4-Formylphenylboronic Acid 4-甲酰基苯硼酸
CAS 87199-17-5 MFCD00151823
化学结构图
SMILES: O=Cc1ccc(B(O)O)cc1
化学属性
| Mol. Formula | HCOC6H4B(OH)2 |
|---|---|
| Mol. Weight | 150 |
| Melting Point | 237-242 °C (lit.) |
| TSCA | T |
| Density | 1.422 |
别名和识别编码
| Chemical Name | 4-Formylphenylboronic Acid |
|---|---|
| CAS Number | 87199-17-5 |
| Alfabeta Name | FORMYLPHENYLBORONICACID 4- |
| MDL Number | MFCD00151823 |
| Synonym | 4-Boronobenzaldehyde 4-Formylbenzeneboronic acid 4-Formylbenzeneboronic acid 4-醛基苯硼酸 p-Formylbenzeneboronic acid p-Formylphenylboronic acid 对甲酰苯硼酸 4-formylphenylboronic acid 4-甲酰基苯硼酸 4-甲酰苯硼酸 4-醛基苯硼酸 P-formylphenylboronic acid p-Formylbenzeneboronic acid p-Formylphenylboronic acid 对甲酰基苯硼酸 对甲酰苯硼酸 |
| Beilstein Registry Number | 16(4)1682 |
| PubChem Substance ID | 87570208 |
| EC Number | 438-670-5 |
| Chemical Name Translation | 4-甲酰基苯硼酸 |
| Reaxys-RN | 3030770 |
| InChIKey | VXWBQOJISHAKKM-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00111683 |
| InChI | InChI=1S/C7H7BO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5,10-11H |
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分类
- {SNA} Aldehydes, Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Building Blocks, C7, Carbonyl Compounds, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organic Building Blocks, Organometallic Reagents
- Aldehydes, Aryl Boronic Acids,
相关文献及参考
- 10. Eibergen, N. R.; et al. , Identification of a Novel P
- 3. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
- 7. Yu, A.; et al. , Palladacycle-catalyzed cross-coupling reactions of arylboronic acids with carboxylic anhydrides or acyl chlorides Tetrahedron 10th ed., 68 , 2283-2288, (2012)
- Beilstein:16(4)1682
安全信息
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P302+P350
- P302+P352
- P302+P352+P333+P313+P362+P364
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P333+P313
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- S24 Avoid contact with skin 避免皮肤接触；
- S37 Wear suitable gloves 戴适当手套；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S22 Do not breathe dust 不要吸入粉尘；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R34 Causes burns 会导致灼伤
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