Vinyl chloride 氯乙烯

CAS 75-01-4 MFCD00040415

化学结构图

75-01-4
SMILES: C=CCl

化学属性

Mol. FormulaC2H3Cl
Mol. Weight62.50
Refractive indexn20/D 1.3700(lit.)
Boiling Point-13.4 °C(lit.)
Density0.7915
Melting Point-153.8 °C(lit.)
Flash Point-78 °F
Solubilityacetone/carbon disulfide, MEK, THF: soluble
Appearance powder

别名和识别编码

Chemical NameVinyl chloride
Synonym {uni_hamburg} 氯乙烯 chloro-ethene monomeres Vinylchorid vinylchloride CHLOROETHYLENE 1-Chloroethene chloro-Ethene chloro-ethylen Vinyl C monomer Monochloräthylen C2H3Cl (chloro-ethene) chloroacetylene Chlorethylen Vinyl chloride monomer Chlorethylene 乙烯基氯 Monochloroethylene 1-Chlor-αthen Vinile (cloruro di) 1-Chlorethen VCM Ethylene monochloride chloroethene Winylu chlorek F 1140 Cloruro di vinile Monochloroethene Chlorethen Chloroethylene C2H3Cl RCRA waste number U043 Ethylene, chloro- Vinylchlorid Chloroethene Vinyl chloride 1-Chlor-äthen vinyl chloride Ethene, chloro- 氯乙炔 chloroethyne VINYL CHLORIDE Vinyle(chlorure de) chloruredevinyle Chlorure de vinyle Chloroacetylenecation Chlorethene chloro-ethen 1-Chloroethylene
MDL NumberMFCD00040415
CAS Number75-01-4
PubChem Substance ID6338
EC Number200-659-6
Beilstein Registry Number1731576
Chemical Name Translation氯乙烯
Merck Number13,10055
Wiswesser Line NotationG1U1
InChIInChI=1S/C2H3Cl/c1-2-3/h2H,1H2
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Specialty Gases, Synthetic Reagents

相关文献及参考

  • Short: II/19c
  • Merck: 14,9994 Beilstein: 1,IV,700
  • Merck: 14,9994
  • Short: II/14a
  • Short: II/19b

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H220 Extremely flammable gas 极易燃气体。
  • H350 May cause cancer 可能致癌
  • H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECSKU9625000
Precautionary statements
  • P410+P403
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P308+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes F+,T F+,T,F
Risk Statements
  • R45 May cause cancer 可能致癌
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R12 Extremely flammable 极端易燃
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
Hazard Class2.1
Storage condition 储存温度2-8℃ 2-8°C
UN Number UN 1086 2.1 
TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10000 ppm/4H
                          female 12-18 day(s) after conception
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Reproductive - Tumorigenic effects - transplacental tumorigenesis
   Endocrine - tumors
REFERENCE :
   CSHCAL Cold Spring Harbor Conferences on Cell Proliferation.  (Cold Spring
   Harb

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 21 mg/kg/65W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Gastrointestinal - tumors
REFERENCE :
   APDCDT Advances in Tumour Prevention, Detection and Characterization.  (New
   York, NY)  V.1-5, 1974-80.  Discontinued.  Volume(issue)/page/year:
   3,216,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3463 mg/kg/52W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 41,3,1981

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 300 mg/m3/W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 11309

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 200 ppm/18M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : I

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 18 pph/15M
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   HUTODJ Human Toxicology.  (Macmillan Press Ltd., Houndmills, Basingstoke,
   Hants., RG 21 2XS, UK) V.1-    1981-  Volume(issue)/page/year: 1,239,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOWCC* Dow Chemical Company Reports.  (Dow Chemical USA, Health and
   Environment Research, Toxicology Research Lab., Midland, MI 4

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 30 pph/30M
TOXIC EFFECTS :
   Behavioral - general anesthetic
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   21,394,1960

{h

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10600 umol/L
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   24,2013,1975

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 48 mmol/L/3H
REFERENCE :
   MUREAV Mutat

{

TYPE OF TEST            : Sex chro

TYPE OF TEST            : DNA inhibition
ROUTE OF EXPOSURE       : Intravenous
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 9500 ug/kg
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   17,239,1977

