Phenylphosphine 苯基膦

CAS 638-21-1 MFCD00002094

化学结构图

638-21-1
SMILES: Pc1ccccc1

化学属性

Vapor Density3.79 (vs air)
Vapor Pressure760 mmHg ( 160 °C)
Refractive index1.578
TSCANo
Mol. FormulaC6H5PH2
Mol. Weight110
Density1.001
Flash Point165°F
Appearance colorless liq.
Boiling Point160°C
Stabilityair sensitive

别名和识别编码

Chemical NamePhenylphosphine
Synonym phenyl-phosphine AURORA KA-1101 Phenylphosphinecolorlessliq 苯膦 Fenylfosfin PHENYLPHOSPHINE, 10% WEIGHT IN HEXANES Phenylphosphine,99%(10wt%inhexane) 苯基膦 Phenylphosphine,99% Phenylphosphine Phenylphosphineinhexane Phosphaniline PHPH2 Phosphine, phenyl- PHENYLPHOSPHINE (10% WT. IN HEXANE) phenylphosphane PHENYLPHOSPHINE Monophenylphosphine phenyl-phosphin phenylphosphine Phenylphosphine,99%(Sure/Sealbottle) Phenyl-phosphane
PubChem Substance ID12519
Beilstein Registry Number0741946
EC Number211-325-4
Chemical Name Translation苯基膦
Wiswesser Line NotationPHHR
LabNetwork Molecule IDLN02124545
InChIInChI=1S/C6H7P/c7-6-4-2-1-3-5-6/h1-5H,7H2
MDL NumberMFCD00002094
CAS Number638-21-1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
  • Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiemann, E.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19c Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54893-9 ISBN: 978-3-540-54893-5 Internet Resource: DOI:10.1007/b44435 RefComment: 8 figs., XI, 295 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplem

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H301+H311+H331
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSSZ2100000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P231 Handle under inert gas. 在惰性气体中操作。
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Packing GroupI
UN Number UN2845 2924 2845
Risk Statements
  • R11 Highly flammable 非常易燃
  • R48/20
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R51/53
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R20 Harmful by inhalation 吸入有害
Storage condition Air & Moisture Sensitive 储存温度 -20°C
Hazard Codes F;T;N F,T,N F;T;N,N,T,F
Hazard Class4.2
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 38 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Sense Organs and Special Senses (Eye) - lacrimation
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,154,1969

其他信息

  • 毒性分级:剧毒
  • 职业标准:TWA 0.25 毫克/立方米
  • 类别:有毒物质
  • 下游产品:4-氟苯胺
  • 灭火剂:泡沫; 干粉
  • 储运特性:库房低温, 通风, 干燥 ;容器密闭; 防火; 与氧化剂, 食品原料分开存放
  • 可燃性危险特性:在空气中可自燃; 火场释放有毒磷氧化物烟雾
  • Alfa Aesar:苯膦 Phenylphosphine(638-21-1)
  • Sigma Aldrich:638-21-1(sigmaaldrich)
  • 苯基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 30155 苯膦 Phenylphosphine 5g 1303元 2010/05/25 30155 苯膦 Phenylphosphine 25g 5656元 2010/05/25 30155 苯膦 Phenylphosphine 1g 325元
  • MSDS 信息:Phenyl phosphine(638-21-1).msds
  • 急性毒性:吸入-大鼠 LC50: 38 ppm/4小时
  • 敏感性:Air & Moisture Sensitive
  • MOL 文件:638-21-1.mol

系列性分类


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