4-Bromoaniline 4-溴苯胺

CAS 106-40-1 MFCD00007822

化学结构图

106-40-1
SMILES: Nc1ccc(Br)cc1

化学属性

Mol. FormulaC6
Mol. Weight172
Density1.5
Melting Point60-67
TSCAYes
Boiling Point124
Solubility不溶于冷水，易溶于乙醇、醚。
Stability对空气敏感，对光敏感
Flash Point222-224°C
Appearance crystalline

别名和识别编码

Chemical Name4-Bromoaniline
MDL NumberMFCD00007822
CAS Number106-40-1
EC Number203-393-9
Beilstein Registry Number742031
Synonym p-Bromoaniline p-Bromoaniline Aniline, p-bromo- 对氨基溴化苯 p-bromo-anilin p-Bromophenylamine p-Bromanilin P-BROMOANILINE 4-Bromaminobenzol 4-BROMOBENZENAMINE 4-BROMOANILINE 对溴苯胺 4-BROMOANILINE 4-溴苯胺, 98+% 4-溴苯胺 4-Bromo-phenylamine 4-BROMOBENZENAMIDE 4-bromanilinu(czech) 4-bromo-benzenamin Benzenamine, 4-bromo- AKOS BBS-00003662 4-氨基-2-溴苯 1-Amino-4-bromobenzene PARA- BROMOANILINE 4-Bromobenzenamine; p-bromophenylamine p-Aminobromobenzene 4-Bromanilinu p-Bromophenylamine 4-Bromanilin 对溴苯胺 {uni_h
PubChem Substance ID7807
Merck Number1404
Alfabeta NameBROMOANILINE 4-
Reaxys-RN742031
Chemical Name Translation4-溴苯胺
Wiswesser Line NotationZR DE
LabNetwork Molecule IDLN00180941
InChIInChI=1S/C6H6BrN/c7-5-1-3-6(8)4-2-5/h1-4H,8H2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C6, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 有机合成，制备二氢喹唑啉。

相关文献及参考

  • Short: II/27B
  • Merck:14,1404
  • Merck:14,1404 Beilstein:12(4)1497
  • Short: III/20a

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R33 Danger of cumulative effects 有累积作用的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSBW9280000
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Packing GroupIII
UN Number 2811 UN 2811 6.1/PG 3
Hazard Codes 6.1 Xn
Warnings 危化品目录(2015) IRRITANT
Storage condition 对光和空气敏感，密封避光保存
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 289 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 44(12),19,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 248 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 44(12),19,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 456 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CEHYAN Ceskoslovenska Hygiena.  Czechoslovak Hygiene.  (PNS-Ustredni
   Expedice a Dovoz Tisku, Kafkova 19, 160 00 Prague 6, Czechoslovakia) V.1-
   1956-  Volume(issue)/page/year: 23,168,1978

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 50 umol/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 3,11,1981

Restrict 危险品

其他信息

  • 可燃性危险特性:遇明火可燃; 燃烧释放有毒氮氧化物和溴化物烟雾
  • TCI Shanghai:4-溴苯胺 4-Bromoaniline,>;99.0%(GC)(106-40-1)
  • F:8-9-23
  • Sigma Aldrich:106-40-1(sigmaaldrich)
  • 急性毒性:口服-大鼠LD50: 456 毫克/公斤; 口服-小鼠 LD50: 289 毫克/公斤
  • 上游原料:4-硝基苯胺
  • 检测方法:GC,NMR
  • 用途一:用于偶氮染料制造及有机合成
  • Hazard Note:Harmful
  • 类别:有毒物品
  • 用途二:有机合成中间体。
  • 方法一:以对硝基苯胺为原料，经重氮化、溴化、还原而得。
  • color:white to light yellow
  • 性状:从60%乙醇中析出者为正交晶系双锥体针状结晶。
  • Alfa Aesar:4-溴苯胺,98+% 4-Bromoaniline, 98+%(106-40-1)
  • 图谱信息:4-溴苯胺(106-40-1)红外图谱(IR1) 4-溴苯胺(106-40-1)核磁图( 1 HNMR) 4-溴苯胺(106-40-1)Raman光谱 4-溴苯胺(106-40-1)质谱(MS) 4-溴苯胺(106-40-1)核磁图( 13 CNMR) 4-溴苯胺(106-40-1)红外图谱(IR2)
  • 存储注意事项:光敏感
  • 海关编码:29214210
  • 外观性质:无色斜方或针状结晶。
  • 下游产品:6-溴-4-氯喹啉 --> 4-氨基联苯酚酯 --> 6-溴喹啉 --> 6-溴喹啉-4(3H)-酮 --> 4-(4-甲基-1-哌嗪基)苯硼酸 --> 溴替尼持 --> 4-溴代联苯 --> 2-(4-溴苯基)噻吩 --> 1-(4-溴苯基)-2-硫代脲 --> 4-氨基苯硼酸频哪醇酯 --> 2-氨基-6-溴苯并噻唑 --> 4-溴苯基脲 --> 4'-溴乙酰苯胺 --> 5-(4-溴苯基)-2-呋喃甲醛 --> 缩聚法合成的聚苯胺
  • MSDS 信息:对氨基溴化苯(106-40-1).msds
  • Acros Organics:4-溴苯胺 4-Bromoaniline, 99+%(106-40-1)
  • 灭火剂:二氧化碳、泡沫、砂土、雾状水。
  • 对光和空气敏感。 除冷石油醚外，易溶于乙醇和乙醚等大多数有机溶剂，不溶于冷水。沸点分解。有刺激性。
  • 毒性分级:高毒
  • 用途三:4-溴苯胺（106-40-1）用于制造染料原料，如偶氮染料、喹啉染料等，医药及有机合成中间体。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • 用途四:有机合成，制备二氢喹唑啉。
  • 4-溴苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80019524 4-溴苯胺;对溴苯胺 25g 70元 2011/04/16 B1393 4-溴苯胺 4-Bromoaniline 25G 420元 2011/04/16 B1393 4-溴苯胺 4-Bromoaniline 500G 4150元
  • MOL 文件:106-40-1.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. C6 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. C10 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C11 to C38
  1. Materials Science 材料科学
  2. Building Blocks for Liquid Crystals