2,4,6-Trinitrobenzenesulfonic acid 2,4,6-三硝基苯磺酸
CAS 2508-19-2 MFCD00064382
化学结构图
SMILES: O=[N+]([O-])c1cc([N+](=O)[O-])c(S(=O)(=O)O)c([N+](=O)[O-])c1
化学属性
| Mol. Formula | C6H3N3O9S |
|---|---|
| Mol. Weight | 293.17 |
| Density | 1.14 g/mL at 20 °C |
| Refractive index | n20/D 1.431 |
| Flash Point | 58 °C |
| Melting Point | 195°C |
别名和识别编码
| Chemical Name | 2,4,6-Trinitrobenzenesulfonic acid |
|---|---|
| Synonym | 2 4 6-三硝基苯磺酸 2,4,6-TRINITOBENZENESULFONIC ACID 2,4,6-TRINITROBENZENESULFONIC ACID 2,4,6-TRINITROBENZENESULFONIC ACID SOL., 0.5 M IN ETHANOL 2,4,6-TRINITROBENZENESULPHONIC ACID 2,4,6-trinitro-benzenesulfonicaci 2,4,6-trinitrobenzenesulfonic acid solution 2,4,6-trinitrobenzenesulfonicacidsol. 2,4,6-三硝基苯磺酸 2,4,6-三硝基苯磺酸 溶液 2,4,6-三硝基苯磺酸 溶液 TNBS 2,4,6-三硝基苯磺酸溶液 Benzenesulfonic acid, 2,4,6-trinitro- PICRYLSULFONIC ACID PICRYLSULFONIC ACID HYDRATE 5% (W/V)*AQU EOUS SOLUTI PICRYLSULFONICACID,10%AQUEOUSSOLUTION PICRYLSULFONICACID,5%(W/V)SOLUTIONINMETHANOL PICRYLSULPHONICACID Picrylsulfonic acid solution TNBS TNBS,2,4,6-三硝基苯磺酸 TNBSA TNBSA溶液;TNBS Trinitrobenzene sulphonic acid TrinitrobenzoylsulfonicAcid picrylsulfonic acid hydrate 5% (W/V)*aqueous solu trinitrobenzenesulfonicacid 三硝基苯磺酸 |
| MDL Number | MFCD00064382 |
| PubChem Substance ID | 11045 |
| Beilstein Registry Number | 572358 |
| CAS Number | 2508-19-2 |
| EC Number | 219-717-7 |
| Chemical Name Translation | 2,4,6-三硝基苯磺酸 |
| LabNetwork Molecule ID | LN00338725 |
| InChI | InChI=1S/C6H3N3O9S/c10-7(11)3-1-4(8(12)13)6(19(16,17)18)5(2-3)9(14)15/h1-2H,(H,16,17,18) |
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分类
- {SNA} General Protein Quantitation, Molecular Biology, Protein Quantitation, Proteomics, Quantitation Kits and Reagents
- {SNA} Derivatization Reagents, Derivatization Reagents HPLC, Reagents for Amino Acid Analysis, Reagents for amino acid derivatisation & detection, Regents for amino acid analysis, UV-VIS, 分析/色谱, 分析试剂, 特定应用试剂
- {SNA} General Protein Quantitation, Quantitation Kits and Reagents, 分子生物学, 蛋白质定量, 蛋白质组学
- {SNA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents HPLC, Reagents for Amino Acid Analysis, Reagents for amino acid derivatisation & detection,
- {
产品应用
- 测定氨基末端，亲水性修饰化试剂，和氨基复合物的衍生物能用联氨再生，在固相多肽合成中用于检测非完全的匹配。
相关文献及参考
- 2. Takahashi, S., et al. Chem. Lett. 1 , 127, (1984)
- Beilstein: 11,III,161
安全信息
- P305+P351+P338
- P308+P313
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H312 Harmful in contact with skin 皮肤接触有害
- H319 Causes serious eye irritation 严重刺激眼睛
- H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H302 Harmful if swallowed 吞食有害
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R1 Explosive when dry 干燥时易爆
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R22 Harmful if swallowed 吞咽有害
- R25 Toxic if swallowed 吞咽有毒
- R34 Causes burns 会导致灼伤
- R11 Highly flammable 非常易燃
- R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
- R36 Irritating to eyes 刺激眼睛
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
其他信息
- Sigma Aldrich:2508-19-2(sigmaaldrich)
- TNBSA Solution is a 5% solution of trinitrobenzene sulfonic acid in methanol that reacts with primary amines (peptides or amino acids) to yield a soluble colored product, a property useful for various assay methods. Trinitrobenzene sulfonic acid (TNBSA), which reacts readily with the primary amino groups of amino acids in aqueous solution at pH 8 to form yellow adducts. No colored derivatives are formed with the secondary amino acids praline and hydroxyproline. The colored derivatives are monitored at 335 to 345nm and have extinction coefficients in the range of 10,000-15,000. TNBSA has been used as a hydrophilic modifying reagent for the detection of primary amines in samples containing amino acids, peptides or proteins. It is an excellent reagent for rapid qualitative and quantitative estimation of these biomolecules.
- TCI Shanghai:2,4,6-三硝基苯磺酸(约1%的N,N-二甲基甲酰胺溶液)[用于伯胺类的检出] Picrylsulfonic Acid (ca. 1% in N,N-Dimethylformamide) [for Detection of Primary Amines](2508-19-2)
- 用途一:测定氨基末端，亲水性修饰化试剂，和氨基复合物的衍生物能用联氨再生，在固相多肽合成中用于检测非完全的匹配。
- TNBSA Solution is a 5% solution of trinitrobenzene sulfonic acid in methanol that reacts with primary amines (peptides or amino acids) to yield a soluble colored product, a property useful for various assay methods.
- Highlights: ? TNBSA component reacts readily with primary amino groups of amino acids in aqueous format at pH 8 to form yellow adducts ? Colored derivatives are monitored at 345nm and have extinction coefficients of 10,000 to 15,000 ? Supplied as 5% solution (w/v) of TNBSA in methanol, which is easily diluted approximately 1000-fold in assay buffer for typical protein and peptide applications ? No colored derivatives are formed with secondary amino acids proline and hydroxyproline ? Applicable to solution or solid phase analysis
- Highlights:
- 2 4 6-三硝基苯磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 SP229701 2,4,
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