Trifluoromethanesulfonyl Chloride 三氟甲烷磺酰氯

CAS 421-83-0 MFCD00007451

化学结构图

421-83-0
SMILES: O=S(=O)(Cl)C(F)(F)F

化学属性

Mol. FormulaCClF3O2S
Mol. Weight169
Refractive index1.3320 to 1.3380
Boiling Point29-32
Vapor Pressure10.36 psi ( 20 °C)
Density1.583
TSCANo
Flash Point32°C
Stability对热及湿度敏感
Danger-Level乙类

别名和识别编码

Chemical NameTrifluoromethanesulfonyl Chloride
Synonym Trifluoromethylsulfuryl chloride Trifluoromathanesulfonyl chloride TRIFLUOROMETHANESULFONYLCLORIDE PFC-MSC Trifluormethansulfonylchlorid 三氟甲磺酰氯 {un 三氟甲烷磺酰氯; 三氟甲基磺酰氯 Trifluoro-methanesulfonyl chloride TRIFLUOROMETHANESULFONYL CHLORIDE, 99+% Trifluoromethylsulphonyl chloride 三氟甲烷磺酰氯 TRIFLYL CHLORIDE Triflyl chloride Trifluormethansulfonsäurechlorid TRIFLUOROMETHANESULPHONYL CHLORIDE Methanesulfonyl chloride, trifluoro- TRIFLUOROMETHANESULFONYL CHLORIDE trifluoromethylsulfonyl chloride Trifluoromethanesulfonylchloride,98% Trifluoromethylsulfonyl chloride Trifluoromethanesulphonylchloride,99% Methanesulfonylchloride-trifluoro
MDL NumberMFCD00007451
CAS Number421-83-0
PubChem Substance ID87576831
EC Number207-009-0
Beilstein Registry Number3(4)35
Chemical Name Translation三氟甲烷磺酰氯
Reaxys-RN1812106
InChIKeyGRGCWBWNLSTIEN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00111207
InChIInChI=1S/CClF3O2S/c2-8(6,7)1(3,4)5
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分类

  • {SNA} Chemical Synthesis, Other Protecting and Derivatizing Reagents, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

产品应用

  • 钌(II)复合物催化的芳香族化合物和烯的三氟甲基化试剂。

相关文献及参考

  • Short: II/25B
  • Short: III/35E
  • Beilstein:3(4)35

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S8 Keep container dry 保持容器干燥；
Storage condition Moisture Sensitive 储存温度2-8°C,充氩保存 储存温度2-8°C 0-10°C 0-10 2-8°C
Hazard Codes 8 C
Hazard Class8

其他信息

  • 水中分解
  • 用途一:钌(II)复合物催化的芳香族化合物和烯的三氟甲基化试剂。
  • Acros Organics:三氟甲烷磺酰氯 Trifluoromethanesulfonyl chloride, 99%(421-83-0)
  • Hazard Note:Corrosive/Lachrymatory
  • 下游产品:N-苯基双(三氟甲烷磺酰)亚胺
  • MOL 文件:421-83-0.mol
  • 三氟甲烷磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1027 三氟甲磺酰氯 Trifluoromethanesulfonyl Chloride 5G 565元 2014/06/02 T1027 三氟甲磺酰氯 Trifluoromethanesulfonyl Chloride 25G 1720元 2010/06/21 173050050 三氟甲烷磺酰氯 Trifluoromethanesulfonyl chloride 99% 5 GR 553元
  • Sigma Aldrich:421-83-0(sigmaaldrich)
  • Alfa Aesar:三氟甲烷磺酰氯,98% Trifluoromethanesulfonyl chloride, 98%(421-83-0)
  • TCI Shanghai:三氟甲磺酰氯 Trifluoromethanesulfonyl Chloride,>;98.0%(GC)(421-83-0)
  • 图谱信息:三氟甲烷磺酰氯(421-83-0)红外图谱(IR1) 三氟甲烷磺酰氯(421-83-0)质谱(MS) 三氟甲烷磺酰氯(421-83-0)核磁图( 13 CNMR)
  • F:10-21
  • 蒸气压:10.36 psi ( 20 °C)
  • 敏感性:Lachrymatory

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents
  1. sulfonyl halide

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