Boron tribromide 三溴化硼

CAS 10294-33-4 MFCD00011312

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 377607
Boron tribromide 三溴化硼
1.0 M solution in methylene chloride, SpcSeal 100mL 260
BY-CN
中国国内现货 1.0 M solution 二氯甲烷
INFI 377607
Boron tribromide 三溴化硼
1.0 M solution in methylene chloride, SpcSeal 500mL 890
1.0 M solution 二氯甲烷
INFI 508589
Boron tribromide 三溴化硼
99.9% metals basis 25g 110
99e1 %
INFI 508589
Boron tribromide 三溴化硼
99.9% metals basis 100g 270
99e1 %
INFI 508589
Boron tribromide 三溴化硼
99.9% metals basis 500g 950
99e1 %
INFI 515493
Boron tribromide 三溴化硼
1.0 M solution in heptane, SpcSeal 100mL 310
LN-CN
中国国内现货 1.0 M solution 庚烷
INFI 515493
Boron tribromide 三溴化硼
1.0 M solution in heptane, SpcSeal 500mL 1,080
LN-CN
中国国内现货 1.0 M solution 庚烷
INFI 515494
Boron tribromide 三溴化硼
1.0 M solution in hexanes, SpcSeal 100mL 260
LN-CN
中国国内现货 1.0 M solution 己烷
INFI 515494
Boron tribromide 三溴化硼
1.0 M solution in hexanes, SpcSeal 500mL 890
LN-CN
中国国内现货 1.0 M solution 己烷
INFI 588794
Boron tribromide 三溴化硼
2.0 M solution in toluene, SpcSeal 100mL 370
LN-CN
中国国内现货 2.0 M solution 甲苯
INFI 588794
Boron tribromide 三溴化硼
2.0 M solution in toluene, SpcSeal 500mL 1,290
LN-CN
中国国内现货 2.0 M solution 甲苯
INFI 702355
Boron tribromide 三溴化硼
2.0 M solution in methylene chloride, SpcSeal 100mL 260
2.0 M solution 二氯甲烷
INFI 702355
Boron tribromide 三溴化硼
2.0 M solution in methylene chloride, SpcSeal 500mL 890
2.0 M solution 二氯甲烷
Innochem 669502
Boron tribromide 三溴化硼
99.9% metals basis 25g 140
99e1 %
Innochem 669502
Boron tribromide 三溴化硼
99.9% metals basis 100g 340
99e1 %
Innochem 669502
Boron tribromide 三溴化硼
99.9% metals basis 500g 1,190
99e1 %
Innochem 669502
Boron tribromide 三溴化硼
99.9% metals basis 1kg 1,990
99e1 %
TCI 133948
Boron Tribromide (17% in Dichloromethane, ca . 1mol/L) >
ca. 1mol/L) 100mL 980
SH-CN BJ-CN
中国国内现货 0
Alfa 133949
Boron tribromide, 1M soln. in dichloromethane
N/A 25mL 326
BJ-CN CN
中国国内现货 0
Alfa 133949
Boron tribromide, 1M soln. in dichloromethane
N/A 100mL 844
BJ-CN CN
中国国内现货 0
Alfa 133951
Boron tribromide
99.999% (metals basis) 10g 1,304
CN
中国国内现货 99e3
Alfa 133951
Boron tribromide
99.999% (metals basis) 50g 6,571
CN
中国国内现货 99e3
Alfa 133953
Boron tribromide
99% min 50g 691
CN
中国国内现货 99
Alfa 133953
Boron tribromide
99% min 250g 3,663
CN
中国国内现货 99
Alfa 133954
Boron tribromide
1M soln. in heptane 100mL 828
0
TCI 544442
Boron Tribromide (29% in Heptane, ca . 1mol/L) >
100mL 1,390
J&K 377833
Boron tribromide, 1.0 M solution in CH2Cl2
100mL 802
HB
中国国内现货 1.0 M solution 二氯甲烷
Aldrich 133924
Boron tribromide 三溴化硼
>=99.99% 5g 433
99e2
Aldrich 133924
Boron tribromide 三溴化硼
>=99.99% 25g 1,295
99e2
Aldrich 133924
Boron tribromide 三溴化硼
>=99.99% 100g 3,611
99e2
Aldrich 133925
99.9% 25g 713
99e1
Aldrich 133925
99.9% 100g 1,792
99e1
Aldrich 133925
99.9% 250g 3,234
99e1
Aldrich 133925
99.9% 2kg 17,667
99e1
Aldrich 133927
>=99% 25g 1,034
99
Aldrich 133927
>=99% 100g 1,034
99
Aldrich 133927
>=99% 500g 3,195
99
Aldrich 133929
