(1,3-Dioxolan-2-Ylmethyl)Triphenylphosphonium Bromide (1,3-二氧戊环-2-基)甲基三苯基溴化鏻

CAS 52509-14-5 MFCD00011966

化学结构图

52509-14-5
SMILES: [Br-].C(C1OCCO1)[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC22H22BrO2P
Mol. Weight429
Melting Point193-195
TSCANo

别名和识别编码

Chemical Name(1,3-Dioxolan-2-Ylmethyl)Triphenylphosphonium Bromide
MDL NumberMFCD00011966
PubChem Substance ID87568604
CAS Number52509-14-5
EC Number257-977-3
Reaxys-RN3581786
Alfabeta NameDIOXOLANYLMETHYLTRIPHENYLPHOSPHONIUMBROMIDE 132()----,
Synonym (1,3-二氧环戊基-2-甲基)三苯基溴化膦
Chemical Name Translation(1,3-二氧戊环-2-基)甲基三苯基溴化鏻
LabNetwork Molecule IDLN00184427
InChIKeyFRHRVQQUICVJDG-UHFFFAOYSA-M
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Yuan, L.; et al. Chem. Commun. 47 , 6275, (2011)
  • 2. Bruno, C.; et al. Synthesis , 4193, (2010)
  • 3. Maestrup, E. G.; et al. Bioorg. Med. Chem. 19 , 393, (2011)
  • 4. Sisa, M.; et al. J. Med. Chem. 52 , 6217, (2009)
  • 5. Marchetti, M.; et al. J. Mol. Catal. A: Chem. 288 , 103, (2008)
  • Aldrich MSDS 1 , 821:A / Corp MSDS 1 (1), 1449:B / FT-IR 2 (2), 3334:A / FT-IR 1 (2), 547:B / FT-NMR 1 (2), 1673:C / IR-Spectra (3), 1184:E / RegBook 1 (2), 2277:A / Structure Index 1 , 356:E:4
  • Fieser 5 ,269

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Hygroscopic
Warnings IRRITANT

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Dioxanes & Dioxolanes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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