(1R)-(-)-(10-Camphorsulfonyl)oxaziridine (1R)-(-)-10-樟脑磺哑嗪
CAS 104372-31-8 MFCD00075428
化学结构图
SMILES: CC1(C)[C@H]2CC34ON3S(=O)(=O)C[C@]14CC2
化学属性
| Mol. Formula | C10H15NO3S |
|---|---|
| Mol. Weight | 229 |
| Melting Point | 168°C |
| TSCA | No |
| Density | 1.422 |
别名和识别编码
| Chemical Name | (1R)-(-)-(10-Camphorsulfonyl)oxaziridine |
|---|---|
| CAS Number | 104372-31-8 |
| Synonym | 2-莰烷磺内酰胺 (1R)-(-)-樟脑磺哑嗪 (1R)-(-)-2,N-环氧基-exo-10,2-莰烷磺内酰胺 (1R)-(-)-(10-樟脑磺)哑嗪 N-环氧基-exo-10 |
| MDL Number | MFCD00075428 |
| PubChem Substance ID | 87566340 |
| Beilstein Registry Number | 6274369 |
| EC Number | 250-023-7 |
| Chemical Name Translation | (1R)-(-)-10-樟脑磺哑嗪 |
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分类
- Pharmaceuticals
- Intermediates & Fine Chemicals
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydroxylation
产品应用
- 非均化氧化试剂
相关文献及参考
- Davis, F.A., et al.: J. Am. Chem. Soc., 112, 6679 (1990)
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
其他信息
- TCI Shanghai:(2S,8aR)-(-)-樟脑磺哑嗪[非均化氧化试剂] (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent],>;95.0%(T)(104372-31-8)
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