1.0M SOLUTION IN HEPTA NE 100mL 1,074
0
Aldrich 133930
1.0M SOLUTION IN HEXAN ES 100mL 1,156
0
Acros 280497
Boron tribromide, 1M solution in methylene chloride
10mL 826
SH-CN
中国国内现货 0
Acros 280497
Boron tribromide, 1M solution in methylene chloride
100mL 2,462
SH-CN
中国国内现货 0
Acros 280497
Boron tribromide, 1M solution in methylene chloride
800mL 12,413
0
Acros 285208
Boron tribromide, 99+%
25g 594
SH-CN CN
中国国内现货 0
Acros 285208
Boron tribromide, 99+%
100g 896
SH-CN CN
中国国内现货 0
Acros 285208
Boron tribromide, 99+%
500g 3,235
0
Acros 296542
Boron tribromide, 1M solution in methylene chloride, AcroSeal?
100mL 1,532
SH-CN
中国国内现货 0
Acros 303563
Boron tribromide, 1M solution in heptane, AcroSeal
100mL 1,063
0
Acros 303563
Boron tribromide, 1M solution in heptane, AcroSeal
800mL 4,549
0
Acros 311236
Boron tribromide, 99.9%
25g 707
SH-CN
中国国内现货 0
Acros 311236
Boron tribromide, 99.9%
100g 1,476
0
Acros 311236
Boron tribromide, 99.9%
500g 4,971
0
TRC 382386
Boron Tribromide
1g 1,540
TRC 382386
Boron Tribromide
25g 1,750
Energy-chemical 397798
Boron tribromide 三溴化硼
99.9% 25g 65
CN-BJ CN-SH
中国国内现货 99e1 %
Energy-chemical 397798
Boron tribromide 三溴化硼
99.9% 100g 198
CN-BJ CN-SH
中国国内现货 99e1 %
Energy-chemical 397798
Boron tribromide 三溴化硼
99.9% 500g 745
CN-BJ CN-SH
中国国内现货 99e1 %
Aladdin 397799
Boron tribromide 三溴化硼
99.999% metals basis 10g 999
CN-SH
中国国内现货 99e3 %
Aladdin 397799
Boron tribromide 三溴化硼
99.999% metals basis 50g 3,499
CN-SH
中国国内现货 99e3 %
Aladdin 397800
Boron tribromide 三溴化硼
99.9% metals basis 25g 64
CN-SH
中国国内现货 99e1 %
Aladdin 397800
Boron tribromide 三溴化硼
99.9% metals basis 100g 197
CN-SH
中国国内现货 99e1 %
Aladdin 397800
Boron tribromide 三溴化硼
99.9% metals basis 500g 743
CN-SH
中国国内现货 99e1 %
Aladdin 397801
Boron tribromide 三溴化硼
99.99% metals basis 25g 899
CN-SH
中国国内现货 99e2 %
Aladdin 397801
Boron tribromide 三溴化硼
99.99% metals basis 100g 2,980
99e2 %
Aladdin 397802
Boron tribromide 三溴化硼
1.0 M 二氯甲烷溶液 100mL 119
CN-SH
中国国内现货 1.0 M
Aladdin 397802
Boron tribromide 三溴化硼
1.0 M 二氯甲烷溶液 500mL 1,485
CN-SH
中国国内现货 1.0 M
Acros 403997
AcroSeal? 800mL 4,640
0
Energy-chemical 409460
1.0mol/l in CH2Cl2, EnergySeal 100mL 860
1.0 M solution 二氯甲烷
Energy-chemical 409460
1.0mol/l in CH2Cl2, EnergySeal 500mL 3,430
1.0 M solution 二氯甲烷
Adamas 410179
99.99% 50g 410
SH-CN BJ-CN CN
中国国内现货 99e2 %
Aldrich 410180
1.0M SOLUTION IN DICHL OROMETHANE 800mL 8,325
0
Aldrich 410181
99.9% 100g 1,792
99e1
Aldrich 410182
>=99% 25g 1,034
99
Aldrich 410183
1.0M SOLUTION IN HEXAN ES 100mL 1,156
0
Aldrich 410184
99.9% 250g 3,234
99e1
Aldrich 410185
>=99% 500g 3,195
99
Aldrich 410186
99.995% 100g 3,611
99e3
Aldrich 410187
99.9% 25g 713
99e1
Aldrich 410188
99.995% 25g 1,295
99e3
Aldrich 410189
99.9% 2kg 17,667
99e1
Aldrich 410190
99.995% 5g 433
99e3
Aldrich 410191
1.0M SOLUTION IN DICHL OROMETHANE 100mL 1,610
0
Aldrich 410192
1.0M SOLUTION IN HEPTA NE 100mL 1,074
0
Aldrich 410194
1.0M SOLUTION IN 2L 12,110
0
Aldrich 410196
>=99% 100g 1,034
99
HY 518406
Boron tribromide 三溴化硼
1.0 M solution in Methylene chloride,HySeal 100mL -
1.0 M solution Methylene Chloride
HY 518406
Boron tribromide 三溴化硼
1.0 M solution in Methylene chloride,HySeal 500mL -
1.0 M solution Methylene Chloride
HY 518406
Boron tribromide 三溴化硼
1.0 M solution in Methylene chloride,HySeal 800mL -
1.0 M solution Methylene Chloride
Strem 544443
Boron bromide, 99+%
99+% 25g 570
99e1 %
Strem 544443
Boron bromide, 99+%
99+% 100g 1,330
99e1 %
Strem 544443
Boron bromide, 99+%
99+% 500g 5,320
99e1 %
Strem 544444
Boron bromide, elec. gr. (99.999%-B) PURATREM
(99.999%-B) 5g 1,335
Strem 544444
Boron bromide, elec. gr. (99.999%-B) PURATREM
(99.999%-B) 25g 4,140
Strem 544444
Boron bromide, elec. gr. (99.999%-B) PURATREM
(99.999%-B) 100g 12,375
Adamas 544445
1.0 M solution in Methylene chloride 100mL 1,026
1.0 M solution Methylene Chloride
Adamas 544446
17% in Methylene chloride,Safeseal 500mL 2,185
SH-CN BJ-CN CN
中国国内现货 10+ % solution Methylene Chloride
TRC 544447
Boron Tribromide
1g 1,320
TRC 544447
Boron Tribromide
25g 1,500
Adamas 544448
17% in Methylene chloride,SafeSeal 100mL 551
SH-CN CN
中国国内现货 10+ % solution Methylene Chloride
Meryer 559540
三溴化硼
1.0 M 二氯甲烷溶液 100mL 474
CN
中国国内现货 1.0 M
Meryer 559540
三溴化硼
1.0 M 二氯甲烷溶液 500mL 1,891
1.0 M
Acros 589660
99+% 25g 516
99e1 %
Acros 589660
99+% 100g 762
99e1 %
Aladdin 622439
25g 64
BJ-CN
中国国内现货
Aladdin 622441
500g 743
BJ-CN
中国国内现货
Aladdin 622443
100g 2,980
BJ-CN
中国国内现货
Aladdin 622445
25g 899
BJ-CN
中国国内现货
Aladdin 622446
10g 999
BJ-CN
中国国内现货
Aladdin 622447
100mL 493
BJ-CN
中国国内现货
Aladdin 622448
50g 3,499
BJ-CN
中国国内现货
Aladdin 622449
500mL 1,968
Aladdin 622450
100g 197
BJ-CN
中国国内现货
3A 634053
Boron tribromide 三溴化硼
99.9% metals basis 25g 110
99e1 %
3A 634053
Boron tribromide 三溴化硼
99.9% metals basis 100g 270
99e1 %
3A 634053
Boron tribromide 三溴化硼
99.9% metals basis 500g 950
99e1 %
3A 634053
Boron tribromide 三溴化硼
99.9% metals basis 1kg 1,530
99e1 %
3A 634157
Boron tribromide 三溴化硼
1.0 M solution in hexanes, SpcSeal 100ml 260
1.0 M solution 己烷
3A 634157
Boron tribromide 三溴化硼
1.0 M solution in hexanes, SpcSeal 500ml 890
1.0 M solution 己烷
3A 634339
Boron tribromide 三溴化硼
1.0 M solution in methylene chloride, SpcSeal 100ml 260
1.0 M solution Methylene Chloride
3A 634339
Boron tribromide 三溴化硼
1.0 M solution in methylene chloride, SpcSeal 500ml 890
1.0 M solution Methylene Chloride
3A 634449
Boron tribromide 三溴化硼
1.0 M solution in heptane, SpcSeal 100ml 310
1.0 M solution Heptane
3A 634449
Boron tribromide 三溴化硼
1.0 M solution in heptane, SpcSeal 500ml 1,080
1.0 M solution Heptane
3A 634450
Boron tribromide 三溴化硼
2.0 M solution in toluene, SpcSeal 100ml 370
2.0 M solution Toluene
3A 634450
Boron tribromide 三溴化硼
2.0 M solution in toluene, SpcSeal 500ml 1,290
2.0 M solution Toluene
Acros 685338
10mL 843
Acros 685339
100mL 2,561
Acros 685340
100mL 1,084
Acros 685341
100mL 1,563
Acros 685342
800mL 12,914
Acros 685343
800mL 8,891
Acros 685344
25g 721
Acros 685345
25g 774
Acros 685346
100g 1,506
Acros 685347
500g 5,070
Acros 685348
500g 3,917

分类

  • {SA} Chemical Synthesis, Deprotecting Reagents, Others, Protection and Derivatization, Synthetic Reagents
  • {Chemicalbook} 无机化工产品: 无机盐: Cb硼化物
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Deprotecting Reagents, Others, Protection and Derivatization, Synthetic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Chemical Synthesis, Deprotecting Reagents, Organometallic Reagents, Others, Protection and Derivatization, Synthetic Reagents

产品应用

  • ⑴.易被水和醇等分解,受热会爆炸,对人体组织有强烈刺激作用,其蒸气剧毒,腐蚀性较强,具有强吸水性,见光、遇热易分解,接触空气冒白烟。为强路易式酸,能与碱反应形成络合物和加成物。
  • ⑵.在干燥空气中不变化。溶于无机酸并剧烈起泡。天然碱产于不同的盐湖沉积物中,主要产于碱湖及古代沉积矿床中,常与针碳钠钙石、水碱、泡碱、石盐、芒硝、钙芒硝、无水芒硝和石膏共生。遇空气中的湿气很容易水解。
  • ⑶.重要的工业原料,广泛用于玻璃、化工、轻工、纺织、漂染、冶金、石油加工、医药、食品等方面。
  • ⑷.用作半导体的掺杂材料,有机 用作有机合成的催化剂、中间体和溴化剂,制造高纯硼及其它有机硼化合物的原料。

相关文献及参考

  • Reagent for cleavage of ethers: Synthesis, 249 (1983). Converts alcohols to alkyl bromides under mild conditions: Tetrahedron Lett., 35, 1051 (1994). Cleavage of N-methoxymethyl: Tetrahedron Lett., 42, 8633 (2001), or N-benzyl: Tetrahedron Lett., 45, 4093 (2004) protecting groups can also be achieved under mild conditions. Alkynes undergo bromoboration; the products can be transformed, e.g. to trisubstituted alkenes: Tetrahedron Lett., 29, 1811 (1988), or enyne-allenes: Tetrahedron Lett., 35, 1829 (1994).
  • Short: II/25A
  • Merck:14,1347
  • Reagent for cleavage of ethers. For a brief feature of uses of the reagent in organic synthesis, see: Synlett, 1636 (2005). See also preceding entry.
  • Reagent for cleavage of ethers: Synthesis, 249 (1983). Converts alcohols to alkyl bromides under mild conditions: Tetrahedron Lett., 35, 1051 (1994). Cl

安全信息

GHS Symbol
WGK Germany3
Hazard Codes
  • T+
  • T+,C
  • T+;C
  • T+,C,F,N
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H300 Fatal if swallowed 吞食致命
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H300+330
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSED7400000
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261305+351+338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+340+310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+330+331+310
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260264280284301+310305+351+338
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P308+311
Signal word
Storage condition
  • Moisture Sensitive
  • 2-8℃易吸潮,密封充氩保存。
  • Poison room
  • 充氩保存
  • 易吸潮,密封充氩保存。
  • Moisture & Light Sensitive
  • 0-10°C
  • 避光,易吸潮,密封充氩保存。
  • 0-10
UN Number
  • 3390
  • UN2692
  • 3489
  • UN3390
  • UN3384
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
  • R14 Reacts violently with water 遇水会猛烈反应
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R11 Highly flammable 非常易燃
  • R50/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R34 Causes burns 会导致灼伤
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupI
Hazard Class6.1/3, 8
Warnings
  • 危化品目录(2015)

其他信息

  • ⑴.储存于阴凉、干燥、通风良好的库房。 ⑵.远离火种、热源。包装必须密封,切勿受潮。 ⑶.应与碱类、醇类等分开存放,切忌混储。不宜久存,以免变质。 ⑷.储区应备有泄漏应急处理设备和合适的收容材料。

化学结构图

CAS 10294-33-4  MFCD00011312
SMILES: BrB(Br)Br

化学属性

Mol. FormulaBBr3
Mol. Weight250.52
Boiling Point90°C
Density1.45
Melting Point-46°C
Refractive index1.4340
TSCAYes
Flash Point-4°C(lit.)
Vapor Density8.6 (vs air)
Vapor Pressure40 mmHg ( 14 °C)
Solubility溶于四氯化碳。
Stability对热、光线、湿度敏感

别名和识别编码

Chemical NameBoron tribromide
Synonym
  • BORON TRIBROMIDE, REAGENTPLUS, >=99%
  • BORON TRIBROMIDE, 99.995%
  • 晶碱石
  • boron (III) bromide
  • BORON TRIBROMIDE, REAGENTPLUS, 99.9%
  • Bortribromid
  • 三溴化硼(0402禁空运)
  • boronbromide(bbr3)
  • 三溴化硼,1M在二氯甲烷溶剂中
  • Boron tribromide
  • tribromoborane
  • 三溴化硼
  • BORON TRIBROMIDE, 1.0M SOLUTION IN HEPTA NE
  • tribromo-boran
  • Boron bromide (BBr3)
  • BORON TRIBROMIDE SOLUTION, ~1 M IN DICHL OROMETHANE
  • Borane,tribromo-
  • Boron,tribromo-
  • trona
  • 天然碱
  • BORON TRIBROMIDE
  • BBr3
  • 三溴化硼 溶液
  • Borane, tribromo-
  • BORON TRIBROMIDE, 1.0M SOLUTION IN HEXAN ES
  • Tribromoboron
  • tribromuredebore
  • 溴化硼
  • boron tribromide
  • 三溴硼烷(爆炸,禁止销售)BORON TRIBROMIDE, 99.9%
  • 三溴硼烷
  • 丝光晶碱石
  • BORON TRIBROMIDE, 1.0M SOLUTION IN DICHL OROMETHANE
  • Boron tribromide Solution
  • BORON BROMIDE
  • Boron bromide
  • 溴化硼;天然碱
  • 三溴化硼, 99% MIN
  • 碳酸钠石
  • tribromoboron
  • Tribromoborane
  • 天然碱;碳酸钠石
  • BBr3
    CAS Number10294-33-4
    PubChem Substance ID 125307031
    EC Number233-657-9
    MDL NumberMFCD00011312
    Reaxys-RN3903058
    Merck Number1347
    Beilstein Registry Number2384789
    Chemical Name Translation三溴化硼
    LabNetwork Molecule IDLN00163667

    系列性分类


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