Tris(Trimethylsilyl)Phosphite 亚磷酸三(三甲基硅)酯

CAS 1795-31-9 MFCD00015588

化学结构图

1795-31-9
SMILES: C[Si](C)(C)OP(O[Si](C)(C)C)O[Si](C)(C)C

化学属性

Mol. FormulaC9H27O3PSi3
Mol. Weight298.54 g/mol
Refractive index1.3990 to 1.4130
Boiling Point73°C/10mmHg(lit.)
Density0.893
TSCANo
Flash Point>;230 °F

别名和识别编码

Chemical NameTris(Trimethylsilyl)Phosphite
CAS Number1795-31-9
PubChem Substance ID137213
Beilstein Registry Number2043814
MDL NumberMFCD00015588
Reaxys-RN2043814
Synonym (三甲基硅基)亚磷酸盐 PHOSPHOROUS ACID TRIS(TRIMETHYLSILYL) ESTER Phosphorous acid tri(trimethylsilyl) ester Phosphorous acid, tristrimethylsilyl Phosphorousacidtrimethylsilylester TRIS(TRIMETHYLSILYL) PHOSPHITE 95% TRIS(TRIMETHYLSILYL)PHOSPHITE TRIS(TRIMETHYLSILYL)PHOSPHITE 97+% Tris(trimethylsiloxy)phosphine Tris(trimethylsily)phosphite Tris(trimethylsilyl) Phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {SNA} 三(三甲代甲硅烷基)亚磷酸盐 三三甲基硅基亚磷酸酯 三（三甲代甲硅烷基）亚磷酸盐 亚磷酸三(三甲硅烷基)
Chemical Name Translation亚磷酸三(三甲基硅)酯
InChIKeyVMZOBROUFBEGAR-UHFFFAOYSA-N
LabNetwork Molecule IDLN01746256
InChIInChI=1S/C9H27O3PSi3/c1-14(2,3)10-13(11-15(4,5)6)12-16(7,8)9/h1-9H3
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

相关文献及参考

  • 1. M. Sekine, T. Hata J. Chem. Soc., Chem. Commun. , 285, (1978)
  • 2. M. Sekine et al. J. Org. Chem. 46 , 2097, (1981)
  • 3. L.E. Dreef et al. Tetrahedron Lett. 29 , 1199, (1988)
  • 4. L. Wozniak, J. Chojnowski Tetrahedron 45 , 2465, (1989)
  • FT-IR 2 (3), 4413:D / Structure Index 1 , 474:B:5

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
Signal word Warning {} {} {} {} {} {TCI}
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Storage condition Air & Moisture Sensitive
Packing GroupIII
Hazard Class8
UN Number 1760

其他信息

  • TCI Shanghai:亚磷酸三(三甲基硅)酯 Tris(trimethylsilyl) Phosphite,>;97.0%(T)(1795-31-9)
  • Sigma Aldrich:1795-31-9(sigmaaldrich)
  • F:10-21
  • Alfa Aesar:亚磷酸三（三甲硅烷基）,96% Tris(trimethylsilyl) phosphite, 96%(1795-31-9)
  • TSCA:No
  • 三（三甲代甲硅烷基）亚磷酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1217 亚磷酸三(三甲基硅)酯 Tris(trimethylsilyl) Phosphite 5ML 653元 2014/06/02 P1217 亚磷酸三(三甲基硅)酯 Tris(trimethylsilyl) Phosphite 25ML 2190元 2010/05/25 17159 亚磷酸三（三甲硅烷基）, 96% Tris(trimethylsilyl) phosphite, 96% 500mg 126元
  • 敏感性:Air & Moisture Sensitive
  • MOL 文件:1795-31-9.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Organic Phosphates/Phosphites - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物

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