4'-Methylacetanilide 4-甲基乙酰苯胺

CAS 103-89-9 MFCD00008677

化学结构图

103-89-9
SMILES: CC(=O)Nc1ccc(C)cc1

化学属性

Mol. FormulaC9H11NO
Mol. Weight149.19
Density1.212
Boiling Point307 °C at 760 mmHg
Melting Point149-151 °C
TSCAYes
Flash Point168 ºC
Solubility1 G/L (25 ºC)
Appearance 无色针状结晶。熔点153℃，沸点307℃（升华），闪点168℃，相对密度1.212。 微溶于水，溶于醇、醚、乙酸乙酯、冰乙酸和热水。

别名和识别编码

Chemical Name4'-Methylacetanilide
CAS Number103-89-9
Synonym N-(4-Methylphenyl)acetamide {LY} N-(4-Methylphenyl)acetamide {} {LY} N-(4-Methylphenyl)acetamide {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {} {PubChem} 4-methylacetanilide {} {} {} {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-Methylphenyl)acetamide {} {} {
MDL NumberMFCD00008677
EC Number203-155-4
Beilstein Registry Number607036
PubChem Substance ID7684
Merck Number14,74
Reaxys-RN607036
Chemical Name Translation4-甲基乙酰苯胺
Wiswesser Line Notation1VMR D1
LabNetwork Molecule IDLN00226065
InChIInChI=1S/C9H11NO/c1-7-3-5-9(6-4-7)10-8(2)11/h3-6H,1-2H3,(H,10,11)
Canonical SMILESCC(NC1=CC=C(C=C1)C)=O
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分类

  • Aromatics
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; amide; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Protected Amines
  • Miscellaneous Reagents

相关文献及参考

  • Short: II/27C Title: Diamagnetic Susceptibility and Magnetic Anisotropy of Organic Compounds Author: Kumar, Mahendra; Gupta, Rajni Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27C Year: 2008 Keyword: diamagnetic susceptibility; magnetic anisotropy; organic compounds ISBN: 978-3-540-44734-4 (print) ISBN: 978-3-540-44736-8 (online) Internet Resource: doi:10.1007/978-3-540-44736-8 RefComment: VIII, 204 p., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds (Part 1); Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds (Part 2). The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005.
  • Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10a Year: 1985 ISBN: 3-540-07834-7 ISBN: 978-3-540-07834-0 Internet Resource: DOI:10.1007/b19984 RefComment: XXII, 634 pages. Hardcover Abstract: The volume includes an alphabetical index of all substances and a separate "ring index" with all cyclic compounds.
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 2

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSAN2930000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 980 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   19,20,1971

Storage condition

其他信息

  • MOL 文件:5602-96-0.mol
  • 灭火剂:干粉、泡沫, 雾状水
  • 储运特性:库房通风低温干燥
  • 下游产品:4-甲基-2-硝基苯胺 --> 2-溴-4-甲基苯胺
  • 毒性分级:中毒
  • Sigma Aldrich:5602-96-0(sigmaaldrich)
  • Sigma Aldrich:103-89-9(sigmaaldrich)
  • 4-甲基乙酰苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0064 乙酰对甲苯胺 p-Acetotoluidine 500G 2890元 2014/06/02 A0064 乙酰对甲苯胺 p-Acetotoluidine 25G 240元 2010/06/21 400165000 4-甲基乙酰苯胺 p-Acetotoluidide 99% 500 GR 2558元
  • 方法一:将23g对甲苯胺与500ml水及18ml浓盐酸搅拌加热至50℃，再加入29ml乙酐，30g乙酸钠溶于100ml水的溶液，激烈搅拌，冰水冷却，滤出产物，水洗，干燥，得约20g对甲基乙酰苯胺。
  • 用途一:有机合成中间体。
  • MSDS 信息:4'-Methylacetanilide(103-89-9).msds
  • 图谱信息:4-甲基乙酰苯胺(103-89-9)核磁图( 13 CNMR) 4-甲基乙酰苯胺(103-89-9)红外图谱(IR2) 4-甲基乙酰苯胺(103-89-9)红外图谱(IR1) 4-甲基乙酰苯胺(103-89-9)Raman光谱 4-甲基乙酰苯胺(103-89-9)核磁图( 1 HNMR) 4-甲基乙酰苯胺(103-89-9)质谱(MS)
  • 可燃性危险特性:可燃; 加热分解释放有毒氮氧化物烟雾
  • Alfa Aesar:4'-甲基乙酰苯胺,98+% 4'-Methylacetanilide, 98+%(103-89-9)
  • TCI Shanghai:乙酰对甲苯胺 p-Acetotoluidine,>;98.0%(GC)(N)(103-89-9)
  • Acros Organics:对甲基乙酰氨基苯/对甲基乙酰苯胺 p-Acetotoluidide, 99%(103-89-9)
  • 海关编码:29242995
  • 检测方法:GC,HPLC,NMR
  • MOL 文件:103-89-9.mol
  • 急性毒性:口服-大鼠 LD 50：2640 毫克/立方米; 口服- 小鼠 LD50: 980 毫克/ 公斤
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Protected Amines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Protected Amines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines

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