(3-Bromopropyl)triphenylphosphonium Bromide (3-溴丙基)三苯基溴化膦

CAS 3607-17-8 MFCD00011866

化学结构图

3607-17-8
SMILES: BrCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]

化学属性

Mol. FormulaC21H21Br2P
Mol. Weight464.17
Melting Point228-230°C
TSCANo
SolubilityHygroscopic
Stability对湿度敏感

别名和识别编码

Chemical Name(3-Bromopropyl)triphenylphosphonium Bromide
Synonym (3-Bromopropyl)triphenylphosphonium bromide {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (3-Bromopropyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00011866
PubChem Substance ID87564144
CAS Number3607-17-8
EC Number222-770-9
Reaxys-RN3811004
Beilstein Registry Number6422974
Chemical Name Translation(3-溴丙基)三苯基溴化膦
InChIKeyZAHUZZUGJRPGKW-UHFFFAOYSA-M
LabNetwork Molecule IDLN00200919
InChIInChI=1S/C21H21BrP.BrH/c22-17-10-18-23(19-11-4-1-5-12-19,20-13-6-2-7-14-20)21-15-8-3-9-16-21;/h1-9,11-16H,10,17-18H2;1H/q+1;/p-1
Canonical SMILESBrCCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • For collected organophosphorus intermediates, see Appendix 1.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:3607-17-8.mol
  • (3-溴丙基)三苯基溴化磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1208 3-溴丙基三苯基溴化磷 3-Bromopropyltriphenylphosphonium Bromide 25G 160元 2010/06/21 159121000 (3-溴丙基)三苯基溴化磷 (3-Bromopropyl)triphenylphosphonium bromide 98% 100 GR 1354元 2010/06/21 159120250 (3-溴丙基)三苯基溴化磷 (3-Bromopropyl)triphenylphosphonium bromide 98% 25 GR 522元
  • Alfa Aesar:（3－溴丙基）三苯基溴化膦,98% (3-Bromopropyl)triphenylphosphonium bromide, 98%(3607-17-8)
  • Sigma Aldrich:3607-17-8(sigmaaldrich)
  • 图谱信息:(3-溴丙基)三苯基溴化磷(3607-17-8)红外图谱(IR1) (3-溴丙基)三苯基溴化磷(3607-17-8)红外图谱(IR2) (3-溴丙基)三苯基溴化磷(3607-17-8)核磁图( 13 CNMR) (3-溴丙基)三苯基溴化磷(3607-17-8)质谱(MS) (3-溴丙基)三苯基溴化磷(3607-17-8)核磁图( 1 HNMR)
  • TCI Shanghai:（3-溴丙基）三苯基溴化磷 3-Bromopropyltriphenylphosphonium Bromide,>;98.0%(LC)(T)(3607-17-8)
  • 敏感性:Hygroscopic
  • Acros Organics:(3-Bromopropyl)triphenylphosphonium bromide, 98%(3607-17-8)
  • (3-溴丙基)三苯基溴化磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B1208 3-溴丙基三苯基溴化磷 3-Bromopropyltriphenylphosphonium Bromide 25G 405元 2010/06/21 159121000 (3-溴丙基)三苯基溴化磷 (3-Bromopropyl)triphenylphosphonium bromide 98% 100 GR 1354元 2010/06/21 159120250 (3-溴丙基)三苯基溴化磷 (3-Bromopropyl)triphenylphosphonium bromide 98% 25 GR 522元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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