(-)-Camphanic acid chloride (1S)-(-)-莰烷酰氯

CAS 39637-74-6 MFCD00135626

化学结构图

39637-74-6
SMILES: CC1(C)[C@@]2(CC[C@@]1(C)C(=O)O2)C(=O)Cl

化学属性

Mol. FormulaC10H13ClO3
Mol. Weight217
Melting Point68-72
TSCANo
Density1.422
Stability耐潮性

别名和识别编码

Chemical Name(-)-Camphanic acid chloride
CAS Number39637-74-6
Synonym (-)-莰烷酰氯 (1S)-(-)-Camphanic chloride (1S)-3-氧代-4,7,7-三甲基-2-氧杂双环[2.2.1]庚烷-1-甲酰氯
PubChem Substance ID87566059
EC Number254-552-4
Beilstein Registry Number3590860
MDL NumberMFCD00135626
Reaxys-RN3590859
Chemical Name Translation(1S)-(-)-莰烷酰氯
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分类

  • {SA} Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • {SNA} Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents,

产品应用

  • An optically active resolving agent.

相关文献及参考

  • Helv. Chim. Acta, 61, 2773 (1978)
  • Chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
  • Resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography: Helv. Chim. Acta, 51, 1587 (1968); 61, 2773 (1978).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 8 C
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Storage condition Moisture Sensitive 0-10 贮存温度2-8°C 0-10°C
UN Number 3261
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
Packing GroupII
Hazard Class8

系列性分类


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