Boron Tribromide Dimethyl Sulfide Complex 硫化硼三溴化二甲基络合物

CAS 29957-59-3 MFCD00043296

化学结构图

29957-59-3
SMILES: C[S+](C)[B-](Br)(Br)Br

化学属性

Mol. FormulaBBr3
Mol. Weight313
Melting Point106-108 °C (lit.)
Density1.456 g/mL at 25 °C

别名和识别编码

Chemical NameBoron Tribromide Dimethyl Sulfide Complex
Synonym Boron tribromide-methyl sulfide complex 硫化硼三溴化二甲基络合物 溶液 三溴化硼-二甲基硫醚 三溴甲基硫化硼 Boron, tribromo[thiobis(methane)], (T-4)- 硫化硼三溴化二甲基络合物 Boron tribromide dimethyl sulfide complex Bortribromid-Dimethylsulfid-Komplex 三溴甲基硫化硼 三溴化硼-二甲基硫醚
MDL NumberMFCD00043296
PubChem Substance ID24854866
CAS Number29957-59-3
Chemical Name Translation硫化硼三溴化二甲基络合物
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分类

  • {SA} Chemical Synthesis, Deprotecting Reagents, Others, Protection and Derivatization, Synthetic Reagents
  • {SNA} Chemical Synthesis, Deprotecting Reagents, Other Deprotecting Reagents, Protection and Derivatization, Synthetic Reagents
  • {SNA} Chemical Synthesis, Deprotecting Reagents, Others, Protection and Derivatization,

相关文献及参考

  • 1. Tetrahedron Lett. 21 , 3731, (1980)
  • Shimizu, M.; et al. Heterocycles 73 , 191, (2007)
  • Shi, M.; Cui, S.-C. Chin. J. Chem. 20 , 277, (2002)
  • RegBook 1 (2), 3079:D / Structure Index 1 (1), 488:B:4
  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes C T
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Deprotecting Reagents - Protection and Derivatization
  5. Others - Deprotecting Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Deprotecting Reagents - Protection and Derivatization
  5. Others - Deprotecting Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfur Compounds for Organic Synthesis 有机合成硫化物

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