Potassium Hexacyanoferrate(III) 铁氰化钾

CAS 13746-66-2 MFCD00011392

化学结构图

13746-66-2
SMILES: N#C[Fe-3](C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+].[K+]

化学属性

Mol. FormulaC6FeK3N6
Mol. Weight329.24
Melting Pointdec.
Density1.89
TSCAYes
Solubility464 G/L (20 ºC)
Stability对光敏感

别名和识别编码

Chemical NamePotassium Hexacyanoferrate(III)
Synonym Potassium ferrocyanide, AR, ≥ 99.5% {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR, ≥ 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium ferrocyanide, AR,
MDL NumberMFCD00011392
PubChem Substance ID57651743
CAS Number13746-66-2
EC Number237-323-3
Merck Number14,7630
Chemical Name Translation铁氰化钾
Wiswesser Line NotationNC-FE-CN&CN&CN&CN&CN &-KA- 3
LabNetwork Molecule IDLN00195663
Canonical SMILES[K][K].[K][Fe](C#N)(C#N)(C#N)(C#N)(C#N)C#N
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分类

  • {SNA} Amprolium, Derivatization Reagents, Derivatization Reagents HPLC, HPLC Derivatization Reagents, by Application, 分析/色谱, 分析试剂
  • Analytical Reagents, Analytical/Chromatography, Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron,
  • {SNA} Essential Chemicals, Metal and Ceramic Science, Potassium Salts, Research Essentials, Salts, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Core Bioreagents, Development Quantities for Research, Essential Chemicals, General Reagents, Iron, Iron Salts, Life Science Reagents for Tran

产品应用

  • 色谱分析用试剂,点滴分析测定高铁、铯、镓、汞、锌和二氧化铀等。有机合成的缓和氧化剂。氮肥生产甲醇的含硫量分析。农药除草醚生产中废水分析。

相关文献及参考

  • 3. Y. Hatefi Meth. Enzymol. 53 , 11, (1978) 摘要
  • Merck: 14,7630 Beilstein: 2,IV,72
  • 2. K. Mihara, R.Sato Meth. Enzymol. 52 , 102, (1978) 摘要
  • Merck: 14,7630
  • Merck 14 ,7630

安全信息

WGK Germany2
RTECSLJ8225000
Personal Protective Equipment Eyeshields, Gloves Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Risk Statements
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2970 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(4),23,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 117,149,1983

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 750 nmol/tube
REFERENCE :
   LAMEDS LARC Medical.  (19 bis, rue d'Inkermann, 59000 Lille, France)  V.1-
   1981-  Volume(issue)/page/year: 6,252,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 117,149,1983

GHS Symbol
UN Number
Hazard Codes
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
Packing GroupIII

其他信息

  • 其热溶液能被酸分解，放出剧毒氰化氢气体。遇亚铁盐生成兰色沉淀。能被光及还原剂还原成亚铁氰化钾。缓慢溶于2.5份冷水、1.3份沸水，微溶于乙醇。其水溶液在存放过程中逐渐分离。最小致死量(大鼠，经口)1600mg/kg。红色透明结晶，溶于水、丙酮，不溶于乙醇、液氨。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iron - 铁催化剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. ACS Grade - Inorganic Salts, Solutions and Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  5. O-P, Puriss p.a. ACS - Puriss p.a. ACS
  1. Research Essentials 基础科研
  2. Core Bioreagents - Research Essentials
  3. Life Science Reagents for Protein Expression and Purification - Core Bioreagents
  4. General Reagents - Life Science Reagents for Protein Expression and Purification
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Potassium Salts - Salts
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. HPLC Derivatization Reagents, by Application - Derivatization Reagents HPLC
  6. Amprolium - HPLC Derivatization Reagents, by Application
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Volumetric Solutions - Titration
  5. Salt Solutions - Volumetric Solutions
  6. N - R - Salt Solutions
  1. Analytical & Chromatography 分析化学与色谱
  2. Routine Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Iridium
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  4. HPLC Derivatization Reagents, by Application
  5. Amino Acids
  1. Analytical & Chromatography 分析化学与色谱
  2. Titration
  3. Indicators
  4. Indicators for non-aqueous titrations
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  4. HPLC Derivatization Reagents, by Application
  5. Amino Acids