2,4-Dinitrophenylsulfenyl Chloride 2,4-二硝基苯硫氯

CAS 528-76-7 MFCD00007129

化学结构图

528-76-7
SMILES: [O-][N+](=O)C1C=C(C=CC=1SCl)[N+]([O-])=O

化学属性

Mol. FormulaC6H3ClN2O4S
Mol. Weight234.61
Melting Point96.0 to 99.0 deg-C

别名和识别编码

Chemical Name2,4-Dinitrophenylsulfenyl Chloride
Synonym 2,4-dinitrobenzenesulphenyl chloride 2,4-Dinitrophenylthio chloride 2,4-dinitrophenylsulphenyl chloride 2,4-DINITROBENZENESULFENYL CHLORIDE 2,4-Dinitrophenylsulfenyl chloride, Kharasch reagent Benzenesulfenyl chloride,2,4-dinitro- 2,4一二硝基苯硫氯 Kharasch 试剂 2,4-二硝基苯硫基氯 Kharasch 试剂 2,4-Dinitrobenzenesulphenyl chloride DNP-SULFENYL CHLORIDE 2,4-dinitro-benzenesulfenyl chloride Dnp-sulfenyl chloride 氯化-2,4-二硝基苯基硫 KHARASCH REAGENT Benzenesulfenyl chloride, 2,4-dinitro- LABOTEST-BB LT00453936 (2,4-Dinitrophenylthio) chloride 2,4-二硝基苯硫基氯 2,4-Dinitrophenylsulfenyl chloride 2,4-Dinitrobenzenesulfenyl chloride 2,4-dinitro-benzenesulfenylchlorid 2,4-二硝基苯硫氯 2 4-DINITROPHENYL SULFENYL CHLORIDE 96% 2,4-DINITROPHENYLSULFENYL CHLORIDE 2,4-Dinitro-benzolsulfenylchlorid
Beilstein Registry Number6(2)316
PubChem Substance ID87567963
CAS Number528-76-7
EC Number208-441-2
MDL NumberMFCD00007129
Reaxys-RN405600
Merck Number3274
Chemical Name Translation2,4-二硝基苯硫氯
LabNetwork Molecule IDLN01741568
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Molecular Biology, Organic Building Blocks, Protein Modification, Protein Structural Analysis, Proteomics, Reagents for tryptophan modification, Specific Amino Acid Modification, Sulfenyl Halides, Sulfur Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Protein Modification, Protein Structural Analysis, Reagents for tryptophan modification, Specific Amino Acid Modification, Sulfenyl Halides, Sulfur Compounds, 分子生物学, 蛋白质组学
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks,

相关文献及参考

  • Merck 14 ,3274
  • Beil. 6 ,IV,1772
  • Fieser 1 ,319 / Fieser 6 ,231 / Fieser 9 ,194
  • Aldrich MSDS 1 , 810:C / Corp MSDS 1 (1), 1431:C / FT-IR 2 (2), 2315:A / FT-IR 1 (1), 1370:B / IR-Spectra (2), 725:H / IR-Spectra (3), 828:B / NMR-Reference 2 (1), 1174:B / RegBook 1 (1), 1589:A / Sigma FT-IR 1 (2), 515:A / Structure Index 1 , 247:D:7
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P303+P361+P353
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P330+P331+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
WGK Germany3
GHS Symbol
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes C
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
UN Number UN 3261 8/PG 2 2925
Storage condition 0-10 0-10°C Store at RT.
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R34 Causes burns 会导致灼伤
Packing GroupII
Hazard Class4.1/8

其他信息

  • Sigma Aldrich:528-76-7(sigmaaldrich)
  • F:8-9-19-21
  • 2,4一二硝基苯硫氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1463 2,4一二硝基苯硫氯 2,4-Dinitrophenylsulfenyl Chloride 5G 424元
  • MOL 文件:528-76-7.mol
  • TCI Shanghai:2,4一二硝基苯硫氯 2,4-Dinitrophenylsulfenyl Chloride,>;96.0%(T)(528-76-7)
  • 图谱信息:2,4一二硝基苯硫氯(528-76-7)红外图谱(IR1) 2,4一二硝基苯硫氯(528-76-7)红外图谱(IR2) 2,4一二硝基苯硫氯(528-76-7)核磁图( 1 HNMR) 2,4一二硝基苯硫氯(528-76-7)核磁图( 13 CNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfenyl Halides - Sulfur Compounds
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Protein Structural Analysis - Proteomics
  4. Protein Modification - Protein Structural Analysis
  5. Specific Amino Acid Modification - Protein Modification
  6. Reagents for tryptophan modification - Specific Amino Acid Modification
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Peptide Synthesis

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