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 pph
REFERENCE :
   EVSRBT Environmental Science Research.  (Plenum Pub. Corp., 233 Spring St.,
   New York, NY 10013) V.1-    1972-  Volume(issue)/page/year: 25,91,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Schizosaccharomyces pombe
DOSE/DURATION           : 16 mmol/L/30M
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,85,1976

TYPE OF TEST

TYPE OF

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Rodent - hamster
DOSE/DURATION           : 600 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    19

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 ppm/7H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 41,171,1981

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1500 ppm/24H
SEX/DURATION            : female 1-9 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 11,45,1978

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE

{

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 500 ppm/7H
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 41,171,1981

Warnings 危险化学品

其他信息

  • 下游产品:异丙氧基乙醇
  • 爆炸物危险特性:与空气混合明火、受热可爆
  • 方法一:1.乙烯氧氯化法该法是世界公认为技术经济较合理的方法。乙烯与氯气在三氯化铁催化剂存在下，液相直接氯化生成1,2-二氯乙烷。1,2-二氯乙烷经精制后裂解，得氯乙烯和氯化氢，经精馏得到成品氯乙烯。副产氯化氢、乙烯与空气，通过载于氧化铝上的氯化铜触媒进行氧氯化反应得1,2-二氯乙烷，精制后在500℃、2.0-2.5MPa压力下，在管式炉内裂解生成氯乙烯和氯化氢，精制得产品氯乙烯。副产品氯化氢可再返回氧氯化反应器与乙烯再进行氧氯化反应。2.乙炔气相合成法本法工艺简单，产品纯度高，但耗电量大，成本高，并有汞污染问题。由电石发生的乙炔与氯化氢混合，在氯化汞存在下，于170-190℃进行反应，反应产物经水洗、碱洗、压缩、全凝、初馏、精馏，得氯乙烯单体。3.乙烯直接氯化法4.烯炔联合法
  • 上游原料:酸性氧化铝 --> 三氯化铁 --> 1,2-二氯乙烷 --> 碳化钙 --> 乙炔 --> 氯化汞 --> 氯乙烯单体
  • 防护措施:对人体有麻醉作用。含量达20%～40%时，可使人发生急性中毒而失去知觉，呼吸渐缓，终致死亡。长期接触能引起指骨溶失症或肝脾肿大等症状。也有报道，氯乙烯会致癌，但有一定争论。发现急性中毒时应及早移出现场，静卧保暖、松衣、输氧气或人工呼吸。如皮肤被液体污染，宜用大量清水冲洗。生产设备应严防跑、冒、滴、漏。操作人员应配戴防护用具。空气中最高容许浓度1ppm。
  • 类别:有害气体
  • 储运特性:库房通风低温干燥; 轻装轻卸; 与氧气、空气等助燃气体钢瓶分开存放
  • Sigma Aldrich:75-01-4(sigmaaldrich)
  • 毒性分级:中毒
  • 职业标准:TWA 10 毫克/ 立方米; STEL 30 毫克/ 立方米
  • F:4.5-31
  • 外观性质:无色、有醚样气味的气体。
  • MSDS 信息:氯乙烯(75-01-4).msds
  • 可燃性危险特性:明火、受热可燃; 燃烧产生有毒氯化物烟雾
  • 灭火剂:雾状水、二氧化碳、泡沫
  • 急性毒性:吸入- 大鼠 LC50: 18000 PPM/ 15分; 口服- 大鼠 LD50: 500 毫克/ 公斤
  • MOL 文件:75-01-4.mol
  • 常规方法:可用管道、耐压贮罐贮运。应隔绝明火，避免和氧化剂接近，防止日晒、受热，运输中防止撞击。公路、铁路均可运输。
  • 用途一:用作多种聚合物的共聚单体
  • 用途二:塑料工业的重要原料，主要用于生产聚氯乙烯树脂。与醋酸乙烯、偏氯乙烯、丁二烯、丙烯腈、丙烯酸酯类及其他单体共聚生成共聚物，也可用作冷冻剂等。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Specialty Gases 特种气体
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. V - Alphabetic
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃

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