(2-Dimethylaminoethyl)Triphenylphosphonium Bromide 2-二甲氨乙基三苯溴化鏻
CAS 21331-80-6 MFCD00011794
化学结构图
SMILES: [Br-].CN(C)CC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | (CH3)2NCH2CH2P(C6H5)3Br |
|---|---|
| Mol. Weight | 414 |
| Melting Point | 196.0 to 202.0 deg-C |
| TSCA | No |
别名和识别编码
| Chemical Name | (2-Dimethylaminoethyl)Triphenylphosphonium Bromide |
|---|---|
| MDL Number | MFCD00011794 |
| Beilstein Registry Number | 4072092 |
| EC Number | 244-335-2 |
| CAS Number | 21331-80-6 |
| Synonym | (2-二甲基氨基乙基)三苯基溴化膦 |
| Chemical Name Translation | 2-二甲氨乙基三苯溴化鏻 |
| Reaxys-RN | 4072092 |
| PubChem Substance ID | 87568131 |
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相关文献及参考
- Wittig reactions with aldehydes or ketones lead to allylic amines. See Appendix 1. Conditions giving predominantly either the (E)- or (Z)-isomer has been reported: Helv. Chim. Acta, 61, 1708 (1978); J. Chem. Soc., Perkin 1, 2033 (1985).
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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