2-Bromo-3,3,3-Trifluoropropene 2-溴-3,3,3-三氟丙烯
CAS 1514-82-5 MFCD00077469
化学结构图
SMILES: C=C(Br)C(F)(F)F
化学属性
| Mol. Formula | C3H2BrF3 |
|---|---|
| Mol. Weight | 175 |
| Boiling Point | 34°C(lit.) |
| Density | 1.66 |
| Refractive index | 1.3510 to 1.3580 |
| TSCA | No |
| Flash Point | ~-10 °F |
别名和识别编码
| Chemical Name | 2-Bromo-3,3,3-Trifluoropropene |
|---|---|
| CAS Number | 1514-82-5 |
| Alfabeta Name | BROMOTRIFLUOROPROPENE 2333---,, |
| MDL Number | MFCD00077469 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 1748624 |
| PubChem Substance ID | 272696 |
| Synonym | 2-Bromo-3,3,3-trifluoro-1-propene 2-Bromo-3,3,3-trifluoroprop-1-ene 98% 2-BROMO-3,3,3-TRIFLUOROPROPENE 2-溴-3,3,3-三氟-1-丙烯 2-Bromo-3,3,3-trifluoroprop-1-ene98% 2-BROMO-3,3,3-TRIFLUOROPROP-1-ENE 2-BROMO-3,3,3-TRIFLUOROPROPENE, 98+% 2-Bromo-3,3,3-Trifluoropropane 2-BROMO-3,3,3-TRIFLUORO-1-PROPENE 2-Bromo-3,3,3-trifluoro-1-propene (stabilized with Copper chip) 2-溴三氟丙烯 2-溴-3,3,3-三氟丙烯 |
| Chemical Name Translation | 2-溴-3,3,3-三氟丙烯 |
| Reaxys-RN | 1748624 |
| InChIKey | QKBKGNDTLQFSEU-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00116601 |
| InChI | InChI=1S/C3H2BrF3/c1-2(4)3(5,6)7/h1H2 |
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分类
- {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
相关文献及参考
- Precursor of 1-(trifluoromethylvinyl) organometallic species which permit the introduction of this useful fragment into a variety of molecules. For a review, see: Tetrahedron, 50, 2993 (1994).
- Treatment with LDA gives a trifluoromethylacetylene anion synthon which reacts with electrophiles to give trifluoromethylethynyl products: J. Fluorine Chem., 80, 145 (1996).
安全信息
GHS Symbol
- S24 Avoid contact with skin 避免皮肤接触；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R12 Extremely flammable 极端易燃
- R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P233 Keep container tightly closed. ?保持容器密闭。
- P234 Keep only in original container. 只保留在原来的容器中。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P301+P312
- P302+P352
- P303+P361+P353
- P304+P312
- P304+P340
- P305+P351+P338
- P308+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P411 Store at temperatures not exceeding … oC/…oF. 储存在温度不超过…oC /…oF。
- P420 Store away from other materials. 远离其他材料。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
- H242 Heating may cause a fire 加热可能会引起火灾
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
其他信息
- MOL 文件:1514-82-5.mol
- Alfa Aesar:2-溴-3,3,3-三氟丙烯,97% 2-Bromo-3,3,3-trifluoro-1-propene, 97%(1514-82-5)
- TCI Shanghai:2-溴-3,3,3-三氟-1-丙烯(含稳定剂铜屑) 2-Bromo-3,3,3-trifluoro-1-propene (stabilized with Copper chip),>;97.0%(GC)(1514-82-5)
- Hazard Note:Extremely Flammable
- 2-溴-3,3,3-三氟丙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1801 2-溴-3,3,3-三氟-1-丙烯(含稳定剂铜屑) 2-Bromo-3,3,3-trifluoro-1-propene (stabilized with Copper chip) 5G 636元 2014/06/02 B1801 2-溴-3,3,3-三氟-1-丙烯(含稳定剂铜屑) 2-Bromo-3,3,3-trifluoro-1-propene (stabilized with Copper chip) 25G 2160元 2010/05/25 B24614 2-溴-3,3,3-三氟丙烯, 97% 2-Bromo-3,3,3-trifluoro-1-propene, 97% 5g 603元
- Sigma Aldrich:1514-82-5(sigmaaldrich)
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