Phenyltrimethylammonium hydroxide 苯基三甲基氢氧化铵

CAS 1899-02-1 MFCD00041899

化学结构图

1899-02-1
SMILES: C[N+](C)(C)c1ccccc1.[OH-]

化学属性

Mol. FormulaC9H15NO
Mol. Weight153.23
Flash Point11 ºC
Refractive indexn20/D 1.395
Boiling Point65 °C at 760 mmHg
Melting Point-98

别名和识别编码

Chemical NamePhenyltrimethylammonium hydroxide
MDL NumberMFCD00041899
CAS Number1899-02-1
Synonym Phenyltrimethylammonium hydroxide {LY} Phenyltrimethylammonium hydroxide {} {LY} Phenyltrimethylammonium hydroxide {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylammonium hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID15913
Beilstein Registry Number3917033
EC Number217-592-3
Reaxys-RN3917033
Chemical Name Translation苯基三甲基氢氧化铵
InChIKeyHADKRTWCOYPCPH-UHFFFAOYSA-M
Wiswesser Line Notation1K1&1&R &Q
LabNetwork Molecule IDLN01313247
InChIInChI=1S/C9H14N.H2O/c1-10(2,3)9-7-5-4-6-8-9;/h4-8H,1-3H3;1H2/q+1;/p-1
Canonical SMILESC[N+](C)(C)C1=CC=CC=C1.[OH-]
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Alkylation & Esterification
  • {SNA} Chemical Synthesis, Organic Bases,
  • {SNA} Alkylation Reagents, Amides, Amines, Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Esterification Reagents, GC Derivatization Reagents, by Application, Steroids
  • {SNA} Derivatization Reagents, Derivatization Reagents GC, Reagents for Alkylation & Esterification, 分析/色谱, 分析试剂
  • {SNA} Acids & Bases, Bases, Chemical Synthesis, Organic Bases, Synthetic Reagents

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H370 Causes damage to organs 导致器官损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P354+P338
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes F,T C F;T
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R34 Causes burns 会导致灼伤
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
UN Number
Packing GroupII
RTECSBT2275000
Hazard Class3/8 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 49 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 28,367,1926

其他信息

  • 图谱信息:三甲基苯基氢氧化铵(1899-02-1)红外图谱(IR1) 三甲基苯基氢氧化铵(1899-02-1)质谱(MS)
  • MOL 文件:1899-02-1.mol
  • 三甲基苯基氢氧化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0878 三甲基苯基氢氧化铵(20-25%的甲醇溶液) Trimethylphenylammonium Hydroxide (20-25% in Methanol) 25ML 379元 2014/06/02 P0878 三甲基苯基氢氧化铵(20-25%的甲醇溶液) Trimethylphenylammonium Hydroxide (20-25% in Methanol) 500ML 3000元 2014/06/02 P0245 苯基三甲基氢氧化铵(20-25%的甲醇溶液)[用于柱上甲基化反应] Trimethylphenylammonium Hydroxide (20-25% in Methanol) [for On-Column Methylation] 25ML 616元
  • Acros Organics:苯基三甲基氢氧化铵 Phenyltrimethylammonium hydroxide, 0.1 M in methanol(1899-02-1)
  • Sigma Aldrich:1899-02-1(sigmaaldrich)
  • TCI Shanghai:苯基三甲基氢氧化铵(20-25%的甲醇溶液)[用于柱上甲基化反应] Trimethylphenylammonium Hydroxide (20-25% in Methanol) [for On-Column Methylation](1899-02-1)
  • F:10-4.4-34

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Bases - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Alkylation & Esterification - Derivatization Reagents GC
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Alkylation & Esterification - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. GC Derivatization Reagents, by Application - Derivatization Reagents GC
  6. Amides - GC Derivatization Reagents, by Application
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents GC
  4. Reagents for Acylation
  1. Analytical & Chromatography 分析化学与色谱
  2. Gas Chromatography (GC) 气相色谱
  3. Derivatization Reagents
  4. Reagents for Acylation
  1. Functional Group 官能团索引
  2. quaternary ammonium salt

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