4-Methoxybenzenesulfonyl Chloride 对甲氧基苯磺酰氯

CAS 98-68-0 MFCD00007446

化学结构图

98-68-0
SMILES: COc1ccc(S(=O)(=O)Cl)cc1

化学属性

Mol. FormulaC7H7ClO3S
Mol. Weight206.65
Density1.376
Boiling Point173°C at 760 mmHg
Melting Point39-42°C
Flash Point>110°(230°F)
TSCANo
Solubilitydecomposes
Stability对湿度敏感

别名和识别编码

Chemical Name4-Methoxybenzenesulfonyl Chloride
MDL NumberMFCD00007446
CAS Number98-68-0
EC Number202-692-1
Beilstein Registry Number609005
PubChem Substance ID87572801
Synonym 4-Methoxybenzenesulfonyl chloride {LY} 4-Methoxybenzenesulfonyl chloride {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxybenzenesulfonyl chloride {} {} {} {} {} {} {} {} {} {} {}
Alfabeta NameMETHOXYBENZENESULFONYLCHLORIDE 4-
Chemical Name Translation对甲氧基苯磺酰氯
Reaxys-RN609005
InChIKeyDTJVECUKADWGMO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008108
InChIInChI=1S/C7H7ClO3S/c1-11-6-2-4-7(5-3-6)12(8,9)10/h2-5H,1H3
Canonical SMILESCOC1=CC=C(S(Cl)(=O)=O)C=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds

相关文献及参考

  • Also used for protection of the guanidino function of arginine residues in peptide synthesis. The sulfonamide is cleaved by triflic acid under less drastic conditions than tosyl groups: Chem. Pharm. Bull., 24, 1568 (1976). Compare also 4-Methoxy-2,3,6-trimethyl­benzenesulfonyl­ chloride, L11829. See Appendix 6.
  • Amines and other N-functions can be protected as 4-methoxybenzenesufonyl (PMBS, Mps) derivatives: Chem. Pharm. Bull., 29, 2592 (1981), useful for the imidazole in histidines, stable to TFA and HBr/AcOH: Bull. Chem. Soc. Jpn., 47, 3146 (1974); J. Org. Chem., 45, 547 (1980); deprotection in TFA is promoted by dimethyl sulfide: J. Chem. Soc., Chem. Commun., 955 (1979). For deprotection of PMBS-indoles using Mg in methanol, see: J. Org. Chem., 62, 6519 (1997).
  • Beilstein:11,243

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupII
UN Number 3261 UN 3261 8/PG 2
Storage condition 2-8°C {LY} 2-8°C 4°C保存 Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Warnings IRRITANT
Hazard Codes 8 C
Hazard Class8

其他信息

  • 水中分解
  • MOL 文件:98-68-0.mol
  • MSDS 信息:4-Methoxybenzene-1-sulfonyl chloride(98-68-0).msds
  • Sigma Aldrich:98-68-0(sigmaaldrich)
  • 用途一:用作医药中间体
  • 图谱信息:对甲氧基苯磺酰氯(98-68-0)质谱(MS) 对甲氧基苯磺酰氯(98-68-0)红外图谱(IR1) 对甲氧基苯磺酰氯(98-68-0)红外图谱(IR2)
  • TCI Shanghai:4-甲氧基苯磺酰氯 4-Methoxybenzenesulfonyl Chloride,>;95.0%(GC)(T)(98-68-0)
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:4-甲氧基苯磺酰氯,98+% 4-Methoxybenzenesulfonyl chloride, 98+%(98-68-0)
  • F:10-21
  • Acros Organics:4-甲氧基苯磺酸氯 4-Methoxybenzenesulfonyl chloride, 99%(98-68-0)
  • 对甲氧基苯磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0802 4-甲氧基苯磺酰氯 4-Methoxybenzenesulfonyl Chloride 25G 509元 2014/06/02 M0802 4-甲氧基苯磺酰氯 4-Methoxybenzenesulfonyl Chloride 500G 4370元 2010/06/21 125735000 对甲氧基苯磺酰氯 4-Methoxybenzenesulfonyl chloride 99% 500 GR 5841元
  • Hazard Note:Corrosive/Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonates/Sulfinates - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonium/Sulfoxonium Compounds
  1. sulfonyl halide

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