Triphenyl(Prop-2-Yn-1-Yl)Phosphonium Bromide 三苯基(丙-2-炔-1-基)溴化鏻
CAS 2091-46-5 MFCD00011811
化学结构图
SMILES: C#CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]
化学属性
| Mol. Formula | C21H18BrP |
|---|---|
| Mol. Weight | 381.25 |
| Melting Point | 177-182° |
| TSCA | No |
别名和识别编码
| Chemical Name | Triphenyl(Prop-2-Yn-1-Yl)Phosphonium Bromide |
|---|---|
| Synonym | 2-PROPYNYLTRIPHENYLPHOSPHONIUM BROMIDE PROPARGYLTRIPHENYLPHOSPHONIUM BROMIDE TRIPHENYLPROPARGYLPHOSPHONIUM BROMIDE prop-2-ynyltriphenylphosphonium bromide 三苯基炔丙基溴化膦 TRIPHENYL(2-PROPYNYL)PHOSPHONIUM BROMIDE Triphenylpropargylphosphonium bromide triphenyl-2-propyn-1-ylphosphonium bromide PROPARGYLTRIPHENYHLPHOSPHONIUM BROMIDE 炔丙基三苯基溴化 Triphenylpropargylphosphonium bromideTriphenyl-2-propyn-1-ylphosphonium bromide 2-PROPINYL-TRIPHENYLPHOSPHONIUM BROMIDE PROPARGYLTRIPHENYLPHOSPHONIUM BROMIDE, 9 8% 炔丙基三苯基溴化膦 PROPARGYLTRIPHENYLPHOSPHONIUM BROMIDE,99+% (2-propyn-1-yl)triphenylphosphonium bromide |
| Beilstein Registry Number | 3579775 |
| PubChem Substance ID | 2724214 |
| CAS Number | 2091-46-5 |
| EC Number | 218-242-2 |
| MDL Number | MFCD00011811 |
| Reaxys-RN | 3579775 |
| Chemical Name Translation | 三苯基(丙-2-炔-1-基)溴化鏻 |
| InChIKey | QDHIFHBNARALLI-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01746301 |
| InChI | InChI=1S/C21H18P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h1,3-17H,18H2;1H/q+1;/p-1 |
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分类
- {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- Fieser 6 ,494
- Aldrich MSDS 1 , 1543:D / Corp MSDS 1 (2), 2954:C / FT-IR 2 (3), 4050:B / FT-IR 1 (2), 950:C / FT-NMR 1 (3), 539:C / RegBook 1 (2), 2717:A / Structure Index 1 , 428:D:1
- Precursor of enynes by the Wittig reaction: Liebigs Ann. Chem., 682, 62 (1965); J. Org. Chem., 42, 200 (1977); see Appendix 1.
- Readily undergoes additions with nucleophiles, e.g. alcohols or amines, to give 2-alkoxy or 2-alkylamino propenyl phosphonium salts. In these reactions, the reactive species is the allenic isomer, propadienyl triphenylphosphonium bromide: J. Org. Chem., 42, 200 (1977). By using a chiral alcohol, the subsequent base-promoted Wittig reaction with carbonyl compounds yields amino or alkoxy dienes which undergo face-selective Diels-Alder additions to dienophiles: J. Chem. Soc., Chem. Commun., 1785 (1995):
- Precursor of enynes by the Wittig reaction: Liebigs Ann. Chem., 682, 62 (1965); J. Org. Chem., 42, 200 (1977); see Appendix 1.
- Readily undergoes additions with nucleophiles, e.g. alcohols or amines, to give 2-alkoxy or 2-alkylamino propenyl phosphonium salts. In these reactions, the reactive species is the allenic isomer, propadienyl triphenylphosphonium bromide: J. Org. Chem., 42, 200 (1977). By using a chiral alcohol, the subsequent base-promoted Wittig reaction with carbonyl compounds yields amino or alkoxy dienes which undergo face-selective Diels-Alder additions to dienophiles: J. Chem. Soc., Chem. Commun., 1785 (1995):
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P312+P330
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P312
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
其他信息
- MOL 文件:2091-46-5.mol
- 炔丙基三苯基溴化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1438 炔丙基三苯基溴化膦 Triphenylpropargylphosphonium Bromide 5G 396元 2014/06/02 P1438 炔丙基三苯基溴化膦 Triphenylpropargylphosphonium Bromide 25G 1130元 2010/05/25 A12753 炔丙基三苯基溴化膦 97% Propargyltriphenylphosphonium bromide, 97% 25g 1358元
- Sigma Aldrich:2091-46-5(sigmaaldrich)
- Alfa Aesar:炔丙基三苯基溴化膦97% Propargyltriphenylphosphonium bromide, 97%(2091-46-5)
- 图谱信息:炔丙基三苯基溴化膦(2091-46-5)核磁图( 13 CNMR) 炔丙基三苯基溴化膦(2091-46-5)质谱(MS) 炔丙基三苯基溴化膦(2091-46-5)红外图谱(IR2) 炔丙基三苯基溴化膦(2091-46-5)核磁图( 1 HNMR) 炔丙基三苯基溴化膦(2091-46-5)红外图谱(IR1)
- 敏感性:Hygroscopic
- TCI Shanghai:炔丙基三苯基膦溴 Triphenylpropargylphosphonium Bromide,>;98.0%(T)(2091-46-5)
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