(R,R)-Tsdpen (1R,2R)-(-)-N-(对甲基苯磺酰基)-1,2-二苯基乙二胺
CAS 144222-34-4 MFCD02093428
化学结构图
SMILES: CC1C=CC(=CC=1)S(=O)(=O)N[C@@H]([C@H](N)C1C=CC=CC=1)C1C=CC=CC=1 |&1:11,12|
化学属性
| TSCA | No |
|---|---|
| Density | 1.224 |
| Refractive index | -30 ° (C=0.4, CHCl3) |
| Mol. Formula | C21H22N2O2S |
| Mol. Weight | 366 |
| Appearance | white xtl. |
| Melting Point | 127-129°C |
别名和识别编码
| Chemical Name | (R,R)-Tsdpen |
|---|---|
| Alfabeta Name | AMINODIPHENYLETHYLTOLUENESULFONAMIDE RRNP212(())-------,, |
| Synonym | (1R,2R)-(-)-N-对甲苯磺酰基-1,2-二苯基乙二胺 (R,R)-N-(对甲苯磺酰基)-1,2-二苯基乙二胺 ######## |
| PubChem Substance ID | 24871941 |
| Reaxys-RN | 8637103 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | (1R,2R)-(-)-N-(对甲基苯磺酰基)-1,2-二苯基乙二胺 |
| MDL Number | MFCD02093428 |
| CAS Number | 144222-34-4 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Organic Building Blocks, Polyamines, Protected Amines
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Organic Building Blocks, Polyamines, Protected Amines
产品应用
- (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide is used as a catalyst in stereoselective preparation of aromatic ketone derivatives as well as other chiral organic compounds.
相关文献及参考
- Tanis, S.P. et al.: Tetrahed. Assym., 17, 2154 (2006); Morris, D.J. et al.: Tetrahed. Lett., 51, 209 (2010);
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- TCI Shanghai:(R,R)-N-(2-氨基-1,2-二苯乙基)-对甲苯磺酰胺 (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide,>;98.0%(T)(144222-34-4)
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