Sodium metabisulfite 偏二亚硫酸钠, ACS级

CAS 7681-57-4 MFCD00167602

化学结构图

7681-57-4
SMILES: O=S([O-])S(=O)(=O)[O-].[Na+].[Na+]

化学属性

Mol. FormulaNa2O5S2
Mol. Weight190.11
Melting Point>300 °C
Density1.480
TSCAYes
SolubilityFreely soluble in water, glycerol. Slightly soluble in alcohol
Boiling Point150°C
Stability对湿度和空气敏感

别名和识别编码

Chemical NameSodium metabisulfite
MDL NumberMFCD00167602
CAS Number7681-57-4
Synonym Sodium metabisulfite {LY} Sodium metabisulfite {} {LY} Sodium metabisulfite {} {} {LY} Sodium metabisulfite {} {} {} {LY} Sodium metabisulfite {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium metabisulfite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sod
EC Number231-673-0
Merck Number14,8638
PubChem Substance ID656671
Chemical Name Translation偏二亚硫酸钠, ACS级
Wiswesser Line NotationNA2 S2-O3-Q2
LabNetwork Molecule IDLN00194236
InChIInChI=1S/2Na.H2O5S2/c;;1-6(2)7(3,4)5/h;;(H,1,2)(H,3,4,5)/q2*+1;/p-2
Canonical SMILES[Na].O=S(O)S(=O)(=O)O
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分类

  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Puriss p.a. ACS, Q-S, Puriss p.a. ACS
  • {SNA} Chemical Synthesis, Essential Chemicals, Inorganic Salts, Research Essentials, Salts, Sodium, Sodium Salts, Synthetic Reagents
  • {SNA} Analytical Reagents for General Use, Essential Chemicals, Puriss p.a. ACS, Q-S, Puriss p.a. ACS, Research Essentials, Salts, Sodium Salts, 分析/色谱, 分析试剂
  • {SNA} Chemical Synthesis, Inorganic Salts, Sodium, Synthetic Reagents

产品应用

  • 分析用。防腐 剂。还原剂。抗氧剂

相关文献及参考

  • Merck: 14,8638

安全信息

RTECSUX8225000
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
Risk Statements
  • R31 Contact with acids liberates toxic gas 与酸接触释放出有毒气体
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
GHS Symbol
Precautionary statements
Signal word
Hazard statements
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
WGK Germany1
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
UN Number 2693
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Air & Moisture Sensitive Store at room temperature, keep dry and cool {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moi
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 192 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   24,266,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 115 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 6,1418,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 910 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 31,120,1968

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 180 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 179,159,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 200 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 20 gm/kg
SEX/DURATION            : multigenerations
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - stillbirth
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,291,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 40 gm/kg
SEX/DURATION            : multigenerations
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 10,291,1972

其他信息

  • 有二氧化硫的气味。在空气中逐渐氧化为硫酸钠。在150℃以上分解。易溶于水(64g/100ml)和甘油,微溶于乙醇,水溶液呈酸性,固体时,本品为焦亚硫酸钠 (Na2S2O5)。溶于水时,得到 NaHSO3 。半数致死量(大鼠,静脉)115mg/kg。对皮肤和粘膜有刺激性。

系列性分类


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