Indium(III) Chloride 三氯化铟(III)

CAS 10025-82-8 MFCD00011058

化学结构图

10025-82-8
SMILES: Cl[In](Cl)Cl

化学属性

Mol. FormulaInCl3
Mol. Weight221
Density3.46 g/mL at 25 °C(lit.)
Melting Point586°
SolubilitySoluble in water
TSCAYes
Boiling Point800°
Flash Point300°C subl.

别名和识别编码

Chemical NameIndium(III) Chloride
Synonym Trichloroindium Indium(III) chloride, anhydrous Indium trichloride Indium(III)-chlorid wasserfrei 三氯化铟 Indium(III) chloride Indium trichloride; Indium (III) chloride Indium chloride (InCl3) indium (III) chloride Indium-III-chlorid Indium(III)-chlorid
CAS Number10025-82-8
PubChem Substance ID87561613
EC Number233-043-0
MDL NumberMFCD00011058
Merck Number4958
Chemical Name Translation三氯化铟(III)
InChIKeyPSCMQHVBLHHWTO-UHFFFAOYSA-K
Reaxys-RN3903075
Wiswesser Line NotationIN G3
LabNetwork Molecule IDLN01239347
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分类

  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, In, Indium, Indium Salts, Materials Science, Metal and Ceramic Science, Salts, Ultra-High Purity Materials
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Indium,

相关文献及参考

  • The combination with NaBH4 has been reported to be an effective radical reducing system, replacing the environmentally unfavorable TBTH (Tri-n-butyl­tin hydride, A13298), e.g. in dehalogenation and cyclization reactions: J. Am. Chem. Soc., 124, 906 (2002).
  • For a brief feature on InCl3, see: Synlett, 531 (2002). For reviews of the use of In compounds in organic synthesis, see: Eur. J. Org. Chem., 2347 (2000); J. Chem. Soc., Perkin 1, 3015 (2000).
  • In combination with Triethyl­silane, A10320 and a radical initiator
  • Promotes efficient azidolysis of ɑß-epoxy carboxyl derivatives in water at pH 4, with results superior to Yb(OTf)3 or Sc(OTf)3: J. Org. Chem., 66, 3554 (2001).
  • Short: II/25A
  • Short: IV/1a
  • In combination with a dithiol, catalyzes the efficient transthioacetalization of acetals to dithioacetals: Synlett, 727 (2002).
  • Short: IV/1b
  • Catalyst for conjugate addition of indoles to electron-deficient alkenes: Synthesis, 2165 (2001):
  • Mild, water tolerant Lewis acid catalyst, e.g. in allylation reactions of sensitive aldehydes with allyltributyltin: J. Org Chem., 61, 105 (1996). The allylstannane can also be generated in situ from the allyl halide in water: Tetrahedron Asym., 7, 1535 (1996). Catalyzes the Mukaiyama aldol reaction, under either solvent-free conditions: Tetrahedron Lett., 39, 1579 (1998), or in water: Chem. Commun., 1819 (1996); 861 (1998); Tetrahedron Lett., 38, 3465 (1997). For Diels-Alder reactions in water, see: Chem. Commun., 2315 (1996).
  • Indium enolates are readily formed by transmetallation of Li enolates. These undergo Reformatsky-type reactions with aldehydes to give ß-hydroxy esters. ɑ-Bromo enolates give Darzens-type ɑß-epoxy carbonyl compounds: J. Chem. Soc., Perkin 1, 825 (2000).
  • Aldoximes can be dehydrated to nitriles; ketoximes undergo the Beckmann rearrangement to amides: Chem. Commun., 1196 (2000).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes C
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSNL1400000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P308+P313
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P304+P340
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P301+P330+P331
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P308+P311
  • P304+P340+P310
  • P303+P361+P353+P310+P363
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
UN Number 3260 UN3260
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R22 Harmful if swallowed 吞咽有害
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
Storage condition Hygroscopic
Packing GroupII
Hazard Class8
TYPE OF TEST            : LD50 - Lethal

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 30(10),28,1965

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 60 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

{h

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2370 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NIIRDN Drugs in Japan (Ethical Drugs).  (Yakugyo Jiho Co., Ltd., Tokyo,
   Japan)  Volume(issue)/page/year: -,136,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 11900 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NIIRDN Drugs in Japan (Ethical Drugs).  (Yakugyo Jiho Co., Ltd., Tokyo,
   Japan)  Volume(issue)/page/year: -,136,1990

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATI

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Mammal - species unspecified Lymphocyte
DOSE/DURATION           : 40 umol/L
REFERENCE :
   JCHODP Journal of Clinical Hematology and Oncology.  (Cancer Center at
   Wadley Institutes, POB 35988, Dallas, TX 75235)  V.5(3)-    1975-
   Volume(issue)/page/year: 7,411,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 2500 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   27,140,1995

系列性分类


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