N-Methylbutan-1-amine N-甲基丁胺

CAS 110-68-9 MFCD00009426

化学结构图

110-68-9
SMILES: CCCCNC

化学属性

Mol. FormulaCH3(CH2)3NHCH3
Mol. Weight87
Refractive index1.4000 to 1.4050
Density0.736 g/mL at 25 °C(lit.)
Boiling Point91°C
Flash Point2°C(lit.)
TSCAYes
Melting Point-75°
Solubility与水混溶,可混溶于乙醇。

别名和识别编码

Chemical NameN-Methylbutan-1-amine
MDL NumberMFCD00009426
CAS Number110-68-9
Synonym 甲基丁胺 N-METHYL-N-BUTYLAMINE N-Butylmethylamin (N,N)-Methyl-butylamin N-甲基(正)丁胺 N-Methyl butyl amine N-methyl butylamine N-Methyl-1-butanamine n-methyl-1-butanamin Methylaminobutane N-丁基甲胺 Methylbutylamine Butylamine,N-methyl- N-BUTYLMETHYLAMINE N-Methyl-1-butaneamine N-甲基丁胺 N-Methyl-1-aminobutan N-Butylmethylamine N-Methylbutylamin 1-Butanamine,N-methyl- N-n-Butylmethylamine N-1-丁基胺 n-methyl-butylamin N-Methylbutanamine N-Methyl-1-butylamine 1-Butanamine, N-methyl- Methyl-N-butylamine N-Methyl-n-butylamine N-Methylbutylamine Butylmethylamine butyl-methyl-amine N-N-BUTYLMETHYLAMINE N-(Methyl) butyl amine N-Butyl-N-methylamine Butylamine, N-methyl- N-METHYLBUTYLAMINE
EC Number203-791-2
Beilstein Registry Number4,157
PubChem Substance ID87572275
Reaxys-RN1209231
Chemical Name TranslationN-甲基丁胺
Wiswesser Line Notation4M1
LabNetwork Molecule IDLN00188125
InChIInChI=1S/C5H13N/c1-3-4-5-6-2/h6H,3-5H2,1-2H3
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分类

  • {SNA} Amines, Building Blocks, C2 to C5, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: IV/10A Title: Heats of Mixing and Solution: Binary Liquid Systems of Nonelectrolytes Author: Grolier, J.-P.E.; Wormald, C.J.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H.V. Editor: Kehiaian; H.V. Source: Landolt-Börnstein, New Series Volume: IV/10A Year: 2004 Keyword: Nitrogen Containing; Organic Compounds; Pressure; Vapor; Vapor Pressure ISBN: 3-540-60347-6 ISBN: 978-3-540-60347-4 Internet Resource: DOI: 10.1007/b56530 RefComment: IX, 564 p. 816 illus., Hardcover RefComment: Written for scientists and engineers in the field of physical chemistry, organic chemistry, applied chemistry Abstract: This subvolume containes selected data on heats of mixing (excess enthalpies) of binary liquid mixtures of organic and inorganic nonelectrolytes, including aqueous-organic systems, in broad ranges of temperature, pressure, and composition. All the data are extracted from the original literature published from 1957 to 2003. The printed volume presents tables for 800 representative mixtures. The CD-ROM displays all these data, as well as 2853 additional data files, in PDF format and in a fully documented computer readable standard electronic file (SELF) format. Moreover, the ELBT-program allows the fast search of data according to property type, chemical system (substances and mixtures), author(s), source and year of publication. Moreover it allows the correlation of the numerical data with several equations and the display of the original data and of the correlated data in tabular and graphical form.
  • Short: IV/13A1 Title: Vapor-Liquid Equilibrium in Mixtures and Solutions. Binary Liquid Systems of Nonelectrolytes. Part 1 Author: Wichterle, I.; Linek, J.; Wagner, Z.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V. Editor: Kehiaian, H.V. Source: Landolt-Börnstein, New Series Volume: IV/13A1 Year: 2007 Keyword: Activity coefficients; Excess Gibbs energy; Mixtures; Nonelectrolytes; Solutions; Vapor-liquid equilibria ISBN: 97

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEO5250000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2945 UN 2945 3/PG 2 UN2945
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R11 Highly flammable 非常易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Hazard Codes F,C
Hazard Class3/8
Storage condition Flammables area
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1260 uL/kg
TOXIC EFFECTS :
   Skin and Appendages - primary irritation (after topical exposure)
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 471 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 88,82,1946

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 420 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 7/6/1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 122 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 88,82,1946

TY

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSU

Restrict 危险品

其他信息

  • TCI Shanghai:N-甲基正丁胺 N-Methylbutylamine,>;90.0%(GC)(110-68-9)
  • Alfa Aesar:N-1-丁基胺,98% N-Methyl-1-butylamine, 98%(110-68-9)
  • 外观性质:无色液体, 具有挥发性, 有强烈的氨气味。
  • 图谱信息:甲基丁胺(110-68-9)核磁图( 1 HNMR) 甲基丁胺(110-68-9)红外图谱(IR1) 甲基丁胺(110-68-9)红外图谱(IR2) 甲基丁胺(110-68-9)质谱(MS) 甲基丁胺(110-68-9)核磁图( 13 CNMR)
  • 毒性分级:中毒
  • 甲基丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0179 N-甲基丁胺 N-Methylbutylamine 500ML 539元 2014/06/02 M0179 N-甲基丁胺 N-Methylbutylamine 25ML 150元 2010/06/21 171815000 甲基丁胺 N-Methylbutylamine 98% 500 ML 506元
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • MSDS 信息:N-甲基丁胺(110-68-9).msds
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • MOL 文件:110-68-9.mol
  • Sigma Aldrich:110-68-9(sigmaaldrich)
  • 急性毒性:口服- 大鼠 LD50: 420 毫克/ 公斤; 吸入- 大鼠 LC50: 2000 PPM/ 4 小时
  • 刺激数据:眼睛- 兔子 74 毫克 重度
  • Acros Organics:N-甲基丁胺 N-Methylbutylamine, 98%(110-68-9)
  • 类别:易燃液体

系列性分类