Bromanil 四溴对苯醌

CAS 488-48-2 MFCD00013785

化学结构图

488-48-2
SMILES: O=C1C(Br)=C(Br)C(=O)C(Br)=C1Br

化学属性

Mol. FormulaC6Br4O2
Mol. Weight423.68
Melting Point292-294°C
TSCANo
Stability对光敏感
Boiling Point340.5 °C at 760 mmHg

别名和识别编码

Chemical NameBromanil
CAS Number488-48-2
Alfabeta NameTETRABROMOBENZOQUINONE 14--,
MDL NumberMFCD00013785
Synonym 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {} {} {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {} {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {} {} {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione
PubChem Substance ID68101
EC Number207-679-4
Beilstein Registry Number1912183
Reaxys-RN1912183
Chemical Name Translation四溴对苯醌
InChIKeyLWHDQPLUIFIFFT-UHFFFAOYSA-N
LabNetwork Molecule IDLN00156215
InChIInChI=1S/C6Br4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11
Canonical SMILESBrC1=C(Br)C(=O)C(Br)=C(Br)C1=O
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分类

  • Inhibitors
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ketone; 1fragment

产品应用

  • A halogenated benxoquinone that is an effective inhibitor of photosynthetic electron transport through the spinach photosystem II and the cytochrome b6/f-complex.

相关文献及参考

  • Beilstein:7,604
  • High-potential quinone, compare p-Chloranil, A13495, useful e.g. in dehydrogenation reactions.
  • Oettmeier, W. et al.: Biochim. Biophys. Acta, Bioenerg., 890, 260 (1987); Soll, H.J. et al.: Adv. Photosynth. Res. Proc. Int. Congr. Photosynth., 4, 5 (1984);
  • Short: II/27C
  • Short: III/20b
  • {

安全信息

Warnings IRRITANT
RTECSDK6772500
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xi
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 5,144,1953

其他信息

  • TCI Shanghai:四溴对苯醌 Bromanil,>;98.0%(T)(488-48-2)
  • Acros Organics:四溴对苯醌 Tetrabromo-p-benzoquinone, 95%(488-48-2)
  • Sigma Aldrich:488-48-2(sigmaaldrich)
  • 四溴对苯醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0617 四溴对苯醌 Bromanil 5G 465元 2014/06/02 T0617 四溴对苯醌 Bromanil 25G 1310元 2010/06/21 386190050 四溴对苯醌 Tetrabromo-p-benzoquinone 95% 5 GR 973元
  • Alfa Aesar:对四溴苯醌,95% p-Bromanil, 95%(488-48-2)
  • 图谱信息:四溴对苯醌(488-48-2)红外图谱(IR1) 四溴对苯醌(488-48-2)红外图谱(IR2) 四溴对苯醌(488-48-2)质谱(MS)
  • MOL 文件:488-48-2.mol

系列性分类


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