CAS 87-60-5 MFCD00007766-3-Chloro-2-methylaniline 3-氯-2-甲基苯胺 -LabNovo

3-Chloro-2-methylaniline 3-氯-2-甲基苯胺

CAS 87-60-5 MFCD00007766

化学结构图

SMILES: Cc1c(N)cccc1Cl

化学属性

Mol. Formula	C7H8ClN
Mol. Weight	141.60
Refractive index	1.5880 to 1.5900
Boiling Point	115-117°C at 760 mmHg
Density	1.185
Melting Point	2°C
Flash Point	113°C
TSCA	Yes
Solubility	微溶于水，溶于稀酸、热醇。
pH	:A

别名和识别编码

Chemical Name	3-Chloro-2-methylaniline
CAS Number	87-60-5
Alfabeta Name	CHLOROMETHYLANILINE 32---
MDL Number	MFCD00007766
Synonym	3-Chloro-2-methylphenylamine {LY} 3-Chloro-2-methylphenylamine {} {LY} 3-Chloro-2-methylphenylamine {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Chloro-2-methylphenylamine {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	6894
EC Number	201-756-6
Beilstein Registry Number	471697
Reaxys-RN	471697
Chemical Name Translation	3-氯-2-甲基苯胺
Wiswesser Line Notation	ZR CG B1
LabNetwork Molecule ID	LN00008119
InChI	InChI=1S/C7H8ClN/c1-5-6(8)3-2-4-7(5)9/h2-4H,9H2,1H3
Canonical SMILES	NC1=CC=CC(Cl)=C1C

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安全信息

Warnings IRRITANT

GHS Symbol

WGK Germany2

Hazard statements

H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H302 Harmful if swallowed 吞食有害
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes Xn C,N

RTECSXU4760000

Precautionary statements

P305+P351+
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P332+P313
P307+P311
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P302+P350
P337+P313
P301+P312+P330
P302+P352+P332+P313+P362+P364

Signal word

UN Number UN3429

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R22 Harmful if swallowed 吞咽有害
R33 Danger of cumulative effects 有累积作用的危险
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R34 Causes burns 会导致灼伤
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R51/53

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Packing GroupIII

Hazard Class6.1

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 237 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 574 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,613,1986

TYPE OF TEST            : DNA inhibition
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 46,305,1977

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

方法一:其制备方法是在压力釜中投入2-氯-6-硝基甲苯、催化剂兰尼镍、助剂和甲醇，于一定温度下通氢气反应2h，脱溶，减压蒸馏得3-氯-2-甲基苯胺。
用途四:有机合成中间体。
MOL 文件:87-60-5.mol
用途一:是合成染料、农药的重要原料，可合成染料DB-50，可生产水田除草剂快杀稗等
下游产品:2,6-二氯甲苯 --> 二氯喹啉酸 --> 3-氯-2-甲基苯甲腈 --> 7-二甲氨基-4-甲基香豆素 --> C. I. 颜料黄 155 --> 2-氯-6-氟甲苯 --> 7-氯-8-甲基喹啉 --> 3-氯-2-甲基苯基异硫氰酸酯
用途三:大红色基 TR 可用于染棉、黏胶纤维、蚕丝、锦纶和醋酸纤维，也可用于棉布的印花。主要用于染红色，如与色酚 AS、AS-BO、AS-ITR 等偶合均得红色。偶合能力中等，偶合速度较快。
TCI Shanghai:2-氨基-6-氯甲苯 2-Amino-6-chlorotoluene,>;99.0%(GC)(T)(87-60-5)
上游原料:铁粉 --> 三氯化铁 --> 2-硝基甲苯 --> 2-氯-6-硝基甲苯
方法三:由邻硝基甲苯经氯化、还原而得。1.氯化在邻硝基甲苯中，加入2%的三氯化铁作为催化剂，于50-60℃通入氯气，至反应液的相对密度到达1.27-1.29（50℃）为止，用5%盐酸洗涤，再用水洗涤，最后用液碱调节pH为7。分尽水层，蒸去水分后，进行减压蒸馏，收集120-150℃（5.33-8.0kPa）馏分，冷却结晶、过滤，得2-氯-6-硝基甲苯。2.还原将盐酸和铁粉加入反应锅中搅拌加热，至90℃，慢慢加入熔化的2-氯-6-硝基甲苯，加毕，回流反应3h。冷却，加液碱调节pH为8，蒸汽蒸馏，得3-氯邻甲苯胺。
图谱信息:3-氯-2-甲基苯胺(87-60-5)核磁图( 1 HNMR) 3-氯-2-甲基苯胺(87-60-5)核磁图( 13 CNMR) 3-氯-2-甲基苯胺(87-60-5)红外图谱(IR1) 3-氯-2-甲基苯胺(87-60-5)质谱(MS)
MSDS 信息:3-氯邻甲苯胺(87-60-5).msds
Sigma Aldrich:87-60-5(sigmaaldrich)
Acros Organics:3-氯-2-甲基苯胺 3-Chloro-2-methylaniline, 99%(87-60-5)
水中溶解度:4.5 g/l (20°C)，溶于乙醚和乙醇。
3-氯-2-甲基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C0300 2-氨基-6-氯甲苯 2-Amino-6-chlorotoluene 25ML 137元 2014/06/02 C0300 2-氨基-6-氯甲苯 2-Amino-6-chlorotoluene 500ML 902元 2010/06/21 146495000 3-氯-2-甲基苯胺 3-Chloro-2-methylaniline 99% 500 ML 1199元
外观性质:黄色液体。
方法二:以邻硝基甲苯为原料，经氯化、还原得产物。产物经蒸馏纯化后与盐酸成盐，过滤、干燥、粉碎得成品。。
海关编码:29214300
Alfa Aesar:3-氯-2-甲基苯胺,98+% 3-Chloro-2-methylaniline, 98+%(87-60-5)
用途二:3-氯-2-甲基苯胺是除草剂二氯喹啉酸的中间体，也可制备2，6-二氯甲苯。

3-Chloro-2-methylaniline 3-氯-2-甲基苯胺

CAS 87-60-5 MFCD00007766

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