杀虫磺的中间体硫代苯磺酸钠，另外也是医药和染料的中间体。
• 苯磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80015128 苯磺酰氯;氯化苯磺酰;氯磺苯 500ml 34.4元 2011/04/16 B0036 苯磺酰氯 Benzenesulfonyl Chloride 25G 165元 2011/04/16 B0036 苯磺酰氯 Benzenesulfonyl Chloride 500G 355元
• 对湿敏感。不溶于水，易溶于乙醇，溶于乙醚。有腐蚀性。
• Benzenesulfonyl chloride is prepared by reaction of benzene and chlorosulfonic acid or from the sodium salt of benzenesulfonic acid and PCl5 or POCl3. It reacts with Grignard reagent from N-unsubstituted indoles to form oxindoles or substituted indoles. Benzenesulfonyl chloride is the derivatization reagent for the determination of various amines in waste water and surface water at the sub-ppb level by gas chromatography-mass spectrometry.
• 储运特性:库房通风低温干燥; 与氧化剂、H发孔剂、碱类、氰化物分开存放
• Alfa Aesar:苯磺酰氯化物,98% Benzenesulfonyl chloride, 98%(98-09-9)
• 爆炸物危险特性:在密封瓶中可爆炸;与二甲基亚砜反应爆炸; 与甲基甲酰胺反应激烈
• 用途二
• 类别:腐蚀物品
• 职业标准:STEL 1 毫克/ 立方米
• 上游原料:苯 --> 氯磺酸
• MOL 文件:98-09-9.mol
• Sigma Aldrich:98-09-9(sigmaaldrich)
• 图谱信息:苯磺酰氯(98-09-9)核磁图( 1 HNMR) 苯磺酰氯(98-09-9)红外图谱(IR1) 苯磺酰氯(98-09-9)质谱(MS) 苯磺酰氯(98-09-9)核磁图( 13 CNMR)
• 蒸气压:0.04 mm Hg ( 20 °C)
• F:21
• 急性毒性:口服- 大鼠 LD50: 1960 毫克/ 公斤; 口服- 小鼠 LD50: 828 毫克/ 公斤
• Acros Organics:苯磺酰氯 Benzenesulfonyl chloride, 96%(98-09-9)