2-Methoxyacetic Acid 2-甲氧基乙酸

CAS 625-45-6 MFCD00004308

化学结构图

625-45-6
SMILES: COCC(=O)O

化学属性

Mol. FormulaC3H6O3
Mol. Weight90.08
Density1.174
Refractive index1.4150 to 1.4180
Boiling Point201°C at 760 mmHg
Melting Point7-9°C
Flash Point121°C
TSCAYes
Solubility易溶
pH:A

别名和识别编码

Chemical Name2-Methoxyacetic Acid
Synonym Methoxyacetic acid {LY} Methoxyacetic acid {} {LY} Methoxyacetic acid {} {} {LY} Methoxyacetic acid {} {} {} {LY} Methoxyacetic acid {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methox
MDL NumberMFCD00004308
CAS Number625-45-6
EC Number210-894-6
Beilstein Registry Number3,232
PubChem Substance ID12251
Reaxys-RN635800
Chemical Name Translation2-甲氧基乙酸
LabNetwork Molecule IDLN00220113
InChIInChI=1S/C3H6O3/c1-6-2-3(4)5/h2H2,1H3,(H,4,5)
Canonical SMILESO=C(O)COC
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Building Blocks, C1 to C5, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; carboxylic acid; ether; 1fragment

相关文献及参考

  • Reacts with thionyl chloride on prolonged refluxing, to give chloromethyl methyl ether, reportedly free from the highly carcinogenic bis(chloromethyl)ether: Synthesis, 727 (1984).
  • Short: II/14a
  • Short: III/38B
  • Short: EINECS
  • Short: IV/20B
  • Reacts with thionyl chloride on prolonged refluxing,

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R60 May impair fertility 可能降低生殖能力
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P308+P313
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSAI8650000
Packing GroupII
UN Number UN3265
Hazard Codes T
Hazard Class8
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   2,158,1982

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Rodent - mouse Embryo
DOSE/DURATION           : 25 mmol/L
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 45,111,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 592 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 32,73,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 901 mg/kg
SEX/DURATION            : female 10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   HIJMAC Hiroshima Journal of Medical Sciences.  (Hiroshima University Medical
   Press, c/o Hiroshima University, School of Medicine, 1-2-3 Kasumi,
   Minami-ku, Hiroshima, 734, Japan)  V.1-    1951-  Volume(issue)/page/year:
   40,93,1991

TYPE OF TEST            : TDLo - Lowest published

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 118 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 43,17,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1 gm/kg
SEX/

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 下游产品:乙醛酸 --> 甲霜灵 --> 甲氧基乙酰氯
  • 甲氧基乙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0827 甲氧基乙酸 Methoxyacetic Acid 25G 150元 2014/06/02 M0827 甲氧基乙酸 Methoxyacetic Acid 500G 989元 2010/06/21 186772500 甲氧基乙酸 Methoxyacetic acid 98% 250 ML 823元
  • TCI Shanghai:甲氧基乙酸 Methoxyacetic Acid,>;96.0%(T)(625-45-6)
  • Acros Organics:2-甲氧基乙酸 Methoxyacetic acid, 98%(625-45-6)
  • Sigma Aldrich:625-45-6(sigmaaldrich)
  • 海关编码:29189090
  • 图谱信息:甲氧基乙酸(625-45-6)核磁图( 13 CNMR) 甲氧基乙酸(625-45-6)核磁图( 1 HNMR) 甲氧基乙酸(625-45-6)质谱(MS) 甲氧基乙酸(625-45-6)红外图谱(IR1)
  • MOL 文件:625-45-6.mol
  • 敏感性:Hygroscopic
  • F:10-21
  • 检测方法:GC,NMR
  • MSDS 信息:Methoxyacetic acid(625-45-6).msds
  • Alfa Aesar:甲氧基乙酸,98% Methoxyacetic acid, 98%(625-45-6)

系列性分类


相关产品推荐