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分类

• {Chemicalbook} 农药中间体: 除草剂中间体: 除草剂中间体
• {uni_hamburg} no charge; 1fragment
• {SNA} Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

相关文献及参考

• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
• Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
• Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standa

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   NTIS** National Technical Information Ser

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 620 mg/m3/6H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - changes in structure or function of salivary glands
   Skin and Appendages - hair
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0571119

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0571119

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 32 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 390,105,1997

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 250 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 320,165,1994

其他信息

• 用途四:甲基磺酰氯是除草剂氟磺胺草醚的中间体，还可制备甲基磺酸，用于杀菌剂烯唑醇的生产中分离异构体。
• {Chem
• Sigma Aldrich:124-63-0(sigmaaldrich)
• 用途五:本品可代替鱼油用于油鞣革或与其他鞣剂配合鞣制毛皮。并可用于轻革加脂。具有结合力强，耐溶剂，耐浣洗，渗透力强等特点。成革鞣制后可用酸性、碱性和硫化染料染色，且使成品具有较好的耐光性。
• 用途二:是生产甲磺酸的原料，用作酯化或聚合的催化剂、染色助剂及油墨、涂料的催干剂，还可用作合成医药、农药原料
• 图谱信息:甲基磺酰氯(124-63-0)红外图谱(IR1) 甲基磺酰氯(124-63-0)核磁图( 13 CNMR) 甲基磺酰氯(124-63-0)质谱(MS)
• 下游产品:1,3-丙烷磺内酯 --> 异丙烯基-2,3-二羟基-1,4-双二苯基膦丁烷 --> 4-甲磺酰胺基苯胺 --> S-烯丙醇酮 --> 3-(Boc-氨基)吡咯烷 --> 3-甲磺酰氨基苯胺 --> (2S,4S)-4-二苯基膦-2-(二苯基膦甲基)-N-叔丁氧羰基-吡咯烷 --> 1-(四氢-2H-吡喃-4-基)肼 --> 培高利特 --> 孕二烯酮 --> 5-氨基水杨酸 --> 3-甲磺酰胺基苯甲酸 --> 2-甲磺酰氨基苯硼酸 --> 甲烷磺酰基乙酸乙酯 --> 非索芬那定 --> (S)-3-叔丁氧羰基氨基吡咯烷 --> 4-氨甲基吡啶-2-氨基甲酸叔丁酯 --> 尼美舒利 --> 2-叔丁氧基甲酰氨基吡啶-4-基)甲基 甲磺酸酯 --> 雷洛昔芬 --> 司他夫定 --> S-炔丙醇酮 --> 利马前列素 --> 氨曲南 --> 安吖啶 --> 头孢卡品酯 --> 光学活性硫代乙酸胺 --> 甲磺酸甲酯 --> 石油酯,T-50,M-50 --> 甲基磺酰胺 --> 沙康唑 --> 奥沙拉嗪 --> 9Α-氟-16Α-甲基孕甾-1,4-二烯-11Β,17Α,21-三醇-3,20-二酮-21-磷酸酯哌嗪盐 --> 卤贝他索丙酸酯 --> 4-甲基磺酰胺基苯甲酸 --> 白消安 --> 2-氨基-4,5-二氟苯甲酸 --> 11Β,17Α-二羟基-21-(甲磺酰氧基)孕甾-1,4-二烯-3,20-二酮 --> 甲磺酸乙酯
• 爆炸物危险特性:遇碱可爆
• 用途一:用于染料、医药、农药等行业
• 可燃性危险特性:可燃; 遇水放出有毒氯化氢气体
• {Chemi
• 常规方法:采用塑料桶装，每桶净重20kg。
• {
• Alfa Aesar:甲磺酰氯,98% Methanesulfonyl chloride, 98%(124-63-0)
• 防护措施:
• 甲基磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80080170 甲烷磺酰氯(*)（剧毒） kg 17.6元 2011/08/23 80080128 甲烷磺酰氯(*)（剧毒） 500ml 250元 2011/08/23 80080126 甲烷磺酰氯(*)（剧毒） 100ml 180元
• 方法三:有以下几种制法。1.由硫脲经甲基化、氯氧化制得；2.由甲烷磺酸与氯化亚砜反应；3.以甲硫醇为原料，经湿式氯化反应制得。
• 防护措施:具有较强的催
• 外观性质:无色或微黄色液体。
• 灭火剂:砂土、干粉、二氧化碳
• Hazard Note:Toxic/Corrosive
• 类别:腐蚀物品
• 方法二:将液体石蜡加入反应釜，在搅拌下通入氯气和二氧化硫（1 mol︰1.2 mol）在50℃下磺氯化反应而得。 RH+SO 2 +Cl 2 →RSO 2 Cl+HCl
• 用途六:甲烷磺酰氯与具有活性氢的化合物极易反应，可用来与氨基、羟基反应，引入甲烷磺酰基。该品可作生产甲磺酸的原料，用作酯化、聚合反应的催化剂，液态二氧化硫稳定剂，蒽醌、咔唑还原染料的氯化剂，干性油油墨、涂料的速干剂，聚酯的染色改进剂，彩色照片的发色调节剂，
• MOL 文件:124-63-0.mol