Diethyl (2-oxopropyl)phosphonate 丙酮基膦酸二乙酯

CAS 1067-71-6 MFCD00044728

化学结构图

1067-71-6
SMILES: CCOP(=O)(CC(C)=O)OCC

化学属性

Mol. FormulaC7H15O4P
Mol. Weight194.17
Density1.01
Boiling Point263.1°C at 760 mmHg
Refractive index1.4330 to 1.4370
Flash Point>113°C
TSCANo
pH:A

别名和识别编码

Chemical NameDiethyl (2-oxopropyl)phosphonate
CAS Number1067-71-6
Alfabeta NameDIETHYLOXOPROPYLPHOSPHONATE 2()-
MDL NumberMFCD00044728
Synonym 1-Diethoxyphosphinyl-2-propanone {LY} 1-Diethoxyphosphinyl-2-propanone {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} { {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Diethoxyphosphinyl-2-propanone
EC Number250-023-7
Beilstein Registry Number1365081
PubChem Substance ID14028
Reaxys-RN1365081
Chemical Name Translation丙酮基膦酸二乙酯
InChIKeyRSAFKRSMGOSHRK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00175986
InChIInChI=1S/C7H15O4P/c1-4-10-12(9,11-5-2)6-7(3)8/h4-6H2,1-3H3
Canonical SMILESCC(CP(OCC)(OCC)=O)=O
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分类

  • {uni_hamburg} no charge; ketone; 1fragment
  • {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents

相关文献及参考

  • Beilstein:4(4)3604
  • Short: III/35C4

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Personal Protective Equipment Eyeshields, Gloves
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

  • MOL 文件:1067-71-6.mol
  • 丙酮基膦酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3174 (2-氧代丙基)磷酸二乙酯 Diethyl (2-Oxopropyl)phosphonate 25G 2930元 2014/06/02 D3174 (2-氧代丙基)磷酸二乙酯 Diethyl (2-Oxopropyl)phosphonate 5G 834元 2010/06/21 123690250 丙酮基膦酸二乙酯 Diethyl (2-oxopropyl)phosphonate 96% 25 GR 4366元
  • Acros Organics:（2-氧丙基）磷酸二乙酯 Diethyl (2-oxopropyl)phosphonate, 96%(1067-71-6)
  • Sigma Aldrich:1067-71-6(sigmaaldrich)
  • Alfa Aesar:乙酰基甲基膦酸二乙酯,97% Diethyl acetylmethylphosphonate, 97%(1067-71-6)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Functional Group 官能团索引
  2. phosphonic acid derivative
  1. Functional Group 官能团索引
  2. phosphonic acid ester

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