O-p-Tolyl chlorothioformate 对甲苯基氯化亚硫代甲酸

CAS 937-63-3 MFCD00014466

化学结构图

937-63-3
SMILES: Cc1ccc(OC(=S)Cl)cc1

化学属性

Mol. FormulaC8H7ClOS
Mol. Weight187
Boiling Point245 °C(lit.)
Refractive indexn20/D 1.573(lit.)
Density1.225 g/mL at 25 °C(lit.)
Flash Point96°(204°F)
TSCANo

别名和识别编码

Chemical NameO-4-Methylphenyl chlorothioformate
CAS Number937-63-3
Alfabeta NameMETHYLPHENYLCHLOROTHIOFORMATE O4--
MDL NumberMFCD00014466
PubChem Substance ID70305
EC Number213-333-3
Beilstein Registry Number1448986
Synonym Carbonochloridothioic acid, O-(4-methylphenyl) ester P-TOLYL CHLOROTHIOFORMATE O-P-TOLYL CHLOROTHIONOFORMATE O-p-Tolyl chlorothioformate 对甲苯基氯化亚硫代甲酸 P-TOLYL CHLOROTHIONOCARBONATE Chlorothioformic acid O-(p-tolyl) ester P-TOLYL CHLOROTHIONOFORMATE Chlorothioformic acid O-p-tolyl ester O-4-METHYLPHENYL CHLOROTHIOFORMATE Chlorothioformic acid O-(4-methylphenyl) ester 4-METHYLPHENYL CHLOROTHIOFORMATE P-TOLYL CHLOROTHIONOFORMATE 97% o-(4-Methylphenyl) chloridothiocarbonate 4-TOLYLCHLOROTHIONOFORMATE Chlorothioformic acid p-tolyl ester
Chemical Name Translation对甲苯基氯化亚硫代甲酸
InChIKeyUNCAXIZUVRKBMN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116968
InChIInChI=1S/C8H7ClOS/c1-6-2-4-7(5-3-6)10-8(9)11/h2-5H,1H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiocarbonyl Compounds

相关文献及参考

  • For examples of the use of aryl chlorothionoformates in dehydration reactions by cyclic elimination of thiocarbonate esters, see Phenyl­ chlorothionoformate, L00838.

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number UN3265 UN 3265 8/PG 2
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R23 Toxic by inhalation 吸入有毒
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
Storage condition Moisture Sensitive 2-8°C
Hazard Codes T T,Xi
Hazard Class8

其他信息

  • MOL 文件:937-63-3.mol
  • 对甲苯基氯化亚硫代甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 376990010 对甲苯基氯化亚硫代甲酸 p-Tolyl chlorothionoformate 98% 1 GR 374元 2010/06/21 376990050 对甲苯基氯化亚硫代甲酸 p-Tolyl chlorothionoformate 98% 5 GR 682元 2010/05/25 B23501 对甲苯基氯化亚硫代甲酸, 97% p-Tolyl chlorothionoformate, 97% 50g 2842元
  • Alfa Aesar:对甲苯基氯化亚硫代甲酸,97% p-Tolyl chlorothionoformate, 97%(937-63-3)
  • Acros Organics:p-Tolyl chlorothionoformate, 98%(937-63-3)
  • 图谱信息:对甲苯基氯化亚硫代甲酸(937-63-3)红外图谱(IR1)
  • F:13-19
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:937-63-3(sigmaaldrich)

系列性分类


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