1,2-Dihydroxymethylbenzene 1,2-二苯甲醇
CAS 612-14-6 MFCD00004626
化学结构图
SMILES: OCC1CCCCC1CO
化学属性
| Mol. Formula | C8H10O2 |
|---|---|
| Mol. Weight | 138 |
| Melting Point | 63-65 |
| TSCA | Yes |
| Density | 1.422 |
| Boiling Point | 145°C/3mmHg(lit.) |
别名和识别编码
| Chemical Name | 1,2-Dihydroxymethylbenzene |
|---|---|
| Synonym | 1, 1,2-BBENZENEDIMETHANOL 1,2-BENZENEDIMETHANOL 97% 1,2-Benzoldimethanol 1,2-Bis(hydroxymethyl)benzene 1,2-Bis-(hydroxymethyl)-benzol 1,2-Di(hydroxymethyl)benzene 1,2-bis(hydroxymethyl)benzene 1,2-bis-hydroxymethyl-benzene 1,2-双(羟基甲基)苯 1,2-双(羟基甲基)苯 邻二甲苯-α,α′-二醇 邻苯二甲醇 1,2-苯二甲醇 2-(Hydroxymethyl)-benzylalkohol o-Bis(hydroxymethyl)benzene o-Xylol-α,α'-diol o-phenylenedimethanol o-xylene α,α'-diol ALPHA,ALPHA'-DIHYDROXY-O-XYLENE O-XYLYLENE DIALCOHOL PHTHALYL ALCOHOL RARECHEM AL BD 0044 [2-(Hydroxymethyl)phenyl]methanol phthalic alcohol α,α'-Dihydroxy-o-xylene 邻苯二甲醇 |
| Beilstein Registry Number | 508775 |
| PubChem Substance ID | 69153 |
| CAS Number | 612-14-6 |
| EC Number | 210-293-9 |
| MDL Number | MFCD00004626 |
| Reaxys-RN | 508775 |
| Chemical Name Translation | 1,2-二苯甲醇 |
| InChIKey | XMUZQOKACOLCSS-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01372805 |
| InChI | InChI=1S/C8H10O2/c9-5-7-3-1-2-4-8(7)6-10/h1-4,9-10H,5-6H2 |
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分类
- Alcohols, Materials Science, Monomers, Polymer Science
- {SNA} Alcohols, Monomers, Polymer Science, 材料科学
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Polyols
相关文献及参考
- Has also been employed for the protection of boronic acids, by reaction in THF in the presence of a dehydrating agent, e.g. Na2SO4. These derivatives can be readily cleaved by hydrogenolysis or hydrolysis: Tetrahedron Lett., 37, 6705 (1996).
- Short: III/35D2
- The 7-membered cyclic orthoformates, formed with triethyl or trimethyl orthoformate, are superior reagents for the protection of carbonyl groups as their 2,4-benzodioxepine derivatives. These can be readily cleaved in high yield by Pd-catalyzed hydrogenolysis: Tetrahedron Lett., 30, 4165 (1989); J. Am. Chem. Soc., 116, 558 (1994).
安全信息
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
GHS Symbol
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P302+P352
- P304+P312
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- MSDS 信息:1,2-Di(hydroxymethyl)benzene(612-14-6).msds
- 图谱信息:邻苯二甲醇(612-14-6)红外图谱(IR2) 邻苯二甲醇(612-14-6)核磁图( 13 CNMR) 邻苯二甲醇(612-14-6)红外图谱(IR1) 邻苯二甲醇(612-14-6)Raman光谱 邻苯二甲醇(612-14-6)核磁图( 1 HNMR) 邻苯二甲醇(612-14-6)质谱(MS)
- TCI Shanghai:1,2-苯二甲醇 1,2-Benzenedimethanol,>;98.0%(GC)(612-14-6)
- Sigma Aldrich:612-14-6(sigmaaldrich)
- 邻苯二甲醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 X0057 1,2-苯二甲醇 1,2-Benzenedimethanol 5G 1220元 2014/06/02 X0057 1,2-苯二甲醇 1,2-Benzenedimethanol 25G 4390元 2010/06/21 180410025 邻苯二甲醇 1,2-Benzenedimethanol 97% 2.5 GR 763元
- 海关编码:29062900
- Alfa Aesar:邻苯二甲醇,97% 1,2-Benzenedimethanol, 97%(612-14-6)
- Acros Organics:1，2-苯二甲醇 1,2-Benzenedimethanol, 97%(612-14-6)
- MOL 文件:612-14-6.mol
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