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• Cell Biology, Cell Culture, Core Bioreagents, Expression and Translation, Functional Profiling of Stem Cells, General Reagents, General Stem Cell Biology, Life Science Reagents for Cell Culture, Miscellaneous Reagents and Supplements, Reagents and Supplements, Research Essentials, Stem Cell Biology
• {SNA} BioUltr
• {SNA} Antioxidants and Reducing Agents for Protein Stabilization, Building Blocks, Chemical Synthesis, HIS Select Supporting Products and Reagents, HIS-Select, Organic Building Blocks, Protein Modification, Reagents and Products for use with HIS-Select, Reagents for Protein Stabilization, Reagents for reduction of proteins, Reduction and Oxidation,

相关文献及参考

• Merck 14 ,5869
• Beil. 1 ,IV,2428
• Aldrich MSDS 1 , 1162:C / Corp MSDS 1 (2), 2209:A / FT-IR 2 (1), 415:B / FT-IR 1 (1), 262:B / FT-NMR 1 (1), 422:B / IR-Spectra (2), 138:E / IR-Spectra (3), 154:F / NMR-Reference 2 (1), 228:B / RegBook 1 (1), 281:L / Sax 6 , 1744 / Sigma FT-IR 1 (2), 700:C / Structure Index 1 , 38:D:7 / Vapor Phase 3 , 344:C
• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-113
• Protective agent for preventing oxidation of thiol groups in proteins: Enzyme Assays, R. Eisenthal and M. J. Danson, Eds., OUP, Oxford (1992), p 265.
• In the presence of BF3 etherate, reacts with carbonyl compounds to give monothioacetals (1,3-oxathiolanes): J. Org. Chem., 33, 2133 (1968). Amberlyst 15 is also effective: Synthesis, 1826 (2001), as is In(OTf)3: Synlett, 1535 (2002). 1,3-Oxathiolanes can be prepared from acid-sensitive aldehydes with LiBH4 as catalyst in acetonitrile: Synlett, 238 (2001). Cleavage can be effected, e.g. with chloramine-T: Tetrahedron Lett., 3445 (1971), isoamyl nitrite: Tetrahedron. Lett., 3561 (1978), or periodic acid: Tetrahedron Lett., 37, 4331 (1996). Selective cleavage of oxathiolanes in the presence of dithiolanes has been achieved with triphenylcarbenium tetrafluoroborate: J. Chem. Soc., Perkin 1, 542 (1972), or 4-nitrobenzaldehyde catalyzed by TMS-OTf: J. Chem. Soc. Chem. Commun., 1937 (1994). Compare 1,2-Ethanedithiol, L12865.
• 2-Mercaptoethanol is a reagent for the specific cleavage of the N-dithiasuccinimide protecting group from amines. See Chlorocarbonyl­sulfenyl­ chloride, L06432.

安全信息

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 190 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Behavioral - muscle contraction or spasticity
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 15(2),56,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 480 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 62,237,1973

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13200 mg/m3
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 15(2),56,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other tha

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - mouse Cells - not otherwise specified
DOSE/DURATION           : 30 mmol/L
REFERENCE :
   BBACAQ Biochimica et Biophysica Acta.  (Elsevier Science Pub. B.V., POB 211,
   1000 AE Amsterdam, Netherlands)  V.1-    1947- Volume(issue)/page/year:
   425,1,1976

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Rodent - mouse Cells - not otherwise specified
DOSE/DURATION           : 100 mg/L
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   56,357,1976

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   ABBIA4 Archives of Biochemistry and Biophysics.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.31-    1951-  Volume(issue)/page/year:
   166,400,1975

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 10 mmol/L
REFERENCE :
   BBRCA9 Biochemical and Biophysical Research Communications.  (Academic
   Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1959-
   Volume(issue)/page/year: 77,1150,1977

其他信息

• 蒸气压:1 mm Hg ( 20 °C)
• 凝固点:<100℃
• 急性毒性:口服-大鼠 LD50: 244 毫克/公斤; 口服-小鼠 LD50: 190 毫克/公斤
• 2-巯基乙醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80076927 2-巯基乙醇（剧毒） 250ml 350元 2011/08/23 80076980 2-巯基乙醇（剧毒） 250ml 351元 2011/08/23 SM625002 2-巯基乙醇(剧毒) 100ml 277元
• 上游原料:2-氯乙醇 --> 硫氢化钠 --> 二(2－羟乙基)硫醚 --> 强碱性阴离子交换树脂
• 海关编码:29309070
• Acros Organics:2-巯基乙醇 2-Mercaptoethanol,extrapure,99%(60-24-2)
• 可燃性危险特性:可燃; 受热分解有毒氧化硫气体
• Alfa Aesar:2-巯基乙醇,98+% 2-Mercaptoethanol, 98+%(60-24-2)
• 外观性质:水白色易流动液体，具有少许硫醇气味。
• 用途三:作为有机合成中间体，用于农药、医药、染料、照相化学品的生产。在橡胶、纺织、塑料、涂料工业中亦可用作助剂。聚合级高纯巯基乙醇可用作氯乙烯、丙烯腈等的调取剂，以及聚合催化剂、聚合物交联剂、固化剂。该品得到美国食品药物管理局的批准，可用作丙烯腈、苯乙烯、甲基丙烯酸甲酯三元树脂制食品包装用吹塑容器时的添加剂。
• 类别:有毒物品
• MSDS 信息:2-巯基乙醇(60-24-2).msds
• 职业标准:STEL 1 毫克/立方米
• MOL 文件:60-24-2.mol
• 储运特性:库房通风低温干燥; 与氧化剂, 食品分开储运
• 敏感性:Air Sensitive & Hygroscopic
• 爆炸物危险特性:与空气混合, 受热、明火可爆
• 刺激数据:皮肤-兔子 10 毫克/24小时 重度; 眼睛-兔子 2 毫克 重度
• Sigma Aldrich:60-24-2(sigmaaldrich)
• 毒性分级:高毒
• 下游产品:丙烯酸酯三元共聚物负载双硫铂配合物催化剂 --> 如氟沙星 --> 更昔洛韦 --> 萎锈灵
• 用途二:用作增塑剂及杀虫剂，也用于染料的制造
• 灭火剂:二氧化碳, 干粉, 砂土
• 方法一:早期采用氯乙醇与硫氢化钠反应制得。环氧乙烷与硫化氢按摩尔比1：3.5配合，以强碱性阴离子交换树脂为催化剂，在42℃左右反应。所得粗品含量约52%，还含少量硫二甘醇（沸点282℃），较易分离获得2-巯基乙醇。
• F:3-10-13-23
• 图谱信息:2-巯基乙醇(60-24-2)质谱(MS) 2-巯基乙醇(60-24-2)核磁图( 13 CNMR) 2-巯基乙醇(60-24-2)红外图谱(IR1)
• 用途一:用于合成染料、农药、医药等，在橡胶、纺织、塑料、涂料工业中可用作助剂
• 蒸气密度:2.69 (vs air)