Holmium(III) trifluoromethanesulfonate 三氟甲磺酸钬

CAS 139177-63-2 MFCD00209590

化学结构图

139177-63-2
SMILES: O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.[Ho+3]

化学属性

TSCANo
Mol. FormulaC3F9HoO9S3
Mol. Weight612.14
Appearance white to off-white pwdr.
Stabilityhygroscopic

别名和识别编码

Chemical NameHolmium(III) trifluoromethanesulfonate
Synonym 三氟甲磺酸钬 Holmium(III) triflate 三氟甲烷磺酸钬(III) 三氟甲磺酸 钬(III) 盐
PubChem Substance ID22482917
Chemical Name Translation三氟甲磺酸钬
MDL NumberMFCD00209590
CAS Number139177-63-2
InChIInChI=1S/3CHF3O3S.Ho/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Holmium

相关文献及参考

  • Used as a water tolerant Lewis Acid.Journal of Organic Chemistry, 59, 3590-3596 (1994).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Holmium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Peroxides - Oxidation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Triflate 三氟甲磺酸盐
  1. Metal Triflate
  2. Holmium